The first objective of this chapter is to briefly review some of the basic ideas about the structure of matter, in particular the concepts of microscopic physics, in order to recall the knowledge gained in previous physics (and chemistry) courses and make it more precise. Our review will be very concise, and most statements will be made without any proof or detailed discussion. A second objective is to give a brief description of some of the crucial stages in the early development of quantum physics. We shall not follow the strict historical order of this development or present the arguments used at the beginning of the last century by the founding fathers of quantum mechanics; rather, we shall stress the concepts which we shall find useful later on. Our last objective is to give an elementary introduction to some of the basic ideas, like those of a quantum particle or energy level, that will reappear throughout this text. We shall base our review on the Bohr theory, which provides a simple, though far from convincing, explanation of how energy levels are quantized and how the spectrum of the hydrogen atom arises. This chapter should be reread later on, once the basic ideas of quantum mechanics have been made explicit and illustrated by examples. From the practical point of view, it is possible to skip the general considerations of Sections 1.1 and 1.2 at the first reading and begin with Section 1.3, returning to those two sections later on as needed.

In this chapter we build up the basic concepts of quantum mechanics using two simple examples, following a heuristic approach which is more inductive than deductive. We start with a familiar phenomenon, that of the polarization of light, which will allow us to introduce the necessary mathematical formalism. We show that the description of polarization leads naturally to the need for a two-dimensional complex vector space, and we establish the correspondence between a polarization state and a vector in this space, referred to as the space of polarization states. We then move on to the quantum description of photon polarization and illustrate the construction of probability amplitudes as scalar products in this space. The second example will be that of spin 1/2, where the space of states is again two-dimensional. We construct the most general states of spin 1/2 using rotational invariance. Finally, we introduce dynamics, which allows us to follow the time evolution of a state vector.

The analogy with the polarization of light will serve as a guide to constructing the quantum theory of photon polarization, but no such classical analog is available for constructing the quantum theory for spin 1/2. In this case the quantum theory will be constructed without reference to any classical theory, using an assumption about the dimension of the space of states and symmetry principles.

The polarization of light and photon polarization

The polarization of an electromagnetic wave

The polarization of light or, more generally, of an electromagnetic wave, is a familiar phenomenon related to the vector nature of the electromagnetic field. Let us consider a plane wave of monochromatic light of frequency ω propagating in the positive z direction.

In Chapter 4 we saw that the canonical commutation relations force us to use a space of states of infinite dimension, in which rigor would require the use of advanced mathematical tools. Fortunately, physicists generally need only to carry the results for finite dimension over to infinite dimension with some simple modifications which we shall indicate here, without embarking on sophisticated mathematics. Nevertheless, it is useful to be aware of the lapses in rigor which are customarily made in physics in order to avoid possible unpleasant surprises.

The objective of this chapter is, on the one hand, to present some concrete examples illustrating the new features which arise in infinite dimension and, on the other, to give the rules for practical calculations, in particular to write down the spectral decomposition of Hermitian and unitary operators. The mathematics we use is a bit more detailed than commonly found in most quantum mechanics textbooks. The reader interested purely in the practical aspects can proceed directly to Section 7.3, where the results essential for later on are summarized.

Hilbert spaces

Definitions

The space of states of quantum mechanics is a Hilbert space ℌ, which in general is of infinite dimension. The axiomatic definition of a Hilbert space is the following.

1. It is a vector space which, for the needs of quantum mechanics, is defined on complex numbers. The vectors of this space are denoted |ϕ〉.

2. […]

This collection of quantum mechanics problems has grown out of many years of teaching the subject to undergraduate and graduate students. It is addressed to both student and teacher and is intended to be used as an auxiliary tool in class or in self-study. The emphasis is on stressing the principles, physical concepts and methods rather than supplying information for immediate use. The problems have been designed primarily for their educational value but they are also used to point out certain properties and concepts worthy of interest; an additional aim is to condition the student to the atmosphere of change that will be encountered in the course of a career. They are usually long and consist of a number of related questions around a central theme. Solutions are presented in sufficient detail to enable the reader to follow every step. The degree of difficulty presented by the problems varies. This approach requires an investment of time, effort and concentration by the student and aims at making him or her fit to deal with analogous problems in different situations. Although problems and exercises are without exception useful, a collection of solved problems can be truly advantageous to the prospective student only if it is treated as a learning tool towards mastering ways of thinking and techniques to be used in addressing new problems rather than a solutions manual. The problems cover most of the subjects that are traditionally covered in undergraduate and graduate courses.

In the last chapter we saw how the measurement problem in quantum theory arises when we try to treat the measurement apparatus as a quantum system. We need more apparatus to measure which state the first apparatus is in, and we have a measurement chain that seems to go on indefinitely. There is, however, one place where this apparently infinite sequence certainly seems to end and that is when the information reaches us. We know from experience that when we look at the photon detector we see that either it has recorded the passage of a photon or it hasn't. When we open the box and look at the cat either it is dead or it is alive; we never see it in the state of suspended animation that quantum physics alleges it should be in until its state is measured. It might follow, therefore, that human beings should be looked on as the ultimate measuring apparatus. If so, what aspect of human beings is it that gives them this apparently unique quality? It is this question and its implications that form the subject of the present chapter.

Let us examine more closely what goes on when a human being observes the quantum state of a system. We return to the set-up described in the last chapter, where a 45° photon passes through a polarisation analyser that moves a pointer to one of two positions (H or V) depending on whether the photon is horizontally or vertically polarised.