Book contents
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
3 - A bipolaron Bose liquid in high-Tc superconductors
Published online by Cambridge University Press: 24 November 2009
- Frontmatter
- Contents
- Preface
- 1 A polaron theory of high-temperature superconductors
- 2 On the possibility of non-BCS superconductivity
- 3 A bipolaron Bose liquid in high-Tc superconductors
- 4 Spin polarons in high-Tc superconductors
- 5 The polaron scenario for high-Tc superconductors
- 6 Formation, phase separation and superconductivity of large bipolarons
- 7 Polarons and bipolarons in WO3−x and YBa2Cu3O7
- 8 Polaron bands in the far- and mid-infrared spectra of e-doped cuprates
- 9 Electron–phonon interaction of non-equilibrium carriers in the photoinduced state of YBa2Cu3O7−δ
- 10 Experimental evidence of local lattice distortion in superconducting oxides
- 11 The Hall effect due to small polarons and conduction in narrow energy bands
- 12 Static and dynamic conductivity of untwinned Y1Ba2Cu4O8: gaps or condensation?
- 13 The near infrared and optical absorption of high- Tc superconductors using powders
- 14 Polaronic theory of mid-infrared conductivity: a numerical cluster study
- 15 Electromagnetic properties of local pair superconductors
- 16 Electron–hole asymmetric polarons
- 17 On the nature of the superconducting state in high-Tc cuprates
- 18 High- Tc superconductivity with polarons and bipolarons: an approach from the insulating states
- 19 Coexistence of small-polaron and Anderson localization in high- Tc superconducting materials
- 20 Concentration and temperature-dependence of magnetic polaron spectra in the t–J model
- 21 Mass enhancement without band-narrowing in t–t′–J and related models: predictions for Fermi-surface and optical conductivity
- 22 Polarons in Peierls–Hubbard models
- 23 Exact estimates of inter-polaron coupling constants resulting in bipolaron formation
- 24 Coulomb interaction and the criteria for bipolaron formation
- 25 Large bipolarons and high-Tc materials
- 26 Collective excitations in the ground state of a two-dimensional attractive Fermi gas
- 27 Strong two-band electron self-trapping, state hybridization effects and related pressure-induced phenomena in semiconductors
- 28 Bismuth disproportionation in super- and semiconducting barium bismuthates
- 29 Magnetic polarons in concentrated and diluted magnetic semiconductors
- 30 Energy scales of exotic superconductors
- Index
Summary
Abstract
The BSC theory is extended to strong electron–phonon coupling for λ > 1. In this limit carriers are charged 2e bosons (singlet and triplet inter-site bipolarons). The Anderson localisation of the bosons resulting from disorder is also considered. Several non Fermi-liquid features of copper-based high-Tc oxides, in particular the spin gap in NMR and neutron scattering, the temperature dependent Hall effect, linear resistivity and divergent Hc2(T) are explained.
The strong-coupling extension of the BCS theory
The electron–phonon coupling constant λ in the BCS theory is the ratio of the characteristic interaction energy V = 2Ep of carriers with a bosonic field, for instance of phonons, which is responsible for the coupling to their kinetic energy EF, λ ⋍ V/(2EF). At the point λ ⋍ 1 the characteristic potential energy due to the local lattice deformation exceeds the kinetic energy. This is a condition of small-polaron formation which has been known for a long time as a solution for a single electron on a lattice coupled with lattice vibrations. So long as λ > 1 the kinetic energy remains smaller than the interaction energy and a self-consistent treatment of a many-electron system strongly coupled with phonons is possible with the ‘1/λ’ expansion technique [1]. This possibility results from the fact, which has been known for a long time, that there is an exact solution for a single electron in the strong-coupling limit λ rarr; infin. Following Lang and Firsov (1962) one can apply the canonical transformation exp (S1) to diagonalise the single-electron Fröhlich Hamiltonian (under the ‘Fröhlich Hamiltonian’ we assume that any electron–phonon interaction occurs with its matrix element depending on the phonon momentum).
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- Publisher: Cambridge University PressPrint publication year: 1995
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