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… You see, therefore, that living force [energy] may be converted into heat, and that heat may be converted into living force, or its equivalent attraction through space. All three, therefore – namely, heat, living force, and attraction through space (to which I might also add light, were it consistent with the scope of the present lecture) – are mutually convertible into one another. In these conversions nothing is ever lost. The same quantity of heat will always be converted into the same quantity of living force. We can therefore express the equivalency in definite language applicable at all times and under all circumstances.
James Prescott Joule, “On Matter, Living Force, and Heat” (1847)
TOWARD AN IDEA OF ENERGY
The law of conservation of energy is one of the most fundamental laws of physics. No matter what you do, energy is always conserved. So why do people tell us to conserve energy? Evidentally the phrase “conserve energy” has one meaning to a scientist and quite a different meaning to other people, for example, to the president of a utility company or to a politician. What then, exactly, is energy?
The notion of energy is one of the few elements of mechanics not handed down to us from Isaac Newton. The idea was not clearly grasped until the middle of the nineteenth century. Nevertheless, we can find its germ even earlier than Newton.
It has been observed that missiles, that is to say, projectiles follow some kind of curved path, but that it is a parabola no one has shown. I will show that it is, together with other things, neither few in number nor less worth knowing, and what I hold to be even more important, they open the door to a vast and crucial science of which these our researches will constitute the elements; other geniuses more acute than mine will penetrate its hidden recesses.
Galileo Galilei, Two New Sciences, Third Day (1638)
IF THE EARTH MOVES: ARISTOTELIAN OBJECTIONS
In 1543 Nicolaus Copernicus's book De Revolutionibus Orbium Coelestium (On the Revolutions of the Heavenly Spheres) appeared in print. Copernicus, mindful of his personal safety, had waited until his deathbed to publish his ideas. Within the pages of De Revolutionibus Copernicus set the earth spinning on its axis and revolving around the sun. In his attempt to return the heavens to their simple beauty, Copernicus had to make the sun, not the earth, the center of the universe, and in doing so he tore the heart out of the Aristotelian world. Without the solid, immovable earth at the center of the universe, there could be no Aristotelian laws of motion. And without these laws, there were none at all, for Copernicus had no laws to replace those he destroyed.
There are however innumerable other local motions which on account of the minuteness of the moving particles cannot be detected, such as the motions of the particles in hot bodies, in fermenting bodies, in putrescent bodies, in growing bodies, in the organs of sensation and so forth. If any one shall have the good fortune to discover all these, I might almost say that he will have laid bare the whole nature of bodies so far as the mechanical causes of things are concerned.
Isaac Newton, in Unpublished Papers of Isaac Newton
TEMPERATURE AND PRESSURE
Everybody talks about the weather, and that usually means the temperature, an inescapable part of our environment. Yet Newton's laws of mechanics tell us nothing about temperature. Is there any connection between mechanics and temperature?
In Chapter 10 we saw a connection. If you drop a block from above a table, its potential energy first turns into kinetic energy, and then is transformed into thermal energy when the block hits the table. After a while the only evidence that those events occurred is a slight warming of the surroundings, that is, a small increase in temperature.
What really happens is that the kinetic energy of the falling block is turned into the energy of motion of atoms and molecules. The energy is still there, but the motions are in random directions, not the organized motion of a whole block of matter.
I was almost driven to madness in considering and calculating the matter. I could not find out why the planet [Mars] would rather go on an elliptical orbit. Oh ridiculous me! As if the libration on the diameter could not also be the way to the ellipse. So this notion brought me up short, that the ellipse exists because of the libration. With reasoning derived from physical principles agreeing with experience, there is no figure left for the orbit of the planet except for a perfect ellipse. …
Why should I mince my words? The truth of Nature, which I had rejected and chased away, returned by stealth through the back door, disguising itself to be accepted. That is to say, I laid [the original equation] aside, and fell back on ellipses, believing that this was a quite different hypothesis, whereas the two, as I shall prove in the next chapter, are one and the same. … I thought and searched, until I went nearly mad, for a reason why the planet preferred an elliptical orbit. … Ah, what a foolish bird I have been!
Johannes Kepler, Astronomia Nova (1609)
THE QUEST FOR PRECISION
Not long after Copernicus published his revolutionary book, Tycho Brahe (1546–1601) provided a multitude of new observations that, despite his own intentions, provided crucial support for the Copernican hypothesis.
The initial shock [of acceleration] is the worst part of it, for he is thrown upward as if by an explosion of gun powder. … Therefore he must be dazed by opiates beforehand; his limbs must be carefully protected so that they are not torn from him and the recoil is spread over all parts of his body. Then he will meet new difficulties: immense cold and inhibited respiration. … When the first part of the journey is completed, it becomes easier because on such a long journey the body no doubt escapes the magnetic force of the earth and enters that of the moon, so that the latter gets the upper hand. At this point we set the travellers free and leave them to their own devices: like spiders they will stretch out and contract, and propel themselves forward by their own force – for, as the magnetic forces of the earth and moon both attract the body and hold it suspended, the effect is as if neither of them were attracting it – so that in the end its mass will by itself turn toward the moon.
Johannes Kepler, Somnium, published posthumously in 1634
FREEWAYS IN THE SKY
Not many years ago, the only conceivable use of the beautiful celestial mechanics developed over hundreds of years was to compute the positions of bodies in the heavens. Today that situation has changed radically.
If I wished to attract the student of any of these sciences to an algebra for vectors, I should tell him that the fundamental notions of this algebra were exactly those with which he was daily conversant. … In fact, I should tell him that the notions which we use in vector analysis are those which he who reads between the lines will meet on every page of the great masters of analysis, or of those who have probed the deepest secrets of nature. …
J. W. Gibbs (in Nature, 16 March 1893)
COORDINATE SYSTEMS
Galileo discovered through the law of inertia that there is no single preferred reference frame. To use this discovery most efficiently, we need to discuss some geometrical ideas. The first kind of geometrical construction we need is a way of describing where things are.
If the world were only one-dimensional, everything would be on a single line. To describe where something is on that line we would first pick a point on the line as a point of reference, the origin. Then we would pick a direction along the line as the positive direction – let's say to the right of the starting point. And having made those choices we would only need to give one number – call it the x coordinate – to specify the location of a point.
We have seen that the gaseous and liquid states are only distant stages of the same condition of matter, and are capable of passing into one another by a process of continuous change. A problem of far greater difficulty yet remains to be solved, the possible continuity of the liquid and solid states of matter. The fine discovery made some years ago by James Thomson, of the influence of pressure on the temperature at which liquefaction occurs, and verified experimentally by Sir. W. Thomson, points, as it appears to me, to the direction this inquiry must take; and in the case at least of those bodies which expand in liquefying, and whose melting-points are raised by pressure, the transition may possibly be effected. But this must be a subject for future investigation; and for the present I will not venture to go beyond the conclusion I have already drawn from direct experiment, that the gaseous and liquid forms of matter may be transformed into one another by a series of continuous and unbroken changes.
Thomas Andrews, Philosophical Transactions of 1869, p. 575
COOLING OFF
How do you make something colder? Making something hotter is easy. For example, if you need to warm yourself on a chilly night, you can build a fire with little or no technology. But to cool yourself on a hot day is quite another matter.
Hitherto we have explained the phenomena of the heavens and of our sea by the power of gravity, but have not yet assigned the cause of this power. This is certain, that it must proceed from a cause that penetrates to the very centres of the sun and planets, without suffering the least diminution of its force; that operates not according to the quantity of the surfaces of the particles upon which it acts (as mechanical causes used to do), but according to the quantity of the solid matter which they contain, and propagates its virtue on all sides to immense distances, decreasing always as the inverse square of the distances.
Isaac Newton, Principia (1686)
THE GENESIS OF AN IDEA
The year was 1665; the month was August; and England was besieged by bubonic plague. Isaac Newton, then a 23-year-old Cambridge University student, retired to the solitude of his family's farm in Lincolnshire until the plague subsided and the university reopened. Not given to inactivity, Newton composed 22 questions for himself ranging from geometric constructions to Galileo's new mechanics to Kepler's planetary laws. During the next 18 months, he immersed himself in the search for answers and along the way discovered calculus, the laws of motion, and the universal law of gravity.
Everybody knows that heat can cause movement, that it possesses great motive power; steam engines so common today are a vivid and familiar proof of it. … The study of these engines is of the greatest interest, their importance is enormous, and their use increases every day. They seem destined to produce a great revolution in the civilized world. …
Despite studies of all kinds devoted to steam engines, and in spite of the satisfactory state they have reached today, the theory of them has advanced very little and the attempts to improve them are still directed almost by change.
Sadi Carnot, “The Motive Power of Heat” (1824)
THE AGE OF STEAM
The age of steam is past. The steam engine is a curiosity, an object of nostalgia that has been replaced by diesel engines, electric motors, turbine engines, and gasoline engines to drive the wheels of civilization. Nonetheless, steam did have its day. The steam engine not only caused the Industrial Revolution, which changed our lives; it also led to discoveries in physics so profound that they changed the way we think. How did investigations into the nature of steam engines lead to a deeper understanding of the universe?
First, we need to understand how a steam engine operates. In essence, a steam engine is a device which heats water in a closed container, a boiler, thereby converting it to steam.
Another question concerns the oscillations of pendulums, and it falls into two parts. One is whether all oscillations, large, medium, and small, are truly and precisely made in equal times. The other concerns the ratio of times for bodies hung from unequal threads; the times of their vibrations, I mean. … As to the prior question, whether the same pendulum makes all its oscillations – the largest, the average, and the smallest – in truly and exactly equal times, I submit myself to that which I once heard from our Academician [Galileo]. He demonstrated that the moveable which falls along chords subtended by every arc [of a given circle] necessarily passes over them all in equal times. …
As to the ratio of times of oscillations of bodies hanging from strings of different lengths, those times are as the square roots of the string lengths; or should we say that the lengths are as the doubled ratios, or squares, of the times.
Galileo Galilei, Two New Sciences (1638)
FINDING A CLOCK THAT WOULDN'T GET SEASICK
Navigation has provided one of the most persistent motives for measuring time accurately. All navigators depend on continuous time information in order to find out where they are and to chart their course. But until about two centuries ago, no one was able to make a clock that could keep time accurately at sea.
For the present I will limit myself to quoting the following result: if we imagine the same quantity, which in the case of a single body I have called its entropy, formed in a consistent manner for the whole universe (taking into account all the conditions), and if at the same time we use the other notion, energy, with its simpler meaning, we can formulate the fundamental laws of the universe corresponding to the laws of the mechanical theory of heat in the following simple form:
1. The energy of the universe is constant.
2. The entropy of the universe tends to a maximum.
Rudolph Clausius in Annalen der Physik, 125 (1865)
TOWARD AN UNDERSTANDING OF ENTROPY
In this chapter we turn our attention to the entropy principle, a concept which, like Newton's second law, is an organizing principle for understanding the world. The principle is relatively simple to state, but understanding its meaning is more challenging.
Through theoretical studies of Carnot's work in 1865, the German physicist Rudolph Clausius introduced a new physical quantity closely linked to energy. He called it entropy, a word which sounds like “energy” and comes from the Greek word for “transformation.” The use of entropy provides a way to analyze the behavior of energy in transformation.
It is most useful that the true origins of memorable inventions be known, especially of those which were conceived not by accident but by an effort of meditation. … One of the noblest inventions of our time has been a new kind of mathematical analysis, known as the differential calculus.
Gottfried Wilhelm Leibniz, Historia et origo calculi differentialis (1714)
THE DEVELOPMENT OF DIFFERENTIAL CALCULUS
After the advent of algebra in the sixteenth century, a flood of mathematical discoveries swept through Europe. The most important were differential calculus and integral calculus, bold new methods for attacking a host of problems that had challenged the world's best minds for more than 2000 years. Differential calculus deals with ideas such as speed, rate of growth, tangent lines, and curvature, whereas integral calculus treats topics such as area, volume, arc length, and centroids.
Work begun by Archimedes in the third century b.c. led ultimately to the birth of integral calculus in the seventeenth century a.d. This development has a long and fascinating history which we will explore in more detail later.
Differential calculus has a relatively short history. The concept of derivative was first formulated early in the seventeenth century when the French mathematician Pierre de Fermat tried to devise a way of finding the smallest and largest values of a given function. He imagined the graph of a function having, at each of its points, a direction given by a tangent line, as suggested by the points labeled in Fig. 3.1.
Then from these forces, by other propositions which are also mathematical, I deduce the motions of the planets, the comets, the moon, and the sea. I wish we could derive the rest of the phenomena of Nature by the same kind of reasoning from mechanical principles, for I am induced by many reasons to suspect that they may all depend upon certain forces by which the particles of bodies, by some cause hitherto unknown, are either mutually impelled towards one another, and cohere in regular figures, or are repelled and recede from one another. These forces being unknown, philosophers have hitherto attempted the search of nature in vain; but I hope the principles here laid down will afford some light either to this or some truer method of philosophy.
Isaac Newton, Principia (1686)
THE END OF THE CONFUSION
In 1543 Copernicus published his book, and a tremor rocked the foundations of the Aristotelian world. A century later the Aristotelian world lay in ruins, but nothing had risen to replace it. Galileo and Kepler had made mighty discoveries, but there was no central principle that could organize the world. The unified harmony of the Aristotelian view had been replaced by buzzing confusion.
Galileo was concerned not with the causes of motion but instead with its description. The branch of mechanics he reared is known as kinematics; it is a mathematically descriptive account of motion without concern for its causes.
In the center of all the celestial bodies rests the sun. For who could in this most beautiful temple place this lamp in another or better place than that from which it can illuminate everything at the same time? Indeed, it is not unsuitable that some have called it the light of the world; others, its minds, and still others, its ruler. Trismegistus calls it the visible God; Sophocles' Electra, the all-seeing. So indeed, as if sitting on a royal throne, the Sun rules the family of the stars which surround it.
Nicolaus Copernicus in De Revolutionibus Orbium Coelestium (1543)
THE COPERNICAN REVOLUTION
We find it difficult to imagine the frame of mind of people who once firmly believed the earth to be the immovable center of the universe, with all the heavenly bodies revolving harmoniously around it. It is ironic that this view, inherited from the Middle Ages and handed down by the Greeks, particularly Greek thought frozen in the writings of Plato and Aristotle, was one designed to illustrate our insignificance amid the grand scheme of the universe – even while we resided at its center.
Aristotle's world consisted of four fundamental elements – fire, air, water, and earth – and each element was inclined to seek its own natural place.