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triple layer theory

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11 - Three-Layer Complexation
from PART I - EQUILIBRIUM IN NATURAL WATERS
Craig M. Bethke, University of Illinois, Urbana-Champaign
Book:

Geochemical and Biogeochemical Reaction Modeling

Published online:

09 December 2021

Print publication:

06 January 2022, pp 147-156
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Summary

Surface complexation is the process by which aqueous species react chemically with specific sites at the aqueous–solid interface to form surface complexes. This chapter describes in detail electrostatic triple-layer theory and its cousin the CD-MUSIC model, and how the methods can be integrated into multicomponent equilibrium models. A worked example demonstrates how the theory might be applied in the study of natural waters.