During a rainfall event, water infiltrates into the ground where it accumulates in porous rocks. This accumulation pushes the underlying groundwater towards neighbouring streams, where it runs to the sea. After the rain has stopped, the aquifer gradually releases its excess water, as the water table relaxes, until the next rain. In the absence of recharge, the water table would eventually reach its horizontal equilibrium position. The volume of groundwater stored above this level, which we call the active volume, sustains the river between two rainfall events. In this article, we use an experimental aquifer recharged by artificial rain to investigate how this active volume depends on the rainfall rate. Restricting our analysis to the steady-state regime, wherein the discharge into the stream balances rainfall, we explore a broad range of rainfall rates, for which the water table deforms significantly. We find that the active volume of water stored in the aquifer decreases with its depth. Using conformal mapping, we derive the flow equations and develop a numerical procedure that accounts for the active volume of groundwater in our experiments. In the case of an infinitely deep aquifer, the problem admits a closed-form solution, which provides a satisfying estimate of the active volume when the aquifer's depth is at least half its width. In the general case, a rougher estimate results from the energy balance of the dissipative groundwater flow.

The Hele-Shaw–Cahn–Hilliard model, coupled with phase separation, is numerically simulated to demonstrate the formation of anomalous fingering patterns in a radial displacement of a partially miscible binary-fluid system. The composition of injected fluid is set to be less viscous than the displaced fluid and within the spinodal or metastable phase-separated region, in which the second derivative of the free energy is negative or positive, respectively. Because of phase separation, concentration evolves non-monotonically between the injected and displaced fluids. The simulations reveal four areas of the concentration distribution between the fluids: the inner core; the low-concentration grooves/high-concentration ridges; the isolated fluid fragments or droplets; the mixing zone. The grooves/ridges and the fragments/droplets, which are the unique features of phase separation, form in the spinodal and metastable regions. Four typical types of patterns are categorized: core separation (CS); fingering separation (FS); separation fingering (SF); lollipop fingering, in the order of the dominance of phase separation, respectively. For the patterns of CS and FS, isolated fluid fragments or droplets around the inner core are the main features. Fingering formation is better maintained with droplets in the SF pattern if the phase separation is relatively weaker than viscous fingering (VF). Even continuous fingers are well preserved in the case of dominant VF; phase separation results in lollipop-shaped fingers. The evolving trend of the patterns is in line with the experiments. These patterns are summarized in a pattern diagram, mainly by the magnitude of the second derivative of the free energy profile.

We develop a simple model which describes the repeated injection and extraction of hydrogen in a permeable water-saturated rock which has the form of an anticline. We demonstrate that the flow is controlled by the dimensionless ratio of the square of the buoyancy speed to the product of the two-dimensional volume injection rate and the injection–extraction frequency, and we explore the cases in which this ratio is large and small. Over the first few cycles, the volume of hydrogen in the system gradually builds up since during the extraction phase, some of the water eventually reaches the extraction well, and in our model the system ceases to extract fluid for the remainder of this extraction phase. After many cycles, there is sufficient hydrogen in the system that a quasi-equilibrium state develops in which the mass of fluid injected matches the mass extracted over the course of a cycle. We show that in this equilibrium, the ratio between the mass of gas remaining in the aquifer at the end of the extraction phase, known as the cushion gas, to the mass of gas injected, known as the working gas, decreases if either the flow rate or frequency of the cycles decrease or the buoyancy speed increases, leading to more efficient storage.

We present a theory that quantifies the interplay between intrapore and interpore flow variabilities and their impact on hydrodynamic dispersion. The theory reveals that porous media with varying levels of structural disorder exhibit notable differences in interpore flow variability, characterised by the flux-weighted probability density function (PDF), $\hat {\psi }_\tau (\tau ) \sim \tau ^{-\theta -2}$, for advection times $\tau$ through conduits. These differences result in varying relative strengths of interpore and intrapore flow variabilities, leading to distinct scaling behaviours of the hydrodynamic dispersion coefficient $D_L$, normalised by the molecular diffusion coefficient $D_m$, with respect to the Péclet number $Pe$. Specifically, when $\hat {\psi }_\tau (\tau )$ exhibits a broad distribution of $\tau$ with $\theta$ in the range of $(0, 1)$, the dispersion undergoes a transition from power-law scaling, $D_L/D_m \sim Pe^{2-\theta }$, to linear scaling, $D_L/D_m \sim Pe$, and eventually to logarithmic scaling, $D_L/D_m \sim Pe\ln (Pe)$, as $Pe$ increases. Conversely, when $\tau$ is narrowly distributed or when $\theta$ exceeds 1, dispersion consistently follows a logarithmic scaling, $D_L/D_m \sim Pe\ln (Pe)$. The power-law and linear scaling occur when interpore variability predominates over intrapore variability, while logarithmic scaling arises under the opposite condition. These theoretical predictions are supported by experimental data and network simulations across a broad spectrum of porous media.

Pore-resolved direct numerical simulations have been performed to investigate the turbulent open-channel flow over a rough and permeable sediment bed, represented by a mono-disperse random sphere pack. After a careful validation, eleven cases were simulated to systemically sample a parameter space spanned by a friction Reynolds number $Re_\tau \in [150, 500]$ and a permeability Reynolds number $Re_K \in [0, 2.8]$. By varying the ratio of flow depth to sphere diameter within a range of $h/D \in \{ 3,5,10,\infty \}$, the influence of both Reynolds numbers on the flow field and the turbulence structure could be investigated independently. The simulation results are analysed within a time–space double-averaging framework, whereas flow visualizations provide insight into instantaneous fields. Based on the drag distribution, we propose a consistent interface description, which can be used to define both near-interface and outer-flow coordinates. In these near-interface coordinates, the profiles of the mean velocity and the total shear stress collapse. Furthermore, the proposed interface definition yields outer-layer coordinates, in which the flow and turbulence statistics over a rough and permeable bed reveal similarity to a smooth-wall flow at a similar $Re_\tau$. Within the parameter space, $Re_\tau$ has a strong influence on the wake region of the velocity profile. In contrast, $Re_K$ changes the wall-blocking effect and the shear intensity, which is reflected by the turbulence structure and vortex orientation in the near-interface region. As streamwise velocity streaks disappear and the vortex inclination increases with higher $Re_K$, differences between near-interface and outer-layer turbulence structure are reduced.

We theoretically and experimentally study gravity currents of a Newtonian fluid advancing in a two-dimensional, infinite and saturated porous domain over a horizontal impermeable bed. The driving force is due to the density difference between the denser flowing fluid and the lighter, immobile ambient fluid. The current is taken to be in the Darcy–Forchheimer regime, where a term quadratic in the seepage velocity accounts for inertial contributions to the resistance. The volume of fluid of the current varies as a function of time as $\sim T^{\gamma }$, where the exponent parameterizes the case of constant volume subject to dam break ($\gamma =0$), of constant ($\gamma =1$), waning ($\gamma <1$) and waxing inflow rate ($\gamma >1$). The nonlinear governing equations, developed within the lubrication theory, admit self-similar solutions for some combinations of the parameters involved and for two limiting conditions of low and high local Forchheimer number, a dimensionless quantity involving the local slope of the current profile. Another parameter $N$ expresses the relative importance of the nonlinear term in Darcy–Forchheimer's law; values of $N$ in practical applications may vary in a large interval around unity, e.g. $N\in [10^{-5},10^{2}]$; in our experiments, $N\in [2.8,64]$. Sixteen experiments with three different grain sizes of the porous medium and different inflow rates corroborate the theory: the experimental nose speed and current profiles are in good agreement with the theory. Moreover, the asymptotic behaviour of the self-similar solutions is in excellent agreement with the numerical results of the direct integration of the full problem, confirming the validity of a relatively simple one-dimensional model.

Porous membranes are thin solid structures that allow the flow to pass through their tiny openings, called pores. Flow inertia may play a significant role in several filtration flows of natural and engineering interest. Here, we develop a predictive macroscopic model to describe solvent and solute flows past thin membranes for non-negligible inertia. We leverage homogenization theory to link the solvent velocity and solute concentration to the jumps of solvent stress and solute flux across the membrane. Within this framework, the membrane acts as a boundary separating two distinct fluid regions. These jump conditions rely on several coefficients, stemming from closure problems at the microscopic pore scale. Two approximations for the advective terms of Navier–Stokes and advection–diffusion equations are introduced to include inertia in the microscopic problem. The approximate inertial terms couple the micro- and macroscopic fields. Here, this coupling is solved numerically using an iterative fixed-point procedure. We compare the resulting models against full-scale simulations, with a good agreement both in terms of averaged values across the membrane and far-field values. Eventually, we develop a strategy based on unsupervised machine learning to improve the computational efficiency of the iterative procedure. The extension of homogenization towards weak-inertia flow configurations as well as the performed data-driven approximation may find application in preliminary analyses as well as optimization procedures towards the design of filtration systems, where inertia effects can be instrumental in broadening the spectrum of permeability and selectivity properties of these filters.

Understanding the solutal convection is a crucial step towards accurate prediction of CO$_2$ sequestration in deep saline aquifers. In this study, pore-scale resolved direct numerical simulations (DNS) are performed to analyse the scaling laws of the solutal convection in porous media. The porous media studied are composed of uniformly distributed square or circular elements. The Rayleigh numbers in the range $426 \le Ra \le 80\,000$, the Darcy numbers in the range $1.7\times 10^{-8} \le Da \le 8.8\times 10^{-6}$ and the Schmidt numbers in the range $250 \le Sc \le 10^4$ are considered in the DNS. The main time, length and velocity scales affecting the solutal convection are classified as the diffusive scales ($t_I$, $l_I$ and $u_I$), the convective scales ($t_{II}$, $l_{II}$ and $u_{II}$) and the shut-down scales ($t_{III}$, $l_{III}$ and $u_{III}$). These scales determine the pore-scale Rayleigh number $Ra_K$ and the Rayleigh number $Ra$. Based on the DNS results, the scaling laws for the transient dissolution flux are proposed in the different regimes of convection. It is found that the onset time of convection ($t_{oc}$) and the period of the flux-growth regime ($\Delta t_{fg}$) vary linearly with the convective time scale $t_{II}$. The merging of the original plumes and the re-initiation of the new plumes start in the same period, resulting in the merging re-initiation regime. Horizontal dispersion plays an important role in plume merging. The dissolution flux $F$ and the time since the onset of convection $t^{\ast }$ have an $F / u_{II} \sim (t^{\ast }/ t_{II})^{-0.2}$ scaling in the later stage of the merging re-initiation regime. This scaling is caused by the merging of the low-wavenumber plumes. It becomes more pronounced with decreasing porosity and leads to the nonlinear relationship between the Sherwood number $Sh$ and $Ra$ when the domain is not high enough for the plumes to fully develop. According to the DNS results, a regime is expected that is independent of both $Ra$ and $Ra_K$, while the dimensionless constant flux $F_{cf}/u_{II}$ in this regime decreases with decreasing porosity. When the mean solute concentration reaches approximately 30 %, convection enters the shut-down regime. For large $Ra$, the dimensionless flux in the shut-down regime follows the scaling law $F/u_{III}\sim (t/t_{III})^{-1.2}$ at large porosity ($\phi =0.56$) and $F/u_{III}\sim (t/t_{III})^{-1.5}$ at small porosity ($\phi =0.36$ or $0.32$). The study shows the significant pore-scale effect on the convection. The DNS cases in this study are mainly for simplified geometries and large $Ra_K$. This can lead to uncertainties of the obtained scaling coefficients. It is important to determine the scaling coefficients for real geological formations to predict a real CO$_2$ sequestration process.

The effect of microbial activity on buoyancy-driven flow within a porous layer is analysed. The input fluid provides an energy source for the growth of biofilms on the porous rock. At each location within the porous layer, the porosity and permeability begin to decrease once the input fluid has invaded. This leads to an evolving rock heterogeneity that depends on the passing time of the input fluid. Hence, the evolution of the flow is partly controlled by its own history. We present an axisymmetric gravity current model, accounting for this effect. In general, a reduction in permeability leads to the flow having a lesser extent in the radial direction and greater thickness (extent in the cross-flow direction), whilst a reduction in porosity has negligible effect on the thickness but leads to a much greater radial extent. The flow is fastest near the free surface where the permeability is greatest. In the case where the porosity and permeability reduce as power-law functions of fluid residence time, the evolution of the flow and the rock properties are self-similar. Consumption of the input fluid by the microbes is also incorporated in the model and it generally leads to flows with lesser radial extent but little change in the thickness. The three impacts of microbial growth (volume loss owing to consumption and the reduction in permeability and porosity) each influence the flow in substantially different ways and the interplay is analysed. A motivation of the study, the underground storage of hydrogen, is briefly discussed.

The present study aims to examine the temporal linear stability analysis of isothermal plane Couette flow over a porous layer using the two-domain approach. The flow in the porous layer is described by the unsteady Darcy–Brinkman equations, whereas it is characterised by the Navier–Stokes equations in the fluid layer. In contrast to the Darcy model, it is observed that the isothermal plane Couette flow becomes unstable for such a superposed system on the inclusion of the Brinkman term. From the stability analysis, the two-dimensional mode is found to be least stable, and two modes of instability, namely porous mode and mixed mode are obtained under the consideration of the Darcy–Brinkman model along with advection term (DBA model). For Darcy number $(\delta )=0.01$, depending on the value of the stress-jump coefficient, mixed mode controls the instability of the system at small values of depth ratio $(\hat {d})$, and it disappears for relatively high values of $\hat {d}$, where the porous mode dominates. In addition, it has been observed that when $\hat {d}=0.1$, the critical mode of instability is found to be mixed for $\delta >0.02$ and porous for $\delta \le 0.02$. The stress-jump coefficient destabilises the flow in terms of energy production through perturbed stresses at the interface. As observed in the case of isothermal plane Poiseuille flow studied by Chang, Chen & Straughan (J. Fluid Mech., vol. 564, 2006, pp. 287–303), here also depth ratio (Darcy number) stabilises (destabilises) the flow. However, this characteristic does not remain valid when the advection term is eliminated from the considered momentum equation. For a certain range of $\hat {d} (\delta )$, the destabilising (stabilising) characteristic of the respective parameters are encountered when the fluid mode of instability prevails.

High-pressure fluid transport in nanoporous media such as shale formations requires further understanding because conventional continuum approaches become inadequate due to their ultralow permeability and complexity of transport mechanisms. We propose a species-based approach for modelling two partially miscible, multicomponent fluids in nanoporous media – one that does not rely on conventional bulk fluid transport frameworks but on species movement. We develop a numerical model for species transport of partially miscible, non-ideal fluid mixtures using the chemical potential gradient as the driving force. The model considers the binary friction concept to include the friction between fluid molecules as well as between fluid molecules and pore walls, and incorporates the key multicomponent transport mechanisms – Knudsen, viscous and molecular diffusion. Under single-phase conditions, the system under consideration is quantified by introducing multicomponent Sherwood number (Sh), Péclet number (Pe) and fluid–solid friction modulus (φ). Despite the complexity of fluid transport in nanopores, the steady-state single-phase transport results reveal the contribution of diffusion in nanopores, where all parameters collapse on a set of master curves for the multicomponent Sh with a dependence on multicomponent Pe and φ. Unsteady state, two-phase transport modelling of the codiffusion process shows that light and intermediate alkanes are produced much higher than heavy alkanes when the vapour phase appears. We demonstrate that the pressure gradient is also crucial in promoting CO2 and alkane mixing during counterdiffusion processes. These results stress the need for a paradigm shift from classical bulk flow modelling to species-based transport modelling in nanoporous media.

We investigate effect of porous insert located upstream of the separation edge of a backward-facing step (BFS) in early transitional regime as a function of Reynolds number. This is an example of hydrodynamic system that is a combination of separated shear flow with large amplification potential and porous materials known for efficient flow destabilisation. Spectral analysis reveals that dynamics of BFS is dominated by spectral modes that remain globally coherent along the streamwise direction. We detect two branches of characteristic frequencies in the flow and with Hilbert transform we characterise their spatial support. For low Reynolds numbers, the dynamics of the flow is dominated by lower frequency, whereas for sufficiently large Reynolds numbers cross-over to higher frequencies is observed. Increasing permeability of the porous insert results in decrease in Reynolds number value, at which frequency cross-over occurs. By comparing normalised frequencies on each branch with local stability analysis, we attribute Kelvin–Helmholtz and Tollmien–Schlichting instabilities to upper and lower frequency branches, respectively. Finally, our results show that porous inserts enhance Kelvin–Helmholtz instability and promote transition to oscillator-type dynamics. Specifically, the amplitude of vortical (BFS) structures associated with higher-frequency branch follows Landau model prediction for all investigated porous inserts.

A macroscopic model for perfect-slip flow in porous media is derived in this work, starting from the pore-scale flow problem and making use of an upscaling technique based on the adjoint method and Green's formula. It is shown that the averaged momentum equation has a Darcy form in which the permeability tensor, $\boldsymbol{\mathsf{K}}_{ps}$, is obtained from an associated adjoint (closure) problem that is to be solved on a (periodic) unit cell representative of the structure. Similarly to the classical permeability tensor, $\boldsymbol{\mathsf{K}}$, in the no-slip regime, $\boldsymbol{\mathsf{K}}_{ps}$ is intrinsic to the porous medium under consideration and is shown to be symmetric and positive. Integral relationships between $\boldsymbol{\mathsf{K}}_{ps}$, the partial-slip flow permeability tensor, $\boldsymbol{\mathsf{K}}_{s}$, and $\boldsymbol{\mathsf{K}}$ are derived. Numerical simulations carried out on two-dimensional model porous structures, together with an approximate analytical solution and an empirical correlation for a particular configuration, confirm the validity of the macroscopic model and the relationship between $\boldsymbol{\mathsf{K}}_{ps}$ and $\boldsymbol{\mathsf{K}}$.

In studying the transport of inclusions in multiphase systems we are often interested in integrated quantities such as the net force and the net velocity of the inclusions. In the reciprocal theorem the known solution to the first and typically easier boundary value problem is used to compute the integrated quantities, such as the net force, in the second problem without the need to solve that problem. Here, we derive a reciprocal theorem for poro-viscoelastic (or biphasic) materials that are composed of a linear compressible solid phase, permeated by a viscous fluid. As an example, we analytically calculate the time-dependent net force on a rigid sphere in response to point forces applied to the elastic network and the Newtonian fluid phases of the biphasic material. We show that when the point force is applied to the fluid phase, the net force on the sphere evolves over time scales that are independent of the distance between the point force and the sphere; in comparison, when the point force is applied to the elastic phase, the time scale for force development increases quadratically with the distance, in line with the scaling of poroelastic relaxation time. Finally, we formulate and discuss how the reciprocal theorem can be applied to other areas, including (i) calculating the network slip on the sphere's surface, (ii) computing the leading-order effects of nonlinearities in the fluid and network forces and stresses, and (iii) calculating self-propulsion in biphasic systems.

The injection of ${\rm CO}_2$ into depleted reservoirs carries the potential for significant Joule–Thomson cooling, when dense, supercritical ${\rm CO}_2$ is injected into a strongly under-pressured reservoir. The resulting low temperatures around the wellbore risk causing thermal fracturing of the well/near-well region or causing freezing of pore waters or formation of gas hydrates which would reduce injectivity and jeopardise well and reservoir integrity. These risks are particularly acute during injection start-up when ${\rm CO}_2$ is in the gas stability field. In this paper we present a model of non-isothermal single-phase flow in the near-wellbore region. We show that during radial injection, with fixed mass injection rate, transient Joule–Thomson cooling can be described by similarity solutions at early times. The positions of the ${\rm CO}_2$ and thermal fronts are described by self-similar scaling relations. We show that, in contrast to steady-state flow, transient flow causes slight heating of ${\rm CO}_2$ and reservoir gas either side of the thermal front, as pressure diffuses into the reservoir. The scaling analysis here identifies the parametric dependence of Joule–Thomson cooling. We present a sensitivity analysis which demonstrates that the primary controls on the degree of cooling are reservoir permeability, reservoir thickness, injection rate and Joule–Thomson coefficient. The analysis presented provides a computationally efficient approach for assessing the degree of Joule–Thomson cooling expected during injection start-up, providing a complement to complex, fully resolved numerical simulations.

We explored the instability dynamics of the viscous fingering interaction in dual displacement fronts by varying the viscosity configuration. Four regimes of rear-dominated fingering, front-dominated fingering, dual fingering and stable were identified. By using the breakthrough time, which refers to the breakup of the dual displacement fronts, the instability dynamics were modelled, and a regime map was developed. These serve as a tool for effectively harnessing the dual displacement fronts for various applications, such as hydrogeology, petroleum, chemical processes and microfluidics.

The nature and behaviour of the drag coefficient $C_D$ of irregularly shaped grains within a wide range of Reynolds numbers $Re$ is discussed. The morphology of the grains is controlled by their fractal description, and they differ in shape. Using computational fluid dynamics tools, the characteristics of the boundary layer at high $Re$ has been determined by applying the Reynolds-averaged Navier–Stokes turbulence model. Both grid resolution and mesh size dependence are validated with well-reported previous experimental results applied in flow around isolated smooth spheres. The drag coefficient for irregularly shaped grains is shown to be higher than that for spherical shapes, also showing a strong drop in its value at high $Re$. This drag crisis is reported at lower $Re$ compared to the smooth sphere, but higher critical $C_D$, demonstrating that the morphology of the particle accelerates this crisis. Furthermore, the dependence of $C_D$ on $Re$ in this type of geometry can be represented qualitatively by four defined zones: subcritical, critical, supercritical and transcritical. The orientational dependence for both particles with respect to the fluid flow is analysed, where our findings show an interesting oscillatory behaviour of $C_D$ as a function of the angle of incidence, fitting the results to a sine-squared interpolation, predicted for particles within the Stokes laminar regime ($Re\ll 1$) and for elongated/flattened spheroids up to $Re=2000$. A statistical analysis shows that this system satisfies a Weibullian behaviour of the drag coefficient when random azimuthal and polar rotation angles are considered.

Previous work suggests that the arrangement of elements in an obstruction may influence the bulk flow velocity through the obstruction, but the physical mechanisms for this influence are not yet clear. This is the motivation for this study, where direct numerical simulation is used to investigate flow through an array of cylinders at a resolution sufficient to observe interactions between wakes of individual elements. The arrangement is altered by varying the gap ratio $G/d$ (1.2 – 18, G is the distance between two adjacent cylinders, d is the cylinder diameter), array-to-element diameter ratio $D/d$ (3.6 – 200, D is the array diameter), and incident flow angle ($0^{\circ} - 30^{\circ}$). Depending on the element arrangement, it is found that the average root-mean-square lift and drag coefficients can vary by an order of magnitude, whilst the average time-mean drag coefficient of individual cylinders ($\overline{C_{d}}$), and the bulk velocity are found to vary by up to $50\,\%$ and a factor of 2, respectively. These arrangement effects are a consequence of the variation in flow and drag characteristics of individual cylinders within the array. The arrangement effects become most critical in the intermediate range of flow blockage parameter $\mathit{\Gamma_{D}^{\prime}} = 0.5-1.5$ ($\mathit{\Gamma_{D}^{\prime}}=\overline{C_{d}}aD/(1-\phi)$, where a is frontal element area per unit volume, and $\phi$ is solid volume fraction), due to the high variability in element-scale flow characteristics. Across the full range of arrangements modelled, it is confirmed that the bulk velocity is governed by flow blockage parameter but only if the drag coefficient incorporates arrangement effects. Using these results, this paper proposes a framework for describing and predicting flow through an array across a variety of arrangements.

Mixing describes the process by which solutes evolve from an initial heterogeneous state to uniformity under the stirring action of a fluid flow. Fluid stretching forms thin scalar lamellae that coalesce due to molecular diffusion. Owing to the linearity of the advection–diffusion equation, coalescence can be envisioned as an aggregation process. Here, we demonstrate that in smooth two-dimensional chaotic flows, mixing obeys a correlated aggregation process, where the spatial distribution of the number of lamellae in aggregates is highly correlated with their elongation, and is set by the fractal properties of the advected material lines. We show that the presence of correlations makes mixing less efficient than a completely random aggregation process because lamellae with similar elongations and scalar levels tend to remain isolated from each other. We show that correlated aggregation is uniquely determined by a single exponent that quantifies the effective number of random aggregation events. These findings expand aggregation theories to a larger class of systems, which have relevance to various fundamental and applied mixing problems.

It is known that the dispersion of colloidal particles in porous media is determined by medium structure, pore-scale flow variability and diffusion. However, much less is known about how diffusiophoresis, that is, the motion of colloidal particles along salt gradients, impacts large-scale particle dispersion in porous media. To shed light on this question, we perform detailed pore-scale simulations of fluid flow, solute transport and diffusiophoretic particle transport in a two-dimensional hyper-uniform porous medium. Particles and solute are initially uniformly distributed throughout the medium. The medium is flushed at constant flow rate, and particle breakthrough curves are recorded at the outlet to assess the macroscopic effects of diffusiophoresis. Particle breakthrough curves show non-Fickian behaviour manifested by strong tailing that is controlled by the diffusiophoretic mobility. Although diffusiophoresis is a short-time, microscopic phenomenon owing to the fast attenuation of salt gradients, it governs macroscopic colloid dispersion through the partitioning of particles into transmitting and dead-end pores. We quantify these behaviours by an upscaled analytical model that describes both the retention and release of colloids in dead-end pores and the observed long-time tailings. Our results suggest that diffusiophoresis is an efficient tool to control particle dispersion and filtration through porous media.