A better understanding of the dynamics of different particulate organic matter (OM) pools in the coastal carbon budget is a key issue for quantifying the role of the coastal ocean in the global carbon cycle. To elucidate the benthic component of this carbon cycle at the land-sea interface, we investigated the carbon isotope signatures (δ13C and ∆14C) in the sediment pore waters dissolved inorganic carbon (DIC) in addition to the sediment OM to constrain the origin of the OM mineralized in sediments. The study site is located at the outlet of the Rhône River (Mediterranean Sea), which was chosen because this river is one of the most nuclearized rivers in Europe and nuclear 14C can serve as a tracer to follow the fate of the OM discharged by the river to the coastal sea. The ∆14C results found in the pore waters DIC show a general offset between buried and mineralized OM following a preferential mineralization model of young and fresh particles. For example, we found that the sediment OM has values with a mean ∆14C=–33‰ at sampling stations near the river mouth whereas enriched ∆14C values around +523‰ and +667‰ respectively were found for the pore waters DIC. This indicates complete mineralization of a riverine fraction of OM enriched in 14C in the river conduit during in-stream photosynthesis. In shelf sediments, the ∆14C of pore waters DIC is slightly enriched (+57‰) with sediment OM reaching –570‰. A mixing model shows that particles mineralized near the river mouth are certainly of riverine phytoplanktonic origin whereas OM mineralized on the shelf is of marine origin. This work highlights the fact that pore waters provide additional information compared to sediments alone and it seems essential to work on both pools to study the carbon budget in river prodelta.

This sixth date list for the prehistoric site of El Mirón Cave (Cantabria, Spain) reports on new age determinations for the earliest and last Solutrean occupations (20.4 and 18.0 14C kyr BP) and for a Lower/Initial Magdalenian level with a possible rock wall (16.75 14C kyr BP). The site has now been dated by 92 radiocarbon (14C) assays. In addition, to help resolve inconsistencies in the 14C chronology of La Riera Cave (Asturias)—the first Paleolithic site in Spain to be extensively 14C-dated back in the 1970s—two AMS assays were done on bones from the Lower and Upper Magdalenian collections (15.1 and 13.5 14C kyr BP).

In this paper we analyze the radiocarbon (14C) concentration changes over the whole operational period of the Ignalina Nuclear Power Plant (INPP) including the post-shutdown decommissioning. Environmental samples from the vicinity of the INPP and a rural area as background of pine tree rings were analyzed with the single stage accelerator mass spectrometer (SSAMS). The analysis shows the local influence of the INPP from 3 to 7 pMC. The whole time span from 1983 to 2015 is divided into three periods representing the early and late operational and post-shutdown stages of the INPP with different 14C profiles in analyzed samples. The influence of the maintenance of the INPP and radioactive waste management activities are indicated and discussed.

Ignalina NPP contains two Units with RBMK-1500 reactors. After shutdown, several Unit 1 systems and equipment were radiologically characterized and dismantled. The highest volume of reactor structures is attributed to the graphite stack of the reactor core, radiological characterization of which has not yet been performed. The stack can be visualized as a vertical cylinder 8 m high and 14 m diameter, made up of 2488 columns where each column is made up from several graphite blocks. The total mass of the graphite stack blocks is about 1700 tonnes. Therefore, the main goal of work reported in this paper was to estimate the inventory of 14C and other key radionuclides in the irradiated graphite by a combination of activity measurements and full 3D reactor graphite stack neutron activation modeling. Obtained results show that, based on the combination of modeling and measurement techniques, the total inventory of 14C in graphite stack is estimated at 3.22×1014 Bq at 9 years after Unit 1 reactor final shutdown. 14C activity is the highest among the analyzed radionuclides; the second highest is 60Co (~6 times lower).

We collected peat sediments (sediment core ADK13083002) from Haven Lake on the north side of Adak Island (central Aleutian Islands, Alaska) to determine whether the vegetation has changed. We confirmed the presence of six tephra layers, including Forty Years (0.3 cal ka BP), T2, YBO (3.3 cal ka BP), Intermediate (6.4 cal ka BP), Main (9.5 cal ka BP), and T6. We identified four major pollen assemblage zones (HL-1 to HL-4, in descending order) in the cored sediment. HL-1 was dominated by Ranunculaceae and Empetrum pollen; H-2 was dominated by Poaceae, Ranunculaceae, and Empetrum pollen; HL-3 was dominated by Poaceae and Empetrum pollen; and HL-4 was dominated by Poaceae, Cyperaceae, Lycopodiaceae, and Empetrum pollen. Small charcoal particles, likely transported from a distance, were found at low frequencies until 6.4 cal ka BP. The total cross-sectional area of charcoal particles increased to 1500 μm2 or more by 6.4 cal ka BP, implying that the large charcoal particles originated from nearby Aleut settlements, which were established around the same time.

Ust’-Polui is one of the most extensively studied archaeological sites in the western Siberian Arctic. New radiocarbon (14C) dates for charcoal, faunal remains, bark, hide, and human bone from this site are presented. When modeled, the charcoal dates span from ~260 BC to 140 AD, overlapping with the dendrochronology dates from the site. These dates also overlap with the expected age of the site based on artefact typology. 14C dates on reindeer bone have a slightly younger modeled age range, from ~110 BC to 350 AD. In contrast, dates on the site’s numerous dog remains, and on human and fish bone, all predate these modeled age ranges by over 500 years, despite being from the same deposits. Several sets of paired dates demonstrate significant age differences. Bone dates with lower δ13C values tend to be over 500 years older than those with higher δ13C values. Stable isotope data for the humans, dogs, and other faunal remains are also presented. These data suggest the dogs and the humans were regularly consuming freshwater fish. The dogs were probably fed fish by their human counterparts. Overall, the dog and human dietary patterns at Ust’-Polui created 14C dates biased with major freshwater reservoir effects.

Here, we introduce a new radiocarbon (14C) extraction line operating at the University of Bern, which was designed and built for the extraction of in situ 14C from meteorites. With this system, we achieved two important developments compared to other systems. First, using the MICADAS gas-interface system, 14C can directly be measured from the collected CO2 gas, i.e., without graphitization of the sample. Second, meteorite sample masses as low as ~0.05 g can be used for high precision and reproducibility. Prior to extraction in an oxygen atmosphere held at a pressure of ~20–30 mbar in an iridium crucible at 1600°C for 40 min, samples were preheated for 1 h in a constant oxygen flow at 500°C and continuous pumping. Gas purification followed the method described previously (e.g., Hippe et al. 2009). While the blank levels for preheated samples are low (<2×104 14C atoms), the blanks for non-preheated samples are high, therefore those results cannot be used. We also report preliminary results for the L-chondrite JaH 073. The terrestrial age of 17.7±0.4 ka is in good agreement with previous results for the same sample of this meteorite, confirming that the extraction line, the gas purification system, and the AMS measurements are all reliable.

To date, finding a technique able to effectively isolate the carbon signal from the binder of a mortar is still an open challenge. In this paper, the radiocarbon (14C) dating of one of the most challenging and diffuse types of mortar, the one with pozzolana aggregate, is investigated. Eight mortar samples from three archaeological sites near Rome (Italy) underwent a selection process called Cryo2SoniC. The selected fractions were analyzed by the accelerator mass spectrometry (AMS) 14C technique and compared to known historical references. Additional scanning electron microscopy analysis and petrographic investigations were done, respectively, to check the grain size of the fractions selected by Cryo2SoniC, and further, to characterize the original mortar samples. The masses of carbon yielded from the dated fractions were almost half of those released from some aerial mortars. The 14C dating results were accurate for pozzolana mortars, from buried and unburied structures, with calcination relics and small contamination of secondary calcite. A limitation in the purification protocol was observed on samples with a massive contamination of secondary calcite deposition of ground water origin, occluding porosity and substituting up to the 80% of the original binder matrix.

Distributions of Δ14CTOC studied in bottom sediments collected during 2011–2016 in the Curonian Lagoon and in the open Baltic Sea indicated wide variations of Δ14CTOC values. Laboratory experiments on differential carbon utilization by Pseudomonas putida isolated from bottom sediments were carried out for better understanding of impacts of different sources on Δ14CTOC variations. Preferential glucose uptake (up to 80%) as a carbon source and a rather low (2–10%) inorganic carbon incorporation was found in media with diesel fuel. Pseudomonas putida a specific biomarker analyzed in biomass cultivated on the media with different carbon sources has been used to characterize microbial communities responsible for degradation of organic substances in bottom sediments. Large 14C depletions observed in sediments collected in the Gotland Deep of the Baltic Sea may indicate leakage from dumped chemical weapons.

Two radiocarbon (14C) excursions are caused by an increase of incoming cosmic rays on a short time scale found in the Late Holocene (AD 774–775 and AD 993–994), which are widely explained as due to extreme solar proton events (SPE). In addition, a larger event has also been reported at 5480 BC (Miyake et al. 2017a), which is attributed to a special mode of a grand solar minimum, as well as another at 660 BC (Park et al. 2017). Clearly, other events must exist, but could have different causes. In order to detect more such possible events, we have identified periods when the 14C increase rate is rapid and large in the international radiocarbon calibration (IntCal) data (Reimer et al. 2013). In this paper, we follow on from previous studies and identify a possible excursion starting at 814–813 BC, which may be connected to the beginning of a grand solar minimum associated with the beginning of the Hallstatt period, which is characterized by relatively constant 14C ages in the period from 800–400 BC. We compare results of annual 14C measurements from tree rings of sequoia (California) and cedar (Japan), and compare these results to other identified excursions, as well as geomagnetic data. We note that the structure of the increase from 813 BC is similar to the increase at 5480 BC, suggesting a related origin. We also assess whether there are different kinds of events that may be observed and may be consistent with different types of solar phenomena, or other explanations.

Samples of graphite from a RBMK-1500 reactor at the Ignalina Nuclear Power Plant from different construction elements (stack, sleeve, and bushing) were analyzed by the instrumental neutron activation analysis (INAA) method (LVR-15 experimental reactor of the Research Centre Řež, Ltd.) using the prompt gamma activation analysis (PGAA) method (Heinz Maier-Leibnitz Zentrum) and with an inductively coupled plasma mass spectrometer (ICP-MS) (CPST, Lithuania). These measurements were performed with the aim of obtaining the missing information on the impurity distribution in the RBMK-type nuclear graphite constructions as well as for intercomparison purposes, with the results measured in the graphite sleeve samples previously obtained by INAA & GDMS (Glow Discharge Mass Spectrometry) at CEA Saclay, France, and ICP-MS (CPST, Lithuania) methods. Validation of the ICP-MS method for the nuclear graphite impurity concentration determination was proven. The experimentally obtained RBMK-1500 graphite impurity values in different graphite constructions were compared with other measurements and new limits of the possible maximal concentrations of nuclear RBMK graphite impurity concentrations were obtained.

The so-called Millennium Eruption of Baitoushan Volcano is one of the largest of the Common Era but its date has been uncertain. Recently, Oppenheimer et al. (2017) reported the eruptive year as late AD 946 using a new method called carbon-14 spike matching. However, it is necessary to verify their result to confirm the eruptive year, since only one wood sample was used in their study. We verified the eruptive year by measuring 14C contents in tree rings from another wood sample buried during the Baitoushan eruption. We succeeded in reproducing the AD 774–775 14C spike (Miyake et al. 2012), and counted the number of rings from the outermost ring accompanied by bark to the ring possessing the AD 774–775 14C spike. We found the outermost ring was formed in AD 946. Our study supported the result of Oppenheimer et al. (2017), which makes the eruptive year conclusive. Also, we suggest that the 14C spike-matching method can be a prominent dating tool applicable to ancient woods that are difficult to date using the usual dendrochronology techniques.

Hemiparasitic plants obtain water and solutes from their hosts, but much remains to be learned about these transfers. We used a forest girdling experiment to investigate how leaf gas exchange, carbon and nitrogen cycling in the root hemiparasite Melampyrum lineare Desr. responded to disturbance and changes in physiology of potential host trees. By preventing belowground C allocation by 35% of the canopy, girdling decreased the starch and soluble sugar contents of bulk forest floor fine roots. Photosynthetic rates of M. lineare were statistically significantly lower in the girdled plot, but their hypothesized drivers (foliar N, stomatal conductance and transpiration) had no statistically significant differences between girdled and non-girdled plots. However, M. lineare in the girdled plot had higher foliar C concentrations and Δ14C than in the control plot, suggesting possible photosynthetic down-regulation in the girdled plot due to influx of older (e.g., host-derived) C into the leaves of M. lineare. Within the girdled plot (but not the control plot), M. lineare foliar C concentrations were positively correlated with foliar Δ14C and δ15N, suggesting that M. lineare may respond to changes in both C and N biogeochemistry during the decline of dominant canopy species.

Sea surface reservoir ages (R) are reported from radiocarbon (14C) measurements of the annual growth bands of coral Siderastrea siderea collected on the Atlantic coast off Martinique Island, in the Lesser Antilles volcanic arc. Mean values of R are similar between 1835 and 1845 during pre-anthropogenic times at 385±30 yr and between 1895 and 1905 at 382±20 yr when there was a huge eruption from the Montagne Pelée volcano in 1902–1903. Limited 14C aging of sea surface (~40 yr) may be due to enhanced volcanic activity. Variability of R is slightly greater during 1835–1845 than during 1895–1905. It is linked to a moderate increase of ∆14C of 5‰, strengthened by a clear increase of δ18O of 0.4‰. This is attributed to a decrease of the northward advection of the South Atlantic Waters into the western tropical North Atlantic and Caribbean Sea and relative enhanced westward flux of the tropical North Atlantic surface waters, the southern waters having lower values of 14C and δ18O than the North Atlantic ones. From 1835 to 1845, the fraction of the South Atlantic Waters transported up to Martinique Island was reduced from 25% to 15%.

Archaeological fieldwork at Hjarnø Sund in Horsens Fjord (eastern Jutland, Denmark) has explored an eroding Mesolithic shell midden. Its stratigraphy is characterized by two layers, containing marine mollusk taxa typically collected by Mesolithic hunter-gatherers for food. In the field, the lower layer appeared to be dominated by oysters (Ostrea edulis), while the upper one by cockles (Cerastoderma edule), which was confirmed by our zooarchaeological study. Accelerator mass spectrometry radiocarbon (AMS 14C) dating on shells and paired charcoal samples from the two layers indicate that these are chronologically consecutive (separated by as little as 0–163 yr [95.4%]) and that the oyster-to-cockle shift dated between ~5500–5300 and ~5300–5200 cal BC (around or just after the Kongemose/Ertebølle transition). The shell midden at Hjarnø Sund is, thus, one of the oldest-known in Denmark, demonstrating that intensive shellfish exploitation was a hallmark of the Ertebølle culture from its inception. Oyster-to-cockle shifts, thus, also occurred at times other than the Mesolithic–Neolithic Transition and may have been ultimately caused by local shoreline displacements, resulting from changes in sedimentation, possibly induced by drops in relative sea level.

An increase in atmospheric radiocarbon (14C) content of about 11.3‰ in the period AD 993–994 was observed in annual tree rings from Japanese cedar (Cryptomeria japonica) and Hinoki cypress (Chamaecyparis obtusa) (Miyake et al. 2013, 2014). Single-year samples of dendrochronologically dated tree rings (English oak, Quercus robur) from Kujawy, a village near Krakow (SE Poland), spanning the years AD 981–1000, were collected, and their 14C content was measured using the AMS system in the Leibniz Laboratory. The results clearly show an increase of 6.2±1.6‰ in the 14C concentration in tree rings between AD 993 and 994, with a maximum increase of 10.9±1.7‰ between AD 991 and 994.

The understanding of the 14C behavior in waste packages could lead, in the Spanish context, to a revision of the management strategies for radioactive waste and a revaluation of the near surface repository devoted to the disposal of waste containing this radionuclide in high concentrations. To achieve this objective, and in the context of the EU project Carbon-14 Source Term (CAST), the authors of the work presented in this paper have performed leaching experiments with irradiated graphite considering two different scenarios. One, in which the leaching solution simulates some of the expected conditions in a repository where a granite/bentonite mixture has been used as backfill material, and the other, using deionized water as a high efficiency chemical removal agent and for comparison purposes. The analytical approach to measure the release rate and speciation of 14C from irradiated graphite samples in the aqueous and gaseous phase is also described. The main results obtained shows that, after 359 days of leaching, no 14C activity was detected above the detection limits, and only leaching rates regarding beta-gamma emitters were observed: 2×10–6 cm/day for 137Cs and 1×10–5 cm/day for 60Co in granite/bentonite water media and 4×10–6 cm/day for 137Cs in pure water.

The radiocarbon (14C) content of irradiated graphite is the most important problem for the management of Spanish irradiated graphite (Vandellós I NPP) as L&ILW, due to this material exceeding the maximum 14C inventory for the C.A. El Cabril repository. Therefore, the encapsulation of graphite in an impermeable matrix and making an appropriate waste form are indicated as potential management options to be studied. The conversion of the graphite to a long-term stable glass matrix, called IGM (impermeable graphite matrix), uses a long-term stable inorganic binder which additionally encloses the graphite pore system. The world’s first IGM samples made with irradiated graphite have been manufactured in CIEMAT facilities. The durability of the matrix is investigated in leaching experiments in deionized water and granitic bentonite water. The results show that ∼0.05% of 14C is leached. A species of organic carbon was found as formate and oxalate (∼10–1 mg/L). CO was detected as volatile specie in both media in the first leaching steps; for deionized water (∼3.101 mg/L) and in granitic bentonite water (ranging 1.101–3.101 mg/L). These low values demonstrated the durability of the IGM glass matrix for final disposal.