Book contents
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
8 - Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
Published online by Cambridge University Press: 24 November 2009
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
Summary
Abstract
The far- and mid-infrared reflectivity R(ω) of e-doped single crystals belonging to the family M2−xCexCuO4−y(M = Pr, Nd, Gd; 0<x<0.15; 0<y<0.04) has been studied between 300 and 20 K. In addition to the phonons predicted for the T' structure, R(ω) shows local modes in the far infrared as well as a broad infrared absorption centered at about 0.1 eV (d or J band). These features depend strongly on both T and y. We have resolved the d band at low T, in samples doped by oxygen vacancies. We demonstrate its polaronic origin by showing that it is made up of intense overtones of the local modes observed in the far infrared. We also find that Ce-doped superconductors (x> 0.12,y = 0.03) have the same polaronic structure as the semiconducting ones, partially superimposed on a weak Drude term.
Introduction
Since the discovery of high-Tc superconductors (HTSC), infrared reflectivity measurements have been largely employed to investigate both electronic and transport properties of these cuprates [1]. Early spectra already showed several intriguing features common to all HTSC families, which were then attributed to the peculiar properties of the Cu–O plane. Those features are well reproducible and could be studied in greater detail as soon as large single crystals became available. However, their interpretation is still being debated. In the insulating parent compounds of HTSC, one observes phonon modes in the far infrared, and a broad band at high frequencies (from about 1.5 to 2.5 eV). This latter has been unanimously assigned to charge-transfer (CT) transitions between O 2p and Cu 3d orbitals.
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- Publisher: Cambridge University PressPrint publication year: 1995
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