Absorption and translocation of 14C-fluazifop-butyl {butyl ester of (±)-2-[4-[[5-(trifluoromethyl)-2-pyridinyl] oxy] phenoxy] propanoate} was compared in susceptible quackgrass [Agropyron repens (L.) Beauv. ♯3 AGRRE] and tolerant soybean [Glycine max (L.) Merr.]. Foliar absorption was more rapid in soybeans with 75% of the recovered 14C absorbed 6 h after treatment compared to 36% in quackgrass. Translocation of the radiolabel occurred in both soybean and quackgrass with no significant difference between the species. Differential absorption and translocation did not contribute to the selectivity of fluazifop-butyl. Herbicidal activity was lower on quackgrass plants at the five- to six-leaf stage when compared to the two- to three-leaf stage. Greater quackgrass control was observed at 30 than at 20 C. Foliar absorption of 14C-fluazifop-butyl was significantly greater at 30 than at 20 C. Translocation of the radiolabel was greater in plants exposed to full light as compared to shade. Moisture stress significantly reduced quackgrass control with fluazifop-butyl.

The herbicidal action of sethoxydim {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one} on corn (Zea mays L. ‘Goldencrossbantam’) was investigated in preemergence and postemergence experiments and hydroponic culture. Soil-applied sethoxydim did not inhibit corn germination. Leaves failed to emerge through the coleoptile with a high herbicide rate (1.6 kg ai/ha), but chlorotic leaves emerged at a lower rate (0.8 kg ai/ha). Growth of corn seedlings treated with a foliar application of 0.2 kg ai/ha was inhibited within 1 day after treatment, but at a lower application rate (0.05 kg ai/ha) growth continued with chlorotic zones on newly expanding leaves. Over the concentration range 3 × 10-5 to 1 × 10-6 M, sethoxydim inhibited the growth of primary roots of corn in hydroponic culture within 24 h. Cytological investigation showed that sethoxydim inhibited cell division but did not interfere with mitosis.

The influence of chlorsulfuron {2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl] benzenesulfonamide} on control of wild oat (Avena fatua L. ♯3 AVEFA) when mixed in the spray tank with three herbicides was tested in greenhouse and in field trials at Lacombe and Scott, Canada, during 1981 and 1982. In field experiments, chlorsulfuron mixed with diclofop {2-[4-(2,4-dichlorophenoxy)phenoxy]propanoic acid} caused a 4 to 35% reduction in control of wild oat. Mixtures of chlorsulfuron with difenzoquat (1,2-dimethyl-3,5-diphenyl-1H-pyrazolium) caused a 0 to 19% reduction and mixtures with flamprop {N-benzoyl-N-(3-chloro-4-fluorophenyl)-DL-alanine} a 2 to 30% reduction in control of wild oat. Addition of chlorsulfuron to the wild oat herbicides under greenhouse conditions also resulted in losses in control of wild oat. Increasing the rate of the wild oat herbicide in the mixture tended to overcome these losses.

Sicklepod (Cassia obtusifolia L. ♯ CASOB) was planted at six densities (0 to 39.4/m2) and six durations of competition (0 to 10 weeks after seeding) in lima beans (Phaseolus lunatus L. cv. ‘Jackson Wonder’). The yield of green lima beans was inversely proportional to the density of sicklepod. In general, weed densities at 2.7 to 10.8 sicklepod/m2 did not significantly reduce yields, but higher populations frequently did. The average yields generally decreased if the duration of competition exceeded six weeks.

Acifluorfen {5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid} applied 7 days after cowpea [Vigna unguiculata (L.) Walp.] emergence (unifoliolate leaf stage) gave better control than later applications. Cowpea control was obtained with one acifluorfen application at 7 days after cowpea emergence in 1981, but in 1980 and 1982, applications at 7 and 14 days were necessary for acceptable control (> 80%). Acifluorfen reduced cowpea plant dry weights relative to the weedy control. A single application 7 days after emergence reduced cowpea plant growth more than one at 21 days after emergence. Of all times of application, the greatest soybean [Glycine max (L.) Merr.] injury occurred when acifluorfen was applied at 7, 14, and 21 days after emergence, but seed yields were not reduced relative to the untreated weed-free control. There was no difference in response among three weedy cowpea cultivars to acifluorfen.

Clear and black polyethylene mulches were placed over raised seed beds in four studies during a 3-yr period. At intervals during treatment times of up to 12 weeks, soil samples were taken and the recovered seed were tested for germination. The number of seed killed and depths to which they were killed varied with species. The study included natural seed populations of annual bluegrass (Poa annua L. ♯3 POAAN), barnyardgrass (Echinochloa crus-galli (L.) Beauv. ♯ ECHCG), annual species of Cyperus, dayflower (Commelina communis L. ♯ COMCO), and goosegrass (Eleusine indica L. Gaertn. ♯ ELEIN). After 40 days exposure under clear mulch, seed of dayflower were killed to a depth of 11 cm. Under the same conditions, seed of annual Cyperus sedges and barnyardgrass were killed only in the upper 3 to 4 cm. After 3 weeks under clear plastic, germinable seed of goosegrass were recovered only at depths greater than 5 cm. Seed in plots under clear polyethylene mulch were killed more quickly than those in plots covered with black polyethylene mulch.

The objective of this investigation was to determine if preemergence herbicides, applied at the standard rates and times for smooth crabgrass [Digitaria ischaemum (Schreb.) Muhl. ♯ DIGIS] control, would provide season-long control of goosegrass [Eleusine indica (L.) Gaertn. ♯ ELEIN] in the transition zone. The transition zone is a unique area of turfgrass culture between cool and warm regions where quality of turfgrasses frequently declines due to environmental stresses. Single and sequential applications of bensulide [O,O-diisopropyl phosphorodithioate S-ester with N-(2-mercaptoethyl)benzenesulfonamide] and DCPA (dimethyltetrachloroterephthalate) did not effectively control goosegrass in any of the three test years. Benefin (N-butyl-N-ethyl-α,α,α-trifluoro-2,6-dinitro-p-toluidine) usually required sequential dosages to provide good (90%) to excellent (95%) goosegrass control. Nearly all rates of oxadiazon [2-tert-butyl-4(2,4-dichloro-5-isopropoxyphenyl)-δ2-1,3,4-oxadiazolin-5-one] used provided good to excellent goosegrass control. Napropamide [2-(α-naphthoxy)-N,N-diethylpropionamide] plus bensulide provided excellent goosegrass control in 1981, but not in 1982. Pendimethalin [N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzenamine] also provided effective goosegrass control.

Pretreatment of etiolated cucumber cotyledons with potassium (K), benzyladenine (BA), or δ-aminolevulinic acid (ALA) for 20 h in the dark, followed by exposure to light for 24 h, increased chlorophyll and carotenoid content. A similar treatment with fluridone {1-methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl]-4(1H)-pyridinone} decreased the levels of these photosynthetic pigments. However, when the etiolated cotyledons were pretreated with either BA or ALA for 20 h in the dark, followed by fluridone during a 24-h light period, the inhibitory effects of fluridone on chlorophyll content were reversed and the values were higher than the controls. In these treatments, ALA did not counteract the inhibitory effects of fluridone on carotenoids, but BA reduced the effects. In the cucumber cotyledon greening system, K was found to be most effective in stimulating both chlorophyll and carotenoid accumulation. When K was administered to the cotyledons either together with, prior to, or after the fluridone treatment, the inhibitory effect of fluridone on chlorophyll accumulation was totally eliminated and the stimulatory effects due to K were still maintained. Although K increased carotenoid content, it did not reverse the inhibitory effect of fluridone on carotenoids. From these findings it is concluded that the inhibition of chlorophyll and carotenoid accumulation by fluridone may be mediated via unrelated mechanisms at fluridone concentrations that do not totally eliminate or drastically reduce carotenoid content.

Three annual applications of glyphosate [N-(phosphonomethyl)glycine] with three ropewick applicators were compared to hoeing and cultivation for the control of johnsongrass [Sorghum halepense (L.) Pers. ♯3 SORHA] in cotton (Gossypium hirsutum L. ‘Acala SJ-2′) in 1980 and 1981. The three applicators provided about equal control of johnsongrass. Averaged over treatments, years, and dates of application, plots treated with glyphosate contained 83% fewer live johnsongrass shoots (14/m2) than cultivated control plots (84/m2) 2 to 3 weeks after each application. Glyphosate-treated plots yielded an average of 81% more seed cotton (2010 kg/ha) than cultivated control plots (1110 kg/ha). However, yields of treated plots averaged 33% less than plots maintained weed-free by hoeing. Although applications of glyphosate reduced johnsongrass populations 83%, the competitive effect of johnsongrass on cotton prior to the initiation of treatments, plus the competition from escape plants between treatments, prevented cotton from yielding normally.

The phytotoxicity of difenzoquat (1,2-dimethyl-3,5-diphenyl-1H-pyrazolium) applied to the three-leaf stages of hard red spring wheat (Triticum aestivum L. ‘Waldron’ and ‘Era’), barley (Hordeum vulgare L. ‘Beacon’) and wild oat (Avena fatua L. ♯ AVEFA) grown under constant, fluctuating, or alternating day-night temperatures was determined in controlled environment chambers. Difenzoquat injury to wild oat and Era wheat was greater at a constant 20 or 30 than at 10 C; however, injury to Waldron wheat was similar at 10, 20, and 30 C. Difenzoquat caused only slight injury to barley, and injury was similar at all temperatures. In Era wheat, selectivity of difenzoquat for wild oat was maximum with a 10-C night temperature in an otherwise 30-C-temperature environment; in Beacon barley selectivity was maximum with 3 or more days of 20- or 30-C posttreatment temperature; and in Waldron wheat selectivity was not adequate at any of the temperatures studied.

Downy brome (Bromus tectorum L. # BROTE) has developed into a severe weed in several agricultural production systems throughout North America, particularly on rangeland and in winter wheat (Triticum aestivum L.). Several million hectares of winter wheat, pastureland, alfalfa (Medicago sativa L.), grass seed fields, and overgrazed rangeland, as well as other crops, have been invaded by this annual grass since its introduction into this hemisphere. Downy brome is most abundant in the Great Basin and Columbia Basin areas of the western United States, but is found throughout the continental United States and parts of Canada and Mexico. In some cases, the vegetation on overgrazed rangeland consists totally of downy brome, while winter wheat growers in the western United States proclaim it as their worst weed problem. Changes in tillage practices that are currently being implemented for the control of soil erosion coupled with the lack of selective herbicides for the control of downy brome have aided its increase and spread.

Chlorpropham (isopropyl m-chlorocarbanilate) at 6.7 kg ai/ha controlled a mixture of field dodder (Cuscuta campestris Yunck. ♯3 CVCCA) and largeseed dodder (Cuscuta indecora Choisy ♯ CVCIN) for 3.0 and 4.3 weeks in two greenhouse experiments. The insecticide carbaryl (1-naphthyl N-methylcarbamate) at 0.8 kg ai/ha applied with chlorpropham extended control by 0.7 and 1.8 weeks, and PCMC (p-chlorphenyl N-methylcarbamate) at 0.8 kg ai/ha extended it by 2.7 and 2.8 weeks. Both additives also improved dodder control by chlorpropham in the field, with carbaryl having less effect than PCMC.

Phytotoxicity of fluazifop-butyl {butyl 2-[4-[(5-trifluoromethyl)-2-pyridinyl)oxy] phenoxy] propanoate}, haloxyfop-methyl {methyl 2-[4-[(3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy] propanoate}, and sethoxydim {2-[1-ethoxyimino)-butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one} increased as carrier volume was decreased from 570 to 24 L/ha. Addition of crop oil concentrate to the spray solution increased phytotoxicity, especially at carrier volumes of 190 L/ha and above. Sorghum plants were treated with the same amount of active ingredient in a single 1-, 2-, 4-, 8-, 16-, or 24-μl droplet. Smaller, more concentrated droplets were more phytotoxic than larger, more dilute droplets, with or without crop oil concentrate. Application site of single herbicide droplets also influenced phytotoxicity. In general, application of concentrated droplets to metabolically active leaf tissue resulted in maximum phytotoxicity.

When applied in early February, simazine [2-chloro-4,6-bis(ethylamino)-s-triazine], pronamide [3,5-dichloro-(N-1,1-dimethyl-2-propynyl)benzamide], secbumeton [N-ethyl-6-methoxy-N′-(1-methylpropyl)-1,3,5-triazine-2,4-diamine], and metribuzin [4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one] effectively removed weedy Bromus species from established alfalfa (Medicago sativa L.) and increased yields of alfalfa forage. Diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea], terbacil (3-tert-butyl-5-chloro-6-methyluracil), and hexazinone [3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine- 2,4(1H,3H)-dione] had no adverse effects on yields of alfalfa when applied in late March. Paraquat (1,1′-dimethyl-4,4′-bipyridinium ion) was somewhat less effective for controlling weeds when applied in late March than when applied in February. When applied to weed-free stands of alfalfa after dormancy was broken, metribuzin, terbacil, hexazinone, and simazine, but not pronamide, significantly reduced yields of alfalfa. Terbacil applied immediately after the first cutting did not significantly reduce yields of the second cutting. Terbacil and bentazon [3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide] applied when alfalfa had 5 cm of regrowth significantly reduced yields.

Dicamba (3,6-dichloro-o-anisic acid), 2,4-D [(2,4-dichlorophenoxy)acetic acid], 2,4,5-T [(2,4,5-trichlorophenoxy)acetic acid], 3,6-dichloropicolinic acid, picloram (4-amino-3,5,6-trichloropicolinic acid), triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid}, tebuthiuron {N-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-N,N′-dimethylurea}, and hexazinone [3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] were applied at rates of 0.3, 0.6, 1.1, and 2.2 kg/ha pre- and postemergence to greenhouse-grown common buffelgrass (Cenchrus ciliaris L. ♯3 PESCI). Buffelgrass tolerated preemergence sprays of 3,6-dichloropicolinic acid up to and including 1.1 kg/ha. All other treatments except picloram and 2,4,5-T at 0.3 kg/ha were phytotoxic to emerging buffelgrass. Buffelgrass tolerated early postemergence applications of 2,4-D, picloram, and tebuthiuron at 0.3 kg/ha; dicamba and 2,4,5-T at 0.6 kg/ha; and 3,6-dichloropicolinic acid at 2.2 kg/ha based on oven-dry shoot production 1 month after treatment. Regrowth of buffelgrass from stubble 1 month after original harvest of the early postemergence treatment occurred only with all rates of 3,6-dichloropicolinic acid and 2,4,5-T at 0.3 kg/ha. When treated at 45 days after planting, buffelgrass tolerated dicamba, 2,4-D, 2,4,5-T, 3,6-dichloropicolinic acid, and picloram at 2.2 kg/ha, but top growth production was significantly reduced by most rates of hexazinone and tebuthiuron. Relative differences in regrowth of buffelgrass 1 month after the original harvest were similar to those of the original harvest. Mature buffelgrass (90 or 150 days old) responded similarly to herbicides as the 45-day-old buffelgrass.

Downy brome (Bromus tectorum L. # BROTE), also known as cheatgrass, downy chess, broncograss, Mormon oats, and junegrass, was introduced into the United States from Europe, apparently during the middle of the nineteenth century (11, 21). According to Mack (23), downy brome entered British Columbia, Washington, and Utah around 1890; and by 1928 it had reached its present range, occupying much of the perennial grassland in Washington, Idaho, Oregon, Nevada, Utah, and British Columbia. Today, downy brome is a widespread weed throughout most of Canada, Mexico, and the United States, except for the southeastern United States (5, 17). Some consider downy brome to be an important forage because it provides most of the early spring grazing for livestock in western United States rangeland (21). However, it is also considered a troublesome weed in rangeland (31), winter wheat (Triticum aestivum L.) (27), several other crops (29), and noncropland (32).