Published online by Cambridge University Press: 05 July 2011
It is proposed to investigate the subsidence to thermal equilibrium of a gas slightly disturbed therefrom and included in a solid vessel whose walls retain a constant temperature. The problem differs from those considered by Fourier in consequence of the mobility of the gas, which may give rise to two kinds of complication. In the first place gravity, taking advantage of the different densities prevailing in various parts, tends to produce circulation. In many cases the subsidence to equilibrium must be greatly modified thereby. But this effect diminishes with the amount of the temperature disturbance, and for infinitesimal disturbances the influence of gravity disappears. On the other hand, the second complication remains, even though we limit ourselves to infinitesimal disturbances. When one part of the gas expands in consequence of reception of heat by radiation or conduction, it compresses the remaining parts, and these in their turn become heated in accordance with the laws of gases. To take account of this effect a special investigation is necessary.
But although the fixity of the boundary does not suffice to prevent local expansions and contractions and consequent motions of the gas, we may nevertheless neglect the inertia of these motions since they are very slow in comparison with the free oscillations of the mass regarded as a resonator. Accordingly the pressure, although variable with time, may be treated as uniform at any one moment throughout the mass.
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