High-redshift quasars provide a unique glimpse into the early evolution of massive galaxies. The physical processes that trigger major bursts of star formation in quasar host galaxies (mergers and interactions) probably also funnel gas into the central regions to grow the super-massive black holes (SMBHs) and ignite the luminous quasar phenomenon. The globally dense environments where this occurs were probably also among the first to collapse and manufacture stars in significant numbers after the big bang. Measurements of the elemental abundances near quasars place important constraints on the nature, timing and extent of this star formation. A variety of studies using independent emission and absorption line diagnostics have shown that quasar environments have gas-phase metallicities that are typically a few times solar at all observed redshifts. These results are consistent with galaxy evolution scenarios in which large amounts of star formation (e.g., in the central regions) precede the visibly bright quasar phase. An observed trend for higher metallicities in more luminmous quasars (powered by more massive SMBHs) is probably tied to the well-known mass–metallicity relation among ordinary galaxies. This correlation and the absence of a trend with redshift indicate that mass is a more important parameter in the evolution than the time elapsed since the big bang.

We investigate the metallicity of the narrow line regions (NLRs) of high-z radio galaxies (HzRGs), using new deep optical spectra of 9 HzRGs obtained with FORS2 on VLT and data from the literature. To estimate the metallicity of NLRs we focus on the Civ/Heii and Ciii]/Civ flux ratios. Based on comparison between the observed emission-line flux ratios and the prediction of our photoionization model calculations, we find no significant metallicity evolution in NLRs of HzRGs, up to z ~ 4. We discuss the possibility that massive galaxies had almost completed the major epoch of the star formation in the very high-z universe (z > 5).

We have gathered a representative sample of 88 intermediate mass galaxies at z~0.6 and have provided robust estimates of their gas phase metallicity based on the strong line method R23. We have found that these galaxies have undergone a strong evolution of their metal content during the last 8 Gyrs. We confirmed the shift about ~0.3dex to lower abundance of the M-Z relation at z~0.6 found by Liang et al. 2006. This result shows that the evolution of the gas phase is still active down to z=0.4 and that the close box model is not a valid scenario for local spiral progenitors.

We present two ongoing studies of gas phase abundances around high redshift quasars. First, we examine broad emission line (BEL) metallicities for 29 quasars with 2.3 < z < 4.6 and far-infrared (far-IR) luminosities (LFIR) from 1013.4 to ≤ 1012.2 L⊙, corresponding to star formation rates (SFRs) of 6740 to ≤ 1360 M⊙ yr−1. Quasar samples sorted by LFIR might represent an evolutionary sequence if SFRs in quasar hosts generally diminish across quasar lifetimes. We create three composite spectra from rest-frame ultra-violet Sloan Digital Sky Survey spectra with increasing far-IR luminosity. We measure the N V(λ1240)/C IV(λ1550) and Si IV(λ1397)+O IV](λ1402)/C IV(λ1550) emission line flux ratios for each composite and find uniformly high (~5-10 times solar) metallicities for the three composites, and no evidence for changes in metal enrichment with changes in ongoing SFR. Second, we present preliminary results from the largest ever survey of high resolution associated absorption line (AAL) region metallicities and physical properties in a sample of high redshift (z > 3) quasars. This includes five quasars with previously known AALs at z > 4 and two well measured z ~3 quasars with unusually rich absorption spectra. We determine well-constrained metallicities of about twice solar for five AAL systems. We find a range of lower limits for AAL metallicities in the z > 4 quasars from 1/100ths solar to 3 times solar. Overall, these results for typically super-solar gas-phase metallicities near quasars are consistent with evolutionary schemes where the major episodes of star formation in the host galaxies occur before the visibly luminous quasar phase. High SFRs (comparable to ULIRGs) in the host galaxies are not clearly linked to younger or chemically less mature quasar environments.

During the latest decades the number of papers on stellar chemical abundances has increased dramatically. This is basically reflecting the very great achievements in telescope- and spectrometer-construction technology. The analysis of the resulting stellar spectra, however, is still not up to the standard that is offered by the observational methods. Recent significant advances in the analysis methods (i.e., in constructing model atmospheres and model spectra to compare with the observed ones) is reviewed with the emphasis on the application to abundance analysis of late-type stars. It is found that the very considerable progress that have been made beyond mixing-length convection and LTE is a major break-through for physically consistent modeling. Still, however, further steps must be taken, in particular for the cooler stars, before the situation is fully satisifactory.

Non-local thermodynamic equilibrium (NLTE) line formation for neutral and singly-ionized iron is considered through a range of stellar parameters characteristic of cool stars. A comprehensive model atom for Fe I and Fe II is presented. Our NLTE calculations support the earlier conclusions that the statistical equilibrium (SE) of Fe I shows an underpopulation of Fe I terms. However, the inclusion of the predicted high-excitation levels of Fe I in our model atom leads to a substantial decrease in the departures from LTE. As a test and first application of the Fe I/II model atom, iron abundances are determined for the Sun and four selected stars with well determined stellar parameters and high-quality observed spectra. Within the error bars, lines of Fe I and Fe II give consistent abundances for the Sun and two metal-poor stars when inelastic collisions with hydrogen atoms are taken into account in the SE calculations. For the close-to-solar metallicity stars Procyon and β Vir, the difference (Fe II - Fe I) is about 0.1 dex independent of the line formation model, either NLTE or LTE. We evaluate the influence of departures from LTE on Fe abundance and surface gravity determination for cool stars.

We present solar photospheric abundances for 12 elements from optical and near-infrared spectroscopy. The abundance analysis was conducted employing 3D hydrodynamical (CO5BOLD) as well as standard 1D hydrostatic model atmospheres. We compare our results to others with emphasis on discrepancies and still lingering problems, in particular exemplified by the pivotal abundance of oxygen. We argue that the thermal structure of the lower solar photosphere is very well represented by our 3D model. We obtain an excellent match of the observed center-to-limb variation of the line-blanketed continuum intensity, also at wavelengths shortward of the Balmer jump.

Thermohaline mixing has been recently identified as the dominating process that governs the photospheric composition of low-mass bright giant stars (Charbonnel & Zahn 2007). Here we present the predictions of stellar models computed with the code STAREVOL taking into account this mechanism together with rotational mixing and atomic diffusion. We compare our theorical predictions with recent observations and discuss how the corresponding yields for 3He are compatible with the observed behaviour of this light element in our Galaxy.

We compare the abundances of various chemical species as derived with 3D hydrodynamical and classical 1D stellar atmosphere codes in a late-type giant characterized by Teff =3640 K, log g = 1.0, [M/H]= 0.0. For this particular set of atmospheric parameters the 3D–1D abundance differences are generally small for neutral atoms and molecules but they may reach up to 0.3–0.4 dex in case of ions. The 3D–1D differences generally become increasingly more negative at higher excitation potentials and are typically largest in the optical wavelength range. Their sign can be both positive and negative, and depends on the excitation potential and wavelength of a given spectral line. While our results obtained with this particular late-type giant model suggest that 1D stellar atmosphere models may be safe to use with neutral atoms and molecules, care should be taken if they are exploited with ions.

We present measurements of equivalent widths of the UV, presumably photospheric lines: C III 1247 Å, N III 1748 Å, N III 1752 Å, N IV 1718 Å and He II 1640 Å in high-resolution IUE spectra of 24 galactic OB supergiants. Equivalent widths measured from the observed spectra have been compared with their counterparts in the Tlusty NLTE synthetic spectra. We discuss possibilities of static plan-parallel model to reproduce observed UV spectra of hot massive stars and possible reasons why observations differ from the model so much.

We present selected results from an investigation that is currently underway to determine the abundances of the Fe group elements in early B stars and assess the extent to which contemporary NLTE and LTE models represent their atmospheres. High resolution UV and optical spectra of B stars that display ultrasharp lines are compared with computations from TLUSTY/SYNSPEC and SYNTHE. Some results from our analysis of the abundance standard ι Her (B3V) are presented here.

We combine results from interferometry, asteroseismology and spectroscopic analyses to determine accurate fundamental parameters (mass, radius and effective temperature) of 10 bright solar-type stars covering the H-R diagram from spectral type F5 to K1. Using “direct” techniques that are only weakly model-dependent we determine the mass, radius and effective temperature. We demonstrate that model-dependent or “indirect” methods can be reliably used even for relatively faint single stars for which direct methods are not applicable. This is important for the characterization of the targets of the CoRoT and Kepler space missions.

As the least massive galaxies we know, dwarf spheroidal galaxies (dSph) allow to probe chemical enrichement on the smallest scales, and perhaps in its simplest expression. Particularly interesting are the issues concerning the efficency with which metals are retained or lost in these shallow potential wells (supernovae feedback), and the effect of this on star formation itself. Another fundamental issue concerns the earliest epochs of star formation: are first stars formed in similar ways and proportions in all halos ? Finally, as the smallest galaxies know, dSph have been suggested to be the surviving cousins of galaxy building blocs that (in λ-CDM) assemble to make larger galaxies. This parenthood would not necessarily hold at all late times, when survivors have lived their own differentiated life, but is expected at least at the earliest epochs.

I review here the chemical abundances of individual stars in the nearest dwarf spheroidal galaxies, that have become available in increasing numbers (sample size and galaxies probed) in the last decade. Special emphasis is given to: a) recent results obtain with FLAMES on VLT, highlighting the power of detailed chemical abundance patterns of large samples of stars to unravel the various evolutionnary paths followed by dSph; b) the oldest and most metal-poor populations in dSph.

Our knowledge about the chemical evolution of the more luminous dwarf spheroidal (dSph) galaxies is constantly growing. However, little is known about the enrichment of the ultrafaint systems recently discovered in large numbers in large Sky Surveys. Low-resolution spectroscopy and photometric data indicate that these galaxies are predominantly metal-poor. On the other hand, the most recent high-resolution abundance analyses indicate that some of these galaxies experienced highly inhomogenous chemical enrichment, where star formation proceeds locally on the smallest scales. Furthermore, these galaxy-contenders appear to contain very metal-poor stars with [Fe/H]< −3 dex and could be the sites of the first stars. Here, we consider the presently available chemical abundance information of the (ultra-) faint Milky Way satellite dSphs. In this context, some of the most peculiar element and inhomogeneous enrichment patterns will be discussed and related to the question of to what extent the faintest dSph candidates and outer halo globular clusters could have contributed to the metal-poor Galactic halo.

We have obtained new spectrophotometric data for 28 Hii regions in the spiral galaxy NGC 300, a member of the nearby Sculptor Group. The detection of several auroral lines has allowed us to measure electron temperatures and direct chemical abundances for the whole sample. We determine for the first time in this galaxy a radial gas-phase oxygen abundance gradient based solely on auroral lines. The gradient corresponds to −0.077±0.006 dex kpc−1, which agrees very well with the galactocentric trend in metallicity obtained for 29 B and A supergiants in the same galaxy. The intercept of the regression for the nebular data virtually coincides with the intercept obtained from the stellar data. This result provides increased confidence on the direct method to determine extragalactic nebular abundances.

We present Keck/HIRES spectra of six metal-poor stars in two of the ultra-faint dwarf galaxies orbiting the Milky Way, Ursa Major II and Coma Berenices, and a Magellan/MIKE spectrum of a star in the classical dwarf spheroidal galaxy (dSph) Sculptor. Our data include the first high-resolution spectroscopic observations of extremely metal-poor stars ([Fe/H] < −3.0) not belonging to the Milky Way (MW) stellar halo field population. We obtain abundance measurements and upper limits for up to 26 elements between carbon and europium. The stars span a range of −3.8 < [Fe/H] < −2.3, with the ultra-faints having large spreads in Fe. A comparison with MW halo stars of similar metallicity reveals substantial agreement between the abundance patterns of the ultra-faint dwarf galaxies and Sculptor and the MW halo for the light, α and iron-peak elements (C to Zn). This agreement contrasts with the results of earlier studies of more metal-rich stars (−2.5 ≲[Fe/H]≲ −1.0) in more luminous dwarfs, which found significant abundance discrepancies with respect to the MW halo data. The abundances of neutron-capture elements (Sr to Eu) in all three galaxies are extremely low, consistent with the most metal-poor halo stars, but not with the typical halo abundance pattern at [Fe/H]≳ −3.0. Our results are broadly consistent with a galaxy formation model which predicts that massive dwarf galaxies are the source of the metal-rich component ([Fe/H]≳ −2.5) of the MW inner halo, but we propose that dwarf galaxies similar to the dSphs are the primary contributors to the metal-poor end of the metallicity distribution of the MW outer halo.

We present the results of a study of the very high velocity (υrad = +448.0 ± 1.0 kms−1) low-metallicity ([Fe/H] = −1.93) star Feh-Duf ((Fehrenbach & Duflot 1981) showing peculiar chemical abundance. Using high-resolution spectrum, we showed that this star has enhanced carbon and heavy s-process element abundance ([C/Fe] = +0.58, [hs/Fe] = +0.88 dex) while the [Y/Fe] = −0.07 dex). The carbon isotopic ratio is low (12C/13C=8). We found that oxygen abundance is reduced ([O/Fe] = +0.10 dex) as compared with Galactic field stars of a similar metallicity. The evolution state of this star and its possible extragalactic origin are discussed.

We present a detailed study of the physical properties of the nebular material in multiple knots of the blue compact dwarf galaxy Haro 15. Using long slit and echelle spectroscopy, obtained at Las Campanas Observatory, we study the physical conditions (electron density and temperature), ionic and total chemical abundances of several atoms, reddening and ionization structure. The latter was derived by comparing the oxygen and sulphur ionic ratios to their corresponding observed emission line ratios (the η and η' plots) in different regions of the galaxy. Applying direct and empirical methods for abundance determination, we perform a comparative analysis between these regions.

The evolution of Fe-peak elements of several Local Group Dwarf Spheroidal Galaxies are discussed based on the comparison between a chemical evolution model and obsevations. In our scenario, the evolution of these galaxies are mainly controlled by a low star formation efficiency coupled with very intense galactic winds. The low star formation rate gives rise to the observed low metallicities and to [alpha/Fe] and [s/Fe] ratios below solar, whereas the intense galactic winds are responsible for the sharp decrease observed in several abundance ratios. The shape of the stellar metallicity distributions are defined by both parameters and the observed data cannot be reproduced without evoking galactic winds. The same scenario applied to a standard model fits very well several Fe-peak elements, with different nucleosynthesis prescriptions for each set of elements.

The distribution of chemical abundances and their variation in space and time are important tools to understand the chemical evolution of disks in spiral galaxies. In this work we present an one infall chemical evolution model for the Galactic disk based on an updated version of the Trieste group model. We adopted a pre enriched gas (to take into account the effect of the halo evolution), an inside-out scenario for the formation of the disk and a threshold in the surface gas density to regulate the star formation rate. The observational constraints for the solar neighbourhood were well reproduced and the spatial and time evolution of the radial abundance gradient were studied. We also used this model to reproduce the chemical evolution of some nearby spiral galaxies. The model was scaled to the disk properties of each galaxy and its dependence with the star formation efficiency and the time scale for the infalling gas into the disk were explored. Using this modified model we were able to reproduce the observed constraints available in the literature for this galaxies. The similarities and the differences between the chemical evolution of these objects and teh Milky Way are discussed to provide a basis to the understanding of the chemical evolution of disks.