Atmospheric acidic deposition introduces hydrogen ions to terrestrial and aquatic ecosystems, which become partially neutralized by chemical weathering. In the southern Alps of Switzerland, small catchments containing little or no soil and lacking carbonate minerals represent sensitive hydrological settings in which the relationship between alteration of granitic gneiss by acid deposition and the resulting composition of lake waters can be studied. Transmission and scanning electron microscopy, coupled with X-ray powder diffraction of lake sediments from such areas showed mainly unaltered minerals from parent rocks and no secondary silicate minerals. Element mapping indicated noncrystalline aluminum hydroxide as a product of the chemical weathering of silicates. Noncrystalline iron hydroxide was also observed. Mass balance calculations and the stoichiometry of suitable chemical reactions representing the weathering processes were used to derive a plausible reaction sequence on the interaction of the predominant reactive rock minerals with acid precipitation that accounted for the measured chemical composition of the acid lakes.

Halloysite and kaolinite occur in gneissic weathering profiles developed under a temperate climate in the Leucogia area of NE Greece. X-ray diffraction analyses of samples from three profiles of partially weathered gneisses have revealed that kaolinite becomes more abundant than halloysite with increasing intensity of the decomposition processes. To resolve the genetic relationship between halloysite and kaolinite, microtextures were examined by scanning electron microscopy using polished thin-sections and freshly exposed fracture surfaces, and their chemical compositions were determined using an analytical scanning electron microscope fitted with energy dispersive and wavelength dispersive spectrometers. Different morphological forms of halloysite and kaolinite were detected within the same rock mass. In the earliest stage of weathering, spheroidal aggregates consisting of microcrystalline halloysite are formed on the plagioclase surface. With progressive weathering, spheroidal halloysite converts to tubular halloysite. As weathering advances, tubular halloysite converts to platy halloysite, which in turn converts to kaolinite. Halloysite and kaolinite may coexist in the upper parts of the profiles. Electron microprobe analyses of spheroidal, tubular and platy halloysite and kaolinite show that the chemical composition of the various forms indicate a progressive Fe enrichment and Al depletion with advancing kaolinization, from VIFe0.08VIAl3.70 a.p.f.u. in spheroidal halloysite through VIFe0.29VIAl3.50 in platy halloysite to VIFe0.53VIAl3.32 in newly formed kaolinite. Final-stage, book-type kaolinite approaches its ideal chemical composition (VIFe0.04VIAl3.95). The mineralogy and composition of the kaolin minerals and the development of the various morphological forms of halloysite and kaolinite in different parts of the profiles are attributed to the chemistry of the ambient solutions. However, other physical and microenvironmental conditions (e.g. time and space available) also seem to have strong influence on the precipitation processes producing the morphological variations.

Zn-rich staurolite occurs in a pelitic gneiss from the Uvete area, central Kenya. The rock was metamorphosed to staurolite-kyanite grade during the Mozambique metamorphism. Microprobe analyses of the staurolite gave the following values (in wt. %): SiO2 26.2–27.3, Al2O3 52.4–53.5, FeO 8.3–9.2, MgO 2.2–2.6, and ZnO 6.0–7.5. Cell dimensions are a = 7.874(± 0.003), b = 16.620(±0.006), c = 5.656(±0.002) Å and β = 90.00 (± 0.002)°. Optical properties are 2Vz = 82–85°, α = 1.742 (±0.002), β = 1.747(±0.002) and γ = 1.753(±0.002). The optical dispersion is moderate and r > v. Density is 3.83(±0.01) g/cm3. Infra-red absorption spectra were also recorded. The cation correlation suggests that the principal substitutions in the staurolite are Zn ⇆ Fe in the tetrahedral sites in the hydroxide sheet and Al ⇆ Mg in the octahedral sites.

Clasts of metamorphosed Cadomian granites from the ∼50—60 Ma Carpathian flysch in Gródek near the Rożnowskie Lake (Silesian Unit, SE Poland) are studied. They are considered to represent the Silesian Ridge, one of the hypothetical, currently unexposed source areas that supplied Carpathian sedimentary basins with clastic material. The gneisses preserve several examples of corona textures that include cores of primary monazite surrounded by polygonal grains of secondary apatite with thorianite inclusions, with intermediate zones of lamellar grains of secondary monazite and outermost rims of clay minerals, or various combinations thereof. Preservation of the complete textures is rare with polygonal apatite with thorianite inclusions, lamellar grains of monazite and clay minerals being particularly prevalent. Locally, polygonal apatite with thorianite inclusions surrounded by allanite and REE-epidote corona with a bastnasite-synchysite phase occurs also. The textures observed developed during primary monazite breakdown and replacement by secondary minerals. The variation in reaction products indicates that alteration was strictly dependent on the local chemical system.

Titanomaghemite occurs in a relatively fresh doleritic intrusion in an area of Precambrian gneiss in Minas Gerais, Brazil. It hosts exsolution lamellae of ilmenite and contains more than 90% of the iron in the ferric form. It is more resistant to weathering than the ilmenite and is inherited virtually unaltered by the resulting soils. Titanomaghemite, extracted as grains from a weathered rind of the rock, has lattice parameter a0 = 0.8348(3) nm and has a canted spin structure due to substitution of non-magnetic ions on tetrahedral and octahedral sites of the spinel structure. The average canting angle is 32 ± 3° and canting occurs predominantly on the octahedral iron sublattice. Its formula, based on microprobe analysis and Mössbauer spectroscopy may be expressed as:

where [] and {} denote ions on tetrahedral and octahedral sites, respectively. The spontaneous magnetization of the mineral is 36(3) J/T/kg.

Coesite has been found as an inclusion in garnet from the Mengzhong eclogite in Donghai county, northeastern Jiangsu province, eastern China. The host eclogite occurs closely associated with regionally developed gneiss and was formed under P-T conditions of about 810°C and more than 28 kbar.

Amphibolite blocks from an Archaean (2.9 Ga) trondhjemite-agmatite complex in the Lewisian at Gruinard Bay have a varied trace element and REE content. Whilst some of the variability is attributable to element mobility during high-grade metamorphism and subsequent trondhjemite magmatism, it is for the main part considered to be a primary feature of the amphibolites. The observed trace element and REE chemistry is best explained in terms of source region heterogeneity and suggests a melting regime comparable with that beneath certain types of mid-ocean ridge. There are geochemical similarities between the amphibolites and the Lewisian layered gabbro-ultramafic complexes, and the two may represent the derivative liquid and associated cumulates respectively from a common parent magma. Thus there is a parallel between the processes which generated some Archaean amphibolites and layered gabbro complexes and those operating beneath modern ocean ridges. Hornblendite and amphibolite pods enclosed within tonalitic gneiss, also found as blocks in the agmatite complex, are geochemically distinct from the main group of amphibolites and are probably of calc-alkaline parentage.

Marine invertebrate borings are very rare in crystalline rocks, providing evidence of particular strategies producers use to colonise these unfavourable substrates. In the Sorbas Basin (Almería, southern Spain), Upper Miocene transgressive successions contain blocks of metamorphic and igneous rocks of the Nevado–Filabride Complex of the Betic Cordillera. Ichnological analysis of the embedded blocks shows the presence of two types of macroborings located in gneiss boulders, revealed to be an extraordinary case worldwide. The most abundant are regular hemispherical depressions ascribed reservedly to the well-known, mostly bivalve boring Gastrochaenolites. The second one is a pouch-like depression, tapering downward, elliptical in outline, and clearly different to other non-circular-in-outline, pouch-shaped macroborings. Thus, a new ichnogenus and ichnospecies Cuenulites sorbasensis has been defined. According to the overall shape, an endolithic or semi-endolithic bivalve using chemical means to bore is suggested as the tracemaker. Colonisation could be determined by sea-level coastal dynamics, with decreasing energy during advancing transgression allowing boring, which was then stopped due to supply of fine-grained sediment that killed the borers.

Composite Sensitive High Resolution Ion Microprobe (SHRIMP) U–Pb zircon and 40Ar–39Ar step-heating biotite-hornblende ages are used to provide constraints on the timing and origin of the felsic gneissic rocks in the Baiyunshan Mountains region and to elucidate their tectonothermal history. SHRIMP dating and CL imaging of zircons give magmatic zircon crystallization ages between Late Ordovician and Early Silurian (c. 453.5 Ma, 446 Ma, and 439 Ma) for three representative felsic gneisses, suggesting that most of the Baiyunshan gneiss cannot represent basement rocks of the Cathaysia Block as previously thought. Including the present age information, a synthesis of available age data for regional Wuyun (Wuyi-Yunkai) events reflects the emergence of orogen-wide magmatism that could be syn-orogenic and have occurred mainly between 460 and 420 Ma in the South China Block. Inherited zircons are abundant, with ages clustering at late Mesoproterozoic (1189–1017 Ma) and middle Mesoproterozoic (772 Ma), which reveals that the Baiyunshan orthogneiss samples a crustal basement containing significant igneous or recycled components related to the Rodinia amalgamation and break-up. A SHRIMP date of 212 ± 12 Ma from a white rim of zircon provides evidence for metamorphic overprinting of an Indosinian tectonothermal event on the Baiyunshan gneiss. Incremental heating experiments with six biotite samples and one hornblende sample from a variety of metamorphic rocks yielded two distinct 40Ar–39Ar age groups: 150–155 and 94–98 Ma. The older ages are similar to zircon U–Pb dates for widespread granitic intrusions in central Guangdong. We attribute them to Late Jurassic magmatism-induced thermal resetting of the biotite K–Ar system. On the other hand, the younger age group is interpreted to record either cooling through the biotite closure temperature of ~300–350 °C or a second resetting of biotite Ar isotopes at c. 94–98 Ma due to contemporaneous magmatic activity. Our present age data suggest that the Maofengshan orthogneiss was exhumed to 8 to 10 km crustal levels at c. 150 Ma, whereas the eastward components of gneissic rock masses appear to have passed upward through the same crustal depth synchronously or later (by c. 94 Ma). Exhumation of middle crustal-level rocks in the study area since c. 155 Ma is roughly coeval with exhumation of gneissic rocks from elsewhere in the Wuyun Orogen, suggesting a large-scale mechanism for the exhumation pulse related to the Yanshanian extensional tectonic regime.

Field observations involving landform evaluation and the physical characterization of sediments, combined with a detailed analysis of the spatial distribution of bedrock and sediment geochemical patterns, suggests a limit to the glacial transport half-distance of c. 3 km in Vestfold Hills. Four morphologically distinct glacial deposits were sampled (small debris ridges, large debris ridges, debris drapes and valley fills) on the basis of field geometry. These landforms were subsequently distinguished by grain size, mineralogy and geochemistry. Since there are no nunataks south of Vestfold Hills, all debris is derived subglacially and sedimentological differences are attributed to the physical weathering of preglacial surfaces in Vestfold Hills and fluvial winnowing during deposition. Given that thrust geometries may occur in large debris ridges, glacial transport distances were short, and fluvial sorting of sediments was an important mechanism, reconstructions of glacial histories based on the stratigraphy of deposits in Vestfold Hills should be made with caution.

Graphite bodies of economic importance occur in the Eastern Ghats migmatite complex of Orissa, India, which consists of sillimanite-rich gneiss (khondalite), calc-silicate granulite, basic (pyroxene) granulite and acidic gneiss palaeosomes and a variety of quartzofeldspathic neosomes and pegmatite veins. There is more graphite in migmatised khondalite and calc-silicate granulite than in their unmigmatised counterparts and it is common at pegmatite-country rock margins. Lodes of graphite are structurally controlled by fold hinge zones, necks of boudins and along the dominant foliation in rocks that show the effects of polyphase deformation. Faults, fractures and joints also act as structural controls. The richest lodes are located where there is the coincidence of several lithological and structural features.

The graphite occurs in graphite-rich schists and gneisses, as veins and as disseminated flakes along grain boundaries and in microfractures and cleavages. It is present in all rock types except pegmatites emplaced after the D4 deformational phase, and is localised in structures developed during the D1, D2, D3 and D4 phases. Most of the bodies of graphite are lenticular and show pinch and swell characters. Fourteen textural and microstructural habits have been recognised and are described with many of the features of fabric, such as intergrowths, inclusions and kinks being particularly well shown under reflected light.

Methanation of carbonate minerals is considered the most likely initial stage in the formation of the carbon with subsequent pyrolysis of the methane being the process of graphitisation. While the possibility of the carbon being either of sedimentary derivation orfrom igneous-derived CO2 cannot be ruled out, there is no convincing evidence for such sources. Remobilisation of graphite following its formation by pyrolysis of methane in structurally controlled low pressure zones is the dominant mechanism of concentration. Thefabric features point to the graphite having moved as a solid phase along open spaces inthe gangue minerals while still maintaining its crystallinity, and having been deformed in the process. The effects of remobilisation apparently have obliterated evidence relating to other methods of concentration.

For much of its length in eastern Finland, the contact between the late Archaean granitoid terrane and early Proterozoic supracrustal rocks is that of a depositional unconformity tectonically modified during the Svecokarelian orogeny. In the Kaavi district, this modification has been extensive, particularly because of thrusting which resulted in tectonic slices of basement being present as inliers within the cover rocks and cover rocks as outliers within the main basement outcrop. Both basement and cover have undergone repeated deformation and metamorphic recrystallisation reflected by the presence of multiple tectonic fabrics and sequential mineral growths. However, it is only locally in major zones of movement that the basement rocks of the Presvecokarelides show major modification as the result of the deformation which had such a profound effect on the cover rocks during the development of the Svecokarelides. Over large areas, the products of four phases of deformation (DI–IV) remain in the basement gneisses together with the products of basic and acidic intrusion whose positions in the deformational sequence can be established‥

In the cover rocks, early nappe emplacement (Outokumpu nappe) was followed by the development of isoclinal folds associated with prograde metamorphism (D1). Regionally expressed asymmetrical folds, overturned to the E, with attenuation of overturned limbs and thrusting, involving basement, followed (D2). Subsequent deformation related to wrench faulting (D2c) was followed by the development of more open folds associated with declining geotherms (D3, D4); F3–F4 interference structures are expressed as domes, some of which were a locus of granitoid emplacement (Maarianvaara granitoid suite). D5 and D6 are expressed as cleavages and fractures.

Correlation of the structural features in the Kaavi district with those in the Outokumpu and adjacent districts forms the basis both for establishing the regional disposition of basement and cover units and for determining the structural evolution of this part of the Svecokarelides.

Fourteen granitoid plutons studied in the Baie d'Espoir area of southern Newfoundland are divisible into a northern group of eight and a southern group of six. The former tend to be undeformed, have thermal aureoles, and intrude greenschist facies Ordovician and Silurian rocks of the Dunnage zone following a period of folding and thrusting towards the SE. Four Rb-Sr whole-rock isochrons yield similar ages around 430 Ma for these plutons, fixing the deformation within early Silurian times. The latter plutons syntectonically intruded without aureole effects, and are all foliated and elongate parallel to the regional fabric of amphibolite facies gneisses and migmatites of the Gander zone. Whole-rock Rb-Sr isochrons around 350 Ma for both syntectonic and post-tectonic plutons indicate a rapid metamorphism, deformation, intrusion and uplift of the Gander zone in this area. There appear to be no systematic relationships between petrological and geochemical characteristics of the plutons and their tectono-stratigraphic setting. This study conclusively invalidates earlier hypotheses that deformed granitoid rocks of the Gander zone are older than the undeformed granitoids of the Dunnage zone; indeed, just the reverse is true.

Basic granulites, a variety of gneisses including sillimanite-garnet gneiss (khondalite), charnockite and intruded quartzofeldspathic material make up a migmatite complex showing evidence of polyphase deformation, polymetamorphism and successive neosome emplacement. The heterogeneity of the migmatites is dominantly the result of folding and boudinage rather than igneous activity.

Tight to isoclinal folds of the second recognised deformational phase affect lithological layering, granulite facies fabric elements of the first deformational phase and early neosome; they played a major role in the development of the macroscopically heterogeneous nature of the complex and they are also a key structure for correlation. Upright folds of the third deformational phase control the major disposition of lithological units and, together with their axial planar fabric, controlled the uprise of quartzofeldspathic neosome and of volatiles and heat which caused localised ‘charnockitisation’ of sillimanite-bearing gneisses. The effects of semibrittle and brittle deformation, including kink bands, fractures and shears, express late deformational phases during which there was neosome emplacement, some at 854 ± 6 m.y. ago (Rb–Sr muscovite age).

U–Pb zircon and Rb–Sr whole-rock analyses from various gneisses and plutonie rocks of the Moldanubian and Moravo-Silesian zones and the stable foreland of the Hercynian (Variscan) orogenic belt indicate that most of the crust in Central Europe was first formed during the Cadomian orogeny which straddles the Precambrian–Cambrian boundary. Zircons, however, have a memory of older ages which correspond with those of events known in Fennoscandia. The new radiometrie data are consistent with the stratigraphie record in that they do not provide any evidence for a major early Palaeozoic tectonothermal event between the Cadomian and Hercynian orogenies.

Granulites from two localities in the Moldanubian zone yield U–Pb zircon ages of 345 ± 5 Ma; discordant zircon data points indicate that the granulite facies metamorphism was not of long duration. Tectonic units containing these high grade rocks were emplaced amongst amphibolite facies rocks during an event of widespread shearing which has been dated at 341 ± 4 Ma on the basis of a lower U–Pb zircon intercept age from one of the sheared gneisses and 338 ± 3 Ma U–Pb ages from monazites. Rb–Sr muscovite ages of 331 ± 5 Ma from pegmatites axial planar to asymmetrical folds date the last stage of SE-directed simple shear. A Rb–Sr whole-rock isochron of 331 ± 4 Ma from a principal magmatic type of the Central Bohemian pluton confirms the field evidence that the large NE-trending plutons of the Moldanubian zone were emplaced during a late stage of the deformation. The strong disturbance of the U–Pb zircon isotopic system in the sheared gneisses suggests U loss while a high U/Th ratio in monazite from one of these tectonised rocks suggests the simultaneous passage of hydrothermal fluids. Thus a crustal source is indicated for the uranium deposits of the Moldanubian zone.

Critical to any plate tectonic model for the development of the Middle European Hercynides was the existence of an ocean in Early Devonian times which separated a North European continent from a South European continent(s). The northward movement of the South European continent over a shallowly-dipping subduction zone and subsequent continental collision can explain the high T–low P metamorphism and the imbricated tectonic style of the Moldanubian zone and adjacent Moravo-Silesian zone along the southeastern Hercynian foreland. The temporal separation of granulites and granites implies distinct conditions of formation and it has been suggested that the plutonism, following on from the imbrication of the Cadomian crust, was initiated by the subduction of wet oceanic sediments.