Current research indicates that full-fledged Neolithic societies emerged in the Southern Caucasus in the early sixth millennium BC, most likely through interaction with and/or the immigration of the Neolithic societies of Southwest Asia. However, the absence of late seventh millennium BC excavated sites has prevented us from being able to interpret the processes in relation to earlier indigenous foraging societies. The 2016–2019 excavations at Damjili Cave, west Azerbaijan, revealed a stratified cultural sequence of the key Mesolithic-to-Neolithic transition period for the first time. Its radiocarbon chronology identified a rather abrupt emergence of the Neolithic economy at around 6000 cal BC, at least in the study region, urging a reconsideration of the long-standing claim that some other form of earlier Neolithic society had existed before this. At the same time, the stratigraphic analysis of cultural remains revealed continuity in certain elements of tool manufacturing and use from the Mesolithic to the Neolithic. This complex situation shows the need for evaluating the degree to which indigenous foraging societies contributed to the Neolithization of the Southern Caucasus, rather than focusing merely on immigration models.

This date list mainly reports on samples processed from 1982 to 1991. Each sample is converted to methanol. Radiocarbon is measured in a Teflon™ vial containing a mixture of 40 g of methanol and 50 cc of xylene, 1% Butyl PBD and 0.1% PBBO using low-background scintillation counters Aloka LSC-800, LB-I and LB-III. The background of LB-III is ca. 8 cpm and counting efficiency is ca. 70%. The recent 14C standard used is 95% of NBS oxalic acid; 5568 yr is used as the half-life of 14C.

In 2008–2009, during construction of the ring road around the town of Sztabin in NE Poland, archaeological rescue excavations were carried out at site no. 12 in Horodnianka. The excavations revealed the remains of a defensive settlement from the Bronze Age, with a total surface of 3 ha. Concentric wooden palisades reinforcing the settlement were situated on sandy, elevated embankments of the Biebrza River. Altogether, 189 samples of archaeological wood, mainly oak (Quercus sp.), were collected. Dendrochronological analysis demonstrated that the trees were cut down within a relatively short period of only 22 yr. On the basis of 22 contemporaneous dendrochronological sequences, the average curve HOR_AA1 (89 yr long) was constructed. However, attempts at dating the average curve against the chronologies from adjacent areas were unsuccessful. Therefore, determination of the time interval represented by the palisade oaks was attempted with the wiggle-matching method. Radiocarbon dating using liquid scintillation counting (LSC) was conducted for 6 suitable samples selected from the average curve. The 14C results, after calibration, suggest the dates of cutting the oaks outlining the Horodnianka chronology most probably fall in the time interval 870–795 cal BC. This means that Horodnianka could be the furthest northeastern defensive fortification of the Lusatian culture.

We present case studies on three objects of high importance for cultural heritage in southern Poland, dated in years 2018–2022 at the Gliwice 14C and Mass Spectrometry Laboratory with radiocarbon (14C) and dendrochronology methods. The first was a richly ornamented wooden cane, discovered during excavations on the market in Bytom city. The cane can be associated with medieval court proceedings. The archaeological context indicates the 13th century AD, and the 14C result corresponds perfectly with this time, confirming that it is the oldest object of this type in Poland. The second was a 4-m-tall oak column from St. Leonard Church in Lipnica Murowana, a UNESCO heritage site. The local story said it was previously devoted to Światowid, a pagan deity. Our analysis excluded the pre-Christian age, as the tree was felled no earlier than the late 15th century, which is in agreement with historical records. The third was a wooden Saint Lawrence Church in Bobrowniki. The presbytery was covered with up to five layers of polychromic paintings, some of high artistic value. We dated three samples from the original wooden board, and by wiggle-matching, the calibrated age interval was narrowed to 1731–1754 cal AD.

This list reports certain measurements made from 1965 to 1967. These samples are devoted to a special study of organic matter in soils. The work in large part is the subject of a thesis defended in Paris by S. M. Nakhla, 1968.

During a rainfall event in early September 2006, the transport behavior of particulate organic carbon (POC) in a small river (Teshio River, northern Japan) with alluvial plain and forest characteristics was investigated chiefly with carbon isotopes. The radiocarbon (Δ14C value) of POC varied widely from –56%‰ at the beginning of the rain event to –10%‰ at peak rainfall. The Δ14C values have a positive correlation with C/N ratios and a negative correlation with Δ13C values except for the data from when both turbidity and water level were at their maximums due to rainfall. These results indicate that the sources of organic matter in the river come from the surface layer of soil as the water level rises during a rainfall event.

A Bayesian multiple-frequency model has been developed for spectral analysis of data with unknown correlated noise. A description of the model is given and the method is applied to decadal atmospheric INTCAL98 Δ14C data. The noise of the INTCAL98 data is found to be red, and there seems to be no support for continuous harmonic frequencies in the data.

Radiocarbon measurements in this list were made from Sept. to Dec., 1968. They are based on acetylene counting in an Oeschger-Houtermans-type proportional counter (1 L) at pressure 1 atm. All data are based on duplicated measurements. For calculation of ages, 95% activity of NBS oxalic acid is used as the modern standard and value of 5570 + 30 years is used for the half-life of C14. Dates are expressed in years B.P. (before A.D. 1950). Error corresponds to 1σ deviation of sample net counting rate as well as modern standard and background. Details of procedures are given in previous reports (R., 1968, v. 10, p. 144–148; 1969, v. 11, p. 509–514)

This list includes mainly the results of datings done from 1967 to 1969. Methods are essentially the same as those described in Radiocarbon, 1966, v. 8, p. 46–53, 1967, v. 9, p. 38–42, and 1969, v. 11, p. 15–21. Samples synthesized to benzene and counted by liquid scintillation spectrometry. Age calculations are based on 95% of the activity of the NBS oxalic acid standard and computed from the Libby half-life of 5570 yr and reference A.D. 1950. The error listed is the one-sigma statistical counting error. Most samples were counted for 2000 to 3000 min. HCL and NaOH pretreatments were applied to samples as required.

Radiocarbon observations (Δ14C) in dissolved inorganic carbon (DIC) of seawater provide useful information about ocean carbon cycling and ocean circulation. To deliver high-quality observations, the Laboratory of Ion Beam Physics (LIP) at ETH-Zurich developed a new simplified method allowing the rapid analysis of radiocarbon in DIC of small seawater samples, which is continually assessed by following internal quality controls. However, a comparison with externally produced 14C measurements to better establish an equivalency between methods was still missing. Here, we make the first intercomparison with the National Ocean Sciences Accelerator Mass Spectrometry (NOSAMS) facility based on 14 duplicate seawater samples collected in 2020. We also compare with prior deep-water observations from the 1970s to 1990s. The results show a very good agreement in both comparisons. The mean Δ14C of 12 duplicate samples measured by LIP and NOSAMS were statistically identical within one sigma uncertainty while two other duplicate samples agreed within two sigma. Based on this small number of duplicate samples, LIP values appear to be slightly lower than the NOSAMS values, but more measurements will be needed for confirmation. We also comment on storage and preservation techniques used in this study, including the freezing of samples collected in foil bags.

Presented below are dates from some important archaeologic and Quaternary sites. All dates are based on τ ½ = 5568 yr; to convert the radiocarbon dates for archaeologic samples into ad/bc scale, 1950 has been used as base as per the resolution passed at the Ninth International Radiocarbon Conference, San Diego, 1976. The dates are not corrected for 13C fractionation. All the dates older than 10,000 yr have been given with 2σ errors. Due to uncertainty about the contribution of the biogenic carbon in caliche (CaCO3) samples, the dates represent apparent and not true ages.

The following list comprises selected measurements obtained by counting methane at 3 atm pressure in a 0.6 L stainless steel counter. Sample preparation, counting procedure, and calculation method are described in previous lists. Dates are reported in terms of the Libby half-life. The quoted errors are the experimental standard deviations including uncertainty on samples and standards.

Radiocarbon (14C) dating has, since its inception, become an integral part of disciplines such as geology and archaeology, underpinning many key findings made by researchers in the past seven decades. As 14C dating develops, the need arises to revisit older findings and legacy data which may well contain laboratory errors or post-analysis misinterpretations. In this paper we examine one such finding from Sweden, namely the 1958 14C dating of the great Jordfallet (“the Earthfall”) landslide, which was published in the very first volume of Radiocarbon in 1959. We further trace how the results of this 14C dating were misunderstood in a time prior to modern radiocarbon calibration, and the impact which this mistake has had throughout academic publications, state reports and local heritage literature through the course of over sixty years. Because of this flawed interpretation the credible date of 1249 AD given to the landslide by historical sources has been overlooked. Instead, a series of dates from the mid-12th and early 13th centuries have been attributed to the landslide event based on erroneous radiocarbon analysis, a mistake which has substantial implications for the understanding of both regional and international history in medieval Scandinavia.

Radiocarbon (14C) is the one of the most important radionuclides released from the nuclear facilities to the environment. Currently, inorganic 14C is checked during regular environmental monitoring as part of the groundwater monitoring program of the Paks Nuclear Power Plant. Several studies have shown that organic 14C can be also an important and sensitive tool for detection of possible leakage of nuclear technological systems. For this reason, a wet oxidation method was developed for the accelerator mass spectrometry (AMS) 14C measurement technique to determine the 14C activity concentration of the total dissolved carbon content of water samples, coming from environmental monitoring wells. The overall efficiency of the oxidation was around 94 ± 5% for different types of tested organic compounds. The typical 14C background (1–2 pMC) is obtained by preparation of blank samples, which allows a detection level of around 5·10–5 Bq L–1. The activity of the organic fraction can be calculated using the formula presented in the study. The method was applied for water samples deriving from environmental monitoring wells of a pressurized-water reactor (PWR) type of NPP. The results of our investigations over the 14 different water samples around the Paks NPP show that DO14C contribution to the total 14C activity concentration was between 5–25%.

Radiocarbon (14C) is one of the key radionuclides for the performance and safety assessment of a radioactive waste disposal, due to its high activity concentration in waste materials from the nuclear cycle and to its mobility. The measurement of the 14C content in spent ion exchange resins from nuclear reactors is important for the safety assessment of the disposal concept and for the choice of the appropriate treatment/disposal method. Ion exchange resins are commonly used in nuclear reactors as filters for the purification of process liquids or wastes streams and they retain molecules containing radioactive isotopes, among which is 14C. Their efficiency, both as filters and as waste containers, is strictly connected with the morphology. The preservation of spherical shape upon aging is one of the key parameters for their quality assessment and for the evaluation of the potential release of 14C during storage conditions. In this study, the change in IERs morphology during storage periods has been investigated in order to verify correlation with 14C release. Both brand new and aged specimens have been studied in order to assess the quality of the resins after 10 yr of storage and to contribute to the understanding of 14C release mechanisms.

Late Holocene relative sea-level reconstructions are commonly generated using proxies preserved in salt-marsh and mangrove sediment. These depositional environments provide abundant material for radiocarbon dating in the form of identifiable macrofossils (salt marshes) and bulk organic sediment (mangroves). We explore if single-step graphitization of these samples in preparation for radiocarbon dating can increase the number and temporal resolution of relative sea-level reconstructions without a corresponding increase in cost. Dating of salt-marsh macrofossils from the northeastern United States and bulk mangrove sediment from the Federated States of Micronesia indicates that single-step graphitization generates radiocarbon ages that are indistinguishable from replicates prepared using traditional graphitization, but with a modest increase in error (mean/maximum of 6.25/15 additional 14C yr for salt-marsh macrofossils). Low 12C currents measured on bulk mangrove sediment following single-step graphitization likely render them unreliable despite their apparent accuracy. Simulated chronologies for six salt-marsh cores indicate that having twice as many radiocarbon dates (since single-step graphitization costs ∼50% of traditional graphitization) results in narrower confidence intervals for sample age estimated by age-depth models when the additional error from the single-step method is less than ∼50 14C yr (∼30 14C yr if the chronology also utilizes historical age markers). Since these thresholds are greater than our empirical estimates of the additional error, we conclude that adopting single-step graphitization for radiocarbon measurements on plant macrofossils is likely to increase precision of age-depth models by more than 20/10% (without/with historical age markers). This improvement can be implemented without additional cost.

Jacob’s Well, located in modern city of Nablus and ancient Shechem (Tall Balata) in the northern West Bank of Palestine, attracts modern day tourists and pilgrims. It is found in the eastern suburbs of the city. Since 333 AD, pilgrims have been writing accounts of the well, and it has been venerated by both Christian and Jewish communities throughout its history. It is believed to be the well referred to in the New Testament, where Jesus conversed with a Samaritan woman, the orthodox saint, Photini. It now forms the central feature in the crypt of the St Photini Greek Orthodox church in the walled grounds of a monastery. In order to gain more information on the chronology of the site, we analyzed human skeletal remains found at the site in 1997. These consist of three skulls and a femur. One of the skulls was found in a sarcophagus alongside the church and the two other skulls and a femur were found in a burial ground alongside the monastery, north of the church, over which a room has now been built. Radiocarbon analysis reveals that the remains date to four historical periods or events: the early Christian period, before structural additions to the well by Constantine the Great in the fourth century; the Samaritan Revolts (AD 529 and 556), the Sassanid Invasion (AD 614–628), and Abbasid rule (AD 750–1258). Dating of one skull suggests it may have been that of Germanus, a fourth century bishop of Nablus, and that there may have been a very early structure, shrine, or burial chamber at the site before the fourth century. We provide contextual information based on historical and contemporary literature.

In this paper we present data from the measurements of carbon isotopes (Δ14C and δ13C) from α-cellulose extracted from pine tree-rings. The samples were collected in four forests located in the most industrialized part of Poland, where coal mining and coal-based energy are an important branch of industry. The investigated period of time (1975–2012) covers the period of development in coal mining and other industry sectors. Stable isotope composition has been determined with using IRMS and radiocarbon concentration was determinate by AMS.