In this study, we examined how land use and urbanization changes in adjacent areas affected biological productivity and carbon cycling in a lake ecosystem over 100 years and how these changes are reflected in carbon isotope variations. We performed radiocarbon (14C) activity and stable carbon isotope ratio analysis in two organic fractions: humin and humic acids of lake sediment. Additionally, we performed pigment and diatom analysis and determined the carbonate and organic matter (OM) content in sediments. Over the last century, the estimated 14C reservoir age in both sediment organic fractions varied from 1136 ± 112 yr to 5733 ± 122 yr. The increase in the reservoir age by 1175 ± 111 yr was related with higher inputs of pre-aged organic carbon and 14C depleted hard water due to the opening of the channel connecting two lakes. Nuclear weapons tests caused an increase in the reservoir age of up to 5421 ± 135 yr and 5733 ± 122 yr in humin and humic acids, respectively. 13C values in the humic acid fraction showed a tendency to decrease, depending on the content of autochthonous versus allochthonous OM in sediments, while changes in the sources of OM had a minor impact on the stable carbon isotope composition in the humin fraction.

14C dating results derived from an absolutely-dated 471-year tree-ring sequence from central European oak show a trend towards somewhat older dates than those for bristleconepine tree rings of the same age, but similar to those for Egyptian historical samples. Differences visible between these trend lines are not relevant considering the standard errors proposed by Clark (1975).

This list comprises age measurements carried out at the Institute from 1979 to 1981. Anticoincidence variant was applied to attain higher counting efficiency of a 2-channel scintillation device. The introduction of a plastic scintillator as an active guard around the detector in the 2π geometry decreases the influence of high energy cosmic radiation and reduces the background ca 35 to 75% (Rajamäe & Punning, 1980). The application of an active guard with 4π geometry has proved most effective; as a result, the background decreased 85% to 0.65cpm with the volume of scintillation cocktail 5ml. We have improved our methods for decreasing the actual error of the background. The application of a control channel and consideration of barometric effect results in the increase of dating limits of up to 5000–6000 years (Rajamäe, 1981). Samples are calculated using a half-life of 5568 ± 30 years for 14C. Results are reported in years before 1950. δ13C measurements were performed on the mass-spectrometer MI-1201 and are reported with PDB as a reference standard. The reproducibility of results is ±0.2‰.

Measurements have continued with the same proportional counter system, pretreatment procedure, methane preparation and measurement, and calculation using a half-life of 5568 ± 30 years, as described previously (R, 1970, v 12, p 298–318). Uncertainties quoted are single standard deviations originating from standard, sample, background counting rates and half-life. No 13C/12C ratios were measured.

The Organisation of Egyptian Antiquities believes that Egypt should play an important role in current international research in the field of radiocarbon dating of archaeologic samples. Thus, such a laboratory was established within the Center of Research and Conservation of Antiquities, CRCA, Cairo.

At the 12th International Radiocarbon Conference held in Trondheim, the potential of the London Underground as a site for liquid scintillation counting was considered (Bowman, 1986). This was discussed in light of a survey of three possible locations using a portable gamma-ray spectrometer. Two liquid scintillation counters, a Packard 3255 and an LKB “Kangaroo”, have now been successfully installed in a vault which is some 30m below ground. The reduction in background count rates achieved is discussed, together with other improvements made to the counting system.

Radiocarbon (14C) dating of sediment deposition around Antarctica is often challenging due to heterogeneity in sources and ages of organic carbon in the sediment. Chemical and thermochemical techniques have been used to separate organic carbon when microfossils are not present. These techniques generally improve on bulk sediment dates, but they necessitate assumptions about the age spectra of specific molecules or compound classes and about the chemical heterogeneity of thermochemical separations. To address this, the Rafter Radiocarbon Laboratory has established parallel ramped pyrolysis oxidation (RPO) and ramped pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) systems to thermochemically separate distinct carbon fractions, diagnose the chemical composition of each fraction, and target suitable RPO fractions for radiocarbon dating. Three case studies of sediment taken from locations around Antarctica are presented to demonstrate the implementation of combined RPO-AMS and Py-GC-MS to provide more robust age determination in detrital sediment stratigraphy. These three depositional environments are good examples of analytical and interpretive challenges related to oceanographic conditions, carbon sources, and other factors. Using parallel RPO-AMS and Py-GC-MS analyses, we reduce the number of radiocarbon measurements required, minimize run times, provide context for unexpected 14C ages, and better support interpretations of radiocarbon measurements in the context of environmental reconstruction.

Measurements reported in this paper were obtained with the 4.5 L and 3 L CO2 counters, details of which were given earlier (Radiocarbon, v. 11, p. 423). The automatic data recording system built in 1968 (Hänsel, 1968) is now operating for both counting apparatus. For each one the counts of the guard counters ring (A counts), the total counts of the C14 counter (B counts), the coincidences of central and guard ring counter (AB counts), and the anticoincidences (ĀB counts) are tape punched every 100th minute. By an ALGOL program, all counts are checked first for large disturbances. Secondly, equation B = AB + ĀB must hold (as an integral check for proper operation of logical circuitry and the data recording system) and finally statistical compatibility is examined before age and other data for the actual counting apparatus are computed. This detailed check of counting rates by computer has proved to be very efficient to yield reliable long-term measurements.

Twelve monoxylous boats were analyzed from different provinces of northern Italy by radiocarbon and dendrodating. Most of them were dated in the range 6th–12th centuries cal AD. All boats were made from single tree trunks containing ~50 to ~250 tree rings. The results from archaeometric dating in logboats confirm that these kinds of vessels remained practically unchanged for centuries and were in use until recently. The technical features are more strictly related to local traditions than to chronology.

The Upper Paleolithic open-air site Sungir is located in the central Russian Plain. The blank production of the lithic industry is characterized by parallel reduction with flakes being the main blank type. The tool assemblage has two components: archaic types (Mousterian-like) on the one hand and Upper Paleolithic types on the other. The available data does not allow for a confident determination of the chronological position of the Sungir site, nor does it enable researchers to distinguish different stages of human occupation. The horizontal distribution of the dated samples demonstrates the almost complete absence of radiocarbon (14C) dates for household features identified at the site (fireplaces, fire and ritual pits, large accumulations of bones, etc.). In addition, the vertical distribution of 14C dates in the rather thick cultural layer points to the exposure of the site to solifluction.

I suggest, on the basis of a statistical analysis, that recently determined “conventional radiocarbon ages” of Dead Sea Scroll documents are offset systematically by about +40 yr, leading to a similar overestimate of the ages of these documents. Much closer agreement with paleographic and specific dates is obtained when a correction of this magnitude is made to the “conventional 14C” values. This indicates that 14C dates may convey more precise information about the ages of these documents than initially recognized.

We present here results of our investigation of the isotopic chemical composition of groundwater and carbonates in the Surdulica geothermal aquifer, Serbia. We considered the effects of carbonate dissolution and measured 13C, 14C, D, 18O, 3H, field pH, temperature, Na+, Ca2+, Mg2+, HCO−3; and other aqueous species from 30 springs and boreholes. Geothermal waters are supersaturated with calcite. Carbon isotope compositions vary with carbonate mineral dissolution. The δD and δ18O of groundwater samples fit the meteoric water line, and indicate that groundwater is recharged mainly from higher altitudes and the cold season. Different groundwater residence times point out two mechanisms for their formation: fissure flow for young waters and standard diffusion processes for old ones.

The Rio Grande Cone is a major fanlike depositional feature in the continental slope of the Pelotas Basin, Southern Brazil. Two representative sediment cores collected in the Cone area were retrieved using a piston core device. In this work, the organic matter (OM) in the sediments was characterized for a continental vs. marine origin using chemical proxies to help constrain the origin of gas in hydrates. The main contribution of OM was from marine organic carbon based on the stable carbon isotope (δ13C-org) and total organic carbon/total nitrogen ratio (TOC:TN) analyses. In addition, the 14C data showed important information about the origin of the OM and we suggest some factors that could modify the original organic matter and therefore mask the “real” 14C ages: (1) biological activity that could modify the carbon isotopic composition of bulk terrestrial organic matter values, (2) the existence of younger sediments from mass wasting deposits unconformably overlying older sediments, and (3) the deep-sediment-sourced methane contribution due to the input of “old” (>50 ka) organic compounds from migrating fluids.

Radiocarbon dating of historical and archaeological wood can be complicated, sometimes involving issues of “inbuilt” age in slow-growing woods, and/or the possibility of reuse or long delays between felling and use of the wood. Terminus dates can be provided by dating the sapwood, or the outermost edge of heartwood, while a date from the pith can give an indication of the first years of growth. A sequence of samples from specific points within the bole can be used to determine the growth rate of the tree. Such a combined dating strategy is particularly useful in cross-referencing dates from a single piece, better placing it in its chronological context. This paper reports paired or multiple dates from 11 wooden sculptures dated as part of the Pre-Hispanic Caribbean Sculptural Arts in Wood project, which studied 66 wooden artifacts attributed to the pre-colonial Taíno, the indigenous peoples of the Caribbean's Greater Antilles. The calibrated ages of the pieces published here range from ∼AD 700–1500, indicating that the Taíno were producing elaborate sculptures much earlier than previously thought. The paired or multiple dates from these carvings confirmed the accuracy of the results, and were also used to construct a growth rate model of what was expected to be a slow-growing species (Guaiacum sp.). This model demonstrates that the boles used to create the sculptures grew on average 1 cm every 6–13 yr.

The need for increased quality assurance for radiocarbon measurements performed by the monitoring laboratories at nuclear stations has spurred the introduction of a number of interlaboratory comparisons. We organized two such intercomparisons: the first set, circulated in 1994, consisted of two milk samples, one containing current global levels of 14C, the other containing an added spike of 14C-methylated casein. The second set, circulated in 1995, consisted of two samples of natural vegetation growing on the site of the Chalk River Laboratories (CRL), containing two different levels of 14C, both well above global background. The response to our invitation to participate in these studies was very encouraging; six laboratories took part in the first intercomparison, eleven in the second. The list included both monitoring laboratories and those whose main function is 14C dating. Understandably, some of the latter preferred not to analyze the higher-activity samples. The results in 3 of the 4 data sets were consistent with a statistical distribution based on the reported errors. This report provides details of two intercomparisons, including the preparation of the samples, which may now be considered potential secondary reference materials, the range of analytical techniques in use at the participating laboratories, and a statistical analysis of the results returned to us.

Most of the 14C measurements reported here were made between October 74 and March 76. The usual procedures and methods of sample preparation are those described in R, 1964, v 6, p 194-196. The electronic apparatus was constructed by J Galliot from results of studies on background of proportional counters (Delibrias & Rapaire, 1967) and was described briefly in R, 1966, v 8, p 286-291.

Recent advancements in accelerator mass spectroscopic (AMS) radiocarbon (14C) analytical methods and instrumentation offer us reliable conventional 14C ages with highly reduced analytical uncertainty for archeological bone collagen. However, after calibration this may be still too high for archeologists in periods where archeochronology is capable of attaining a resolution of 25–30 yr. Furthermore, there are cases when wiggles in the calibration curve yield wider age ranges than initially expected. For the Avar Age in the Carpathian Basin (568 to early 9th century AD) reliable archeotypochronology is available for the 7th century AD alone. The date of Avar invasion (568 AD) is precisely known. Precise archeological dating for the late 6th and the 9th centuries is lacking, calling for other methods to be introduced. This paper reports the first 14C dates for an Early Avar Age cemetery, Makó-Mikócsa. According to archeotypochronology, the cemetery was in use for three generations until the mid-7th century AD. The imprecision in 14C chronology arising from wiggles in the IntCal13 curve was significantly reduced by relative stratigraphy-controlled Bayesian modeling. Introduction of further age constraints from archeotypochronology into the model reduces broad absolute age ranges providing more constraint ages.

Decommissioning of nuclear reactors requires determination of all remnant long-lived isotopes that were produced during their long functioning time of the respective facilities. Radiocarbon (14C) is such an isotope (T1/2 = 5730 yr), widely produced by neutron reactions in a thermal column of a nuclear reactor. Accelerator mass spectrometry (AMS) uses 14C for precise dating of up to 50,000 years old archaeological artifacts. This study presents a premier AMS measurement of high concentrated 14C samples that are strictly forbidden in laboratories dedicated to perform 14C dating. The determined 14C activities range from the natural level (isotopic ratio 14C/12C = 1.2 × 10–12) up to values of 10,000 times higher. 14C bulk and depth profile concentrations were measured in the thermal column disks of a decommissioned nuclear reactor. Results have shown that the 14C concentration in the thermal column, close the reactor core is about 75 kBq/g and decreases to 0.7 Bq/g and the end of the column. Such AMS measurements are applicable for decommissioning and waste management of nuclear reactors.