As a result of collisions during their lifetimes, asteroids have a large variety of different shapes. It is believed that high velocity collisions or rotational spin-up of asteroids continuously replenish the Sun’s zodiacal cloud and debris disks around extrasolar planets (Jewitt (2010)). Knowledge of the spin and shape parameters of the asteroids is very important for understanding collision asteroid processes. Lately photometric observations of asteroids showed that variations in brightness are not accompanied by variations in colour index which indicate that the shape of the lightcurve is caused by varying illuminations of the asteroid surface rather than albedo variations over the surface. This conclusion became possible when photometric investigations were combined with laboratory experiments (Dunlap (1971)). In this article using the convex lightcurve inversion method we obtained the sense of rotation, pole solutions and preliminary shape of 901 Brunsia.

Most interstellar and planetary environments are suffused by a continuous flux of several types of ionizing radiation, including cosmic rays, stellar winds, x-rays, and gamma-rays from radionuclide decay. There is now a large body of experimental work showing that these kinds of radiation can trigger significant physicochemical changes in ices, including the dissociation of species (radiolysis), sputtering of surface species, and ice heating. Even so, modeling the chemical effects that result from interactions between ionizing radiation and interstellar dust grain ice mantles has proven challenging due to the complexity and variety of the underlying physical processes. To address this shortcoming, we have developed a method whereby such effects could easily be included in standard rate-equations-based astrochemical models. Here, we describe how such models, thus improved, can fruitfully be used to simulate experiments in order to better understand bulk chemistry at low temperatures.

The aim of this work is to understand the stability and investigate the chemical evolution of formamide ice due to thermal hydrogenation at simulated interstellar conditions.

Reactions on carbonaceous surfaces play an important role in processes such as H2 formation in the interstellar medium. We have investigated the adsorption of C2 molecules on a highly oriented pyrolytic graphite (HOPG) surface and then exposed them to a beam of deuterium atoms in order to investigate the formation of deuterated fullerenes. Scanning tunneling microscopy (STM) was used to probe the adsorbed molecules and their deuteration. Deuteration of C2 films results in increased thermal stability of the film, relative to films of pristine C2, along with an evolution towards higher deuterated species. The STM data provide confirmatory evidence for the formation of deuterated fullerene species.

Silicate is the most popular dust species in the circumstellar envelope of evolved oxygen-rich stars, yet its seed particles have not been well identified. Among the candidates, corundum and SiO attract intense attention and study. SiO was suggested to be the seed particles in early 1980s and has received various supports as well as oppositions. In this work we investigate the relation of SiO maser and silicate dust emission powers. With both our own observation by using the PMO/Delingha 13.7-m telescope and the archival data, a sample is assembled of 21 SiO v=1, J=2-1 sources and 28 SiO v=1, J=1-0 sources that exhibit silicate emission features in the ISO/SWS spectrum. The analysis of their SiO maser and silicate emission power shows a moderate correlation, which agrees with the idea that SiO molecules are the seed nuclei of silicate dust.

Resolved emission from gas-phase methanol can reveal the abundance and distribution of the comet-forming ice reservoir in protoplanetary disks. ALMA Cycle 4 observations of four transitions of gas-phase methanol in TW Hya allow the first model-independent determination of the rotational temperature of methanol in a prototoplanetary disk. The data confirm that the methanol is rotationally cold (Trot < 50 K), and well constrain the column density to 2 × 1012 cm−2. Astrochemical models will constrain the chemical origin of methanol in TW Hya.

Interstellar carbon has been detected in both gas-phase molecules and solid particles. The goal of this study is to identify the link between these two phases of cosmic carbon. Here we report preliminary results on the low temperature formation of carbonaceous dust grains from gas-phase aromatic hydrocarbon precursors. This is done using the supersonic expansion of an argon jet seeded with aromatic molecules and exposed to an electrical discharge. We report experimental evidence of efficient carbon dust condensation from aromatic molecules including benzene and naphthalene. The molecular content of the solid grains is probed with laser desorption mass spectrometry. The mass spectra reveal a rich molecular composition including fragments of the parent molecule but also growth into larger molecular species.

We use quantum chemical techniques to model the vibrational spectra of small aromatic molecules on a proton-ordered hexagonal crystalline water ice (XIh) model. We achieve a good agreement with experimental data by accounting for vibrational anharmonicity and correcting the potential energy landscape for known failures of density functional theory. A standard harmonic description of the vibrational spectra only leads to a broad qualitative agreement.

The aim of this work is to explain the possible mechanism in the early Solar System, by which water-rich asteroids may have been delivered to Earth. Carbonaceous (C-type) asteroids, with a large fraction of water molecules, dominate in the outer part of the asteroid belt and the possibility of their migration toward Earth is still not well explained. In this work, we observe very efficient dynamical routes along which C-type water-bearing asteroids are delivered to Earth.