Let $\mathbb {F}_q$ be the finite field of q elements. In this paper, we study the vanishing behavior of multizeta values over $\mathbb {F}_q[t]$ at negative integers. These values are analogs of the classical multizeta values. At negative integers, they are series of products of power sums $S_d(k)$ which are polynomials in t. By studying the t-valuation of $S_d(s)$ for $s < 0$ , we show that multizeta values at negative integers vanish only at trivial zeros. The proof is inspired by the idea of Sheats in the proof of a statement of “greedy element” by Carlitz.

In this paper, we study transcendence theory for Thakur multizeta values in positive characteristic. We prove an analogue of the strong form of Goncharov’s conjecture. The same result is also established for Carlitz multiple polylogarithms at algebraic points.