The East Asian winter monsoon (EAWM) has a profound effect on the winter climate in East Asia. The modern EAWM variability is tightly linked to the high-latitude Northern Hemisphere climate change through the Siberian High and can also be regulated by the low-latitude El Niño-Southern Oscillation through oceanic or atmospheric teleconnections. However, the Quaternary EAWM evolution has long been only attributed to the high-latitude climate change, resulting in the uncertainty in interpreting the out-of-phased EAWM variation recording in the East Asian continent and marginal seas. Here we presented a sediment record at Integrated Ocean Drilling Program Site U1427 in the southern Japan Sea to reconstruct the EAWM evolution since the last glacial maximum. By combining our record with previous reconstructions and simulations, we found the synchronous relationship between winter monsoon in northern and southern regions of East Asia from ∼24 to 8 ka, but anti-correlated relationship since ∼8 ka. We proposed the winter insolation and Atlantic meridional overturning circulation were the main drivers from last glacial to early Holocene, and then ENSO became a dominant factor in controlling the regional heterogeneity of EAWM evolution in the middle and late Holocene. This research explains much of the controversy in the Quaternary EAWM records and highlights the low-high latitude interaction in East Asian winter climate change.

A prograde sequence of corrensite and chlorite in pelitic rocks of the diagenetic zone, anchizone, and epizone (illite crystallinity indices = 0.17–0.58°Δ2θ) of the Gaspé Peninsula, Quebec, was studied by analytical and transmission electron microscopy (AEM and TEM). The data collectively suggest that diagenesis/metamorphism of chlorite and corrensite follows a sequence of phase transitions, compositional homogenization, and recrystallization, approaching a state of equilibrium for which chlorite is the stable phase.

Corrensite occurs as coalescing, wavy packets of layers intergrown with chlorite and illite in the diagenetic and low-grade anchizonal rocks. Intergrowths of discrete chlorite and corrensite crystals, interstratified packets of chlorite and corrensite layers, terminations of smectite-like layers by chlorite layers, and 2–3 repeats of R2- and R3-ordered chlorite-smectite mixed layers occur. These materials are alteration products of detrital biotite or other precursor phases like trioctahedral smectite. The crystal size and proportion of corrensite decrease significantly from the diagenetic zone to the anchizone. Deformed corrensite is crosscut by straight packets of chlorite and corrensite in the diagenetic sample. Some chlorite occurs as discrete, euhedral to subhedral crystals intergrown with or enclosed by other phases in the absence of corrensite. The crystal size of chlorite and definition of crystal boundaries increase whereas density of crystal imperfections and randomness in orientation decrease with increase in grade of diagenesis/metamorphism. Crystals that are kinked or bent, or display gliding along (001) form low-angle boundaries with relatively defect-free crystals, implying deformation during crystal growth. Abundant well-defined low-angle boundaries associated with dislocations are observed in the higher grade rocks, consistent with a stage of readjustment of crystal boundaries during crystal growth. The AEM analyses show that the corrensite has lower Fe/(Mg + Fe) and Al/(Si + Al) than the coexisting chlorite in the diagenetic sample, and that the ranges of composition of chlorite of different grades overlap and become smaller with increasing grade, implying prograde homogenization.

The data imply that corrensite is a unique phase that is metastable relative to chlorite: its conversion to chlorite occurred at a grade as low as that of the high-grade diagenetic zone. The textural relations suggest that the metamorphic crystallization and recrystallization were coeval with deformation processes due to tectonism, partially modified by subsequent contact metamorphism. The data, combined with those of previous reports, suggest that the Gaspé Ordovician rocks constitute a part of a regional distribution of trioctahedral phyllosilicate-rich rocks in the northern Appalachians. The regional occurrence of abundant chloritic minerals is thus directly related to a specific tectonic regime with precursor sediments largely derived from an andesitic arc system(s).

The Yellow River originates on the Tibetan Plateau and transports vast amounts of terrestrial sediment to the ocean. However, previous studies have not reached a consensus as to when and how the Yellow River first began to flow into the sea. Here we present Sr-Nd-Pb isotope data and a high-resolution clay mineral record of a 200-m-long sediment core recovered from the modern Yellow River delta. The changes in Sr-Nd-Pb isotopic compositions and clay minerals at 0.71 Ma suggest that a larger proportion of sediment was derived from the Yellow River after this time. We propose that the Yellow River has influenced the Bohai Sea since 1.9 Ma (or even earlier), which provides important evidence for an older Yellow River than 1.2 Ma. A significant increase in discharge of Yellow River sediments since 0.71 Ma is due to continuing subsidence of the eastern China coast, the large amplitude of Quaternary sea-level changes, and increased supply of eroded loess during the last 1.0 Ma. After this time, the contribution of local rivers surrounding the Bohai Sea became negligible due to dilution by the huge amounts of Yellow River sediments. These results provide improved constraints on the evolution of the Yellow River and subsequent land-sea fluxes.

Sediment transfer from the interiors of the Himalaya is complex because the archives are influenced by both glacial and monsoonal cycles. To deconvolve the coupling of glacial and monsoonal effects on sediment transfer processes, we investigate the Late Pleistocene–Holocene sediment archive in the Upper Chenab valley. Optically stimulated luminescence (OSL) ages from the archive indicate major aggradation during ca. 20–10 ka. Isotopic fingerprinting using Sr-Nd isotopes in silt fractions together with clast counts in boulder-pebble fractions indicate a decreasing Higher Himalayan sediment flux in the archive with time. Decreasing clast size, increasing clast roundness, increasing matrix to clast ratio, and dominance of the Higher Himalayan sourcing unequivocally suggest strong glacial influence during the initial stages of the archive formation. This evidence also agrees with the existing retreat ages of glaciers in the Upper Chenab valley. Results of our study also show that the upper parts of the archive contain significant fluvial sediment contribution from the Lesser Himalaya, which suggests an active role of the stronger Indian Summer Monsoon (ISM) in the region during the Early Holocene. The apparent decrease in sediment supply from the Higher Himalayan sources could have been due to longer source-to-sink transport in the Early Holocene and/or increased hillslope flux from Lesser Himalayan sources.

We present the first comprehensive detrital zircon U–Pb age dataset from Palaeozoic sandstones of Saudi Arabia, which provides new insights into the erosion history of the East African Orogen and sediment recycling in northern Gondwana. Five main age populations are present in varying amounts in the zircon age spectra, with age peaks at 625 Ma, 775 Ma, 980 Ma, 1840 Ma and 2480 Ma. Mainly igneous rocks of the Arabian–Nubian Shield are suggested to be the most prominent sources for the Ediacaran to middle Tonian zircon grains. Palaeoproterozoic and Archaean grains may be xenocrystic zircons or they have been recycled from older terrigenous sediment. A primary derivation from Palaeoproterozoic and Archaean basement is also possible, as rocks of such age occur in the vicinity. Approximately 4 % of the detrital zircons show Palaeozoic (340–541 Ma) ages. These grains are likely derived from Palaeozoic post-orogenic and anorogenic igneous rocks of NE Africa and Arabia. A few single grains gave up to Eoarchaean (3.6–4.0 Ga) ages, which are the oldest zircons yet described from Arabia and its vicinity. Their origin, however, is yet unknown. Detrital zircons with U–Pb ages of 1.0 Ga are present in varying amounts in all of the samples and are a feature of terrigenous sediment belonging to the Gondwana super-fan system with an East African – Arabian zircon province.

A geochemical and biostratigraphic approach has been applied to investigate the spatial and stratigraphic variability of Palaeogene sandstones from key wells in Taranaki Basin, New Zealand. Chronostratigraphic control is predominantly based on miospore zonation, while differences in the composition of Paleocene and Eocene sandstones are supported by geochemical evidence. Stratigraphic changes are manifested by a significant decrease in Na2O across the New Zealand miospore PM3b/MH1 early Eocene zonal boundary, at approximately 53.5 Ma. The change in Na2O is associated with a decrease in baseline concentrations of many other major (MnO, CaO, TiO2) and trace elements, and is interpreted to reflect a significant change in sandstone maturity. Paleocene sandstones are characterized by abundant plagioclase (albite and locally Na–Ca plagioclase), significant biotite and a range of heavy minerals, while Eocene sandstones are typically quartzose, with K-feldspar dominant over plagioclase, low mica contents and rare heavy minerals comprising a resistant suite. This change could reflect a change in provenance from local plutonic basement during the Paleocene Epoch to relatively quartz- and K-feldspar-rich granitic sources during Eocene time. However, significant quartz enrichment of Eocene sediment was also likely due to transportation reworking/winnowing along the palaeoshoreface and enhanced chemical weathering, driven in part by long-term global warming associated with the Early Eocene Climatic Optimum. The broad-ranging changes in major-element composition overprint local variations in sediment provenance, which are only detectable from the immobile trace-element geochemistry.

87Sr/86Sr ratios and εNd values of detrital particles at International Ocean Discovery Program (IODP) Site U1456 in the Laxmi Basin of the Arabian Sea were measured to trace changes in sediment provenance over glacial–interglacial cycles. Based on the correlation of planktonic foraminiferal (Globigerinoides ruber) δ18O fluctuations with the LR04 stack of benthic foraminifera δ18O values, combined with shipboard biostratigraphic and palaeomagnetic data, the studied interval spans ∼1.2 Ma. Over the past 800 ka, 87Sr/86Sr values ranged from 0.711 to 0.726 while εNd values ranged between −12.5 and −7.3 in the detrital particles. By comparing 87Sr/86Sr ratios and εNd values of the possible sources of river sediments with our data, we found that sediments in the Laxmi Basin were influenced to various degrees by proportions of at least three sediment sources (i.e. Tapi River, Narmada River and Indus River). The Indus River might be a more important contributor to glacial sediments. Although 87Sr/86Sr ratios and εNd values varied quasi-cyclically, this pattern did not correspond precisely to the glacial–interglacial cycles. In particular, low-magnetic-susceptibility (low-MS) intervals coinciding with pelagic carbonates were characterized by low 87Sr/86Sr ratios and high εNd values, whereas high-MS intervals matching turbidite deposits showed high 87Sr/86Sr ratios and low εNd values. Thus, this study reveals that differences in the depositional processes between glacial and interglacial periods, governed by changes in sea level and monsoon activity, are an important factor in deciding 87Sr/86Sr ratios and εNd values of the detrital fraction in the Indus Fan of the Arabian Sea.

Geochemical analysis of acid-insoluble residues derived from white chalks and marl seams of Campanian age from Sussex, UK, has been undertaken. All display a broadly similar <2 μm mineralogical composition consisting of smectite or smectite-rich illite-smectite with subordinate illite and minor amounts of talc. Plots of K2O/Al2O3 and TiO2/Al2O3 indicate that most marl seams have an acid-insoluble residue composition which is slightly different to that of the over- and underlying white chalk, implying that marl seams are primary sedimentary features not formed through white chalk dissolution. On the basis of a negative Eu anomaly and trace element geochemistry one marl seam, the Old Nore Marl, is considered to be volcanically derived and best classified as a bentonite; it is considered to correlate with the bentonite M1 of the north German succession.

The deposits of the Rhine and the Meuse in the Netherlands alternate intheir delta in a complex way. This paper discusses a method to distinguishthe deposits of the Rhine and the Meuse based on the differences in naturalradioactivity of 40K, 238U and 232Th, andthe effect of the age of the deposits on the radiometrie signal. In total,six channel belts of the Rhine and the Meuse were selected for sampling withan approximate age of about 2000, 4000 and 6000 14C years B.P. Ofeach channel belt 5 samples of different lithology were taken: clay (C),clay leads (CL), sandy clay loam (sCL), sandy loam (sL) and sand (S). Allsamples were analysed on organic matter content, grain size, geochemistryand radioactivity of the radionuclides 40K, 238U and 232Th. The radioactivity of the sample is mainly influenced bythe grain size of the sample. Therefore, this signal is divided in partialradioactivities for three grain size fractions – clay (<16 μm), silt (16– 63 μm) and sand (>63 μm) – to make the radiometric fingerprint, whichis independent of the grain size of the sample. These fingerprints show adifference between the Rhine and the Meuse. Additionally, the radiometricsignal strongly depends on the age of the deposits. Remarkably, this trendwith age is opposite in the deposits of the Rhine and the Meuse and oppositein the clay and silt fraction. Because the radiometrie differences betweenthe samples seem more distinct than the geochemical differences, theradiometric fingerprints are more suitable to distinguish the deposits ofthe Rhine and the Meuse. A method is presented to derive the contribution ofthe Rhine and the Meuse in a deposit of unknown origin, assuming that theradiometric fingerprints found are consistent and valid for the Rhine-Meusedelta. To distinguish the deposits of the Rhine and the Meuse, both thegrain size composition and the age of the deposits have to be known.

Data on grain size and heavy mineral composition for surface sediments on the Prydz Bay continental shelf was analysed to identify sediment features and provenance. The grain size composition of surface sediments indicate spatial variations in the glaciomarine environment and the key factors influencing sedimentation, which on the shelf include topography/water depth, currents and icebergs. The study area was divided into two sections by Q-type factor analysis: section I included Prydz Channel, Amery Basin and Svenner Channel, and section II included Four Ladies Bank, Fram Bank and the area in front of the Amery Ice Shelf. Sedimentation in section I is mainly controlled by currents and topography/water depth. However, in section II, icebergs/floating ice masses, the Amery Ice Shelf and currents have prominent effects on sedimentation. The heavy mineral composition indicates that surface sediments on the eastern side of the bay, including Four Ladies Bank, are primarily derived from Princess Elizabeth Land. Sediments in the area in front of the Amery Ice Shelf, Svenner Channel, Amery Basin and Prydz Channel have a mixed source from the eastern regions around the bay, including the Prince Charles Mountains and Princess Elizabeth Land. The contribution from Mac. Robertson Land to sediment at Fram Bank is limited.

Electron microprobe analyses of 128 detrital rutile grains from two Jurassic sandstone samples (Hettangian and Bajocian–Bathonian in age) from hydrocarbon exploration wells on the Norwegian margin confirm that more than 85 % of the rutiles were derived from metapelitic rocks. Zr-in-rutile geothermometry confirms that about 83 % of the rutile was formed under high-grade metamorphism (>750 °C). Sixty-two rutile grains, including 60 of the identified high-temperature rutile population, were also analysed for U–Pb geochronology using SHRIMP. The 206Pb–238U rutile ages range from approximately 485–292 Ma, with a major cluster between 450 and 380 Ma. These data suggest that the detrital rutile was predominantly derived from a felsic source that experienced granulite-facies metamorphism about 450–380 Ma ago. This conclusion is consistent with derivation from high-grade Caledonian metasedimentary rocks, probably the Krummedal sequence in central East Greenland, as previously suggested by an earlier provenance study using conventional heavy mineral analysis, garnet geochemistry and detrital zircon age dating. The present study underscores the importance of rutile geochemistry and geochronology in quantitative single-mineral provenance analysis of clastic sedimentary rocks.

Metasedimentary rocks constitute an important but comparatively poorly understood part of the Antarctic Peninsula. Herein we report single-grain U-Pb detrital-zircon ages from samples of the Trinity Peninsula and Botany Bay Groups of north-western Graham Land. All studied samples are dominated by a large and narrowly defined population of late Palaeozoic zircons. Significant early–middle Palaeozoic and minor Neoproterozoic and Mesoproterozoic sub-populations constitute the majority of pre-Carboniferous grains. These detrital-zircon age populations are consistent with sediment derivation entirely from western Gondwana sources. Despite the clear Gondwana signatures, our data suggest that the Trinity Peninsula Group province was either a parautochthonous peri-Gondwanan terrane later accreted to the Antarctic Peninsula, or a significant topographic barrier precluded voluminous sediment contributions from the interior of Gondwana. Statistical comparisons with similar metasedimentary complexes of southern South America, the South Shetland Islands and eastern New Zealand indicate a diversity of sediment provenance not previously recognized, but may provide a means to better determine the pre-break-up configuration of western Gondwana. Although insufficient to definitively restore Antarctic Peninsula components adjacent to South American complexes, some Trinity Peninsula Group samples exhibit robust affinities to the Miers Bluff Formation in the South Shetland Islands and the Duque de York and Main Range Metamorphic Complexes of the Patagonian Andes.

U–Pb LA–SF–ICP–MS analyses of detrital zircons from a metalitharenite on Inousses Island, Greece, gave major age groups of 310–350, 450–500, 550–700, 900–1050 and 1880–2040 Ma and minor peaks between 2600 and 2800 Ma. The youngest concordant zircon grains of 310–330 Ma indicate the maximum age of deposition to be Late Carboniferous, rather than Ordovician, as had been earlier assumed. The lack of zircon ages between 1.1 and 1.8 Ga, coupled with the occurrence of c. 2-Ga-old zircons, imply a northern Gondwana-derived source. Detrital zircons from a garnet–mica schist on Psara Island yielded a major age group of c. 295–325 Ma and only minor Early Palaeozoic and Late Neoproterozoic ages. The youngest grains around 270 Ma indicate the maximum age of deposition to be Late Permian. The Early Palaeozoic ages support a source from terranes at the southern margin of Laurussia during the Late Palaeozoic and hence clarify the palaeotectonic position of units from the eastern Aegean Sea within the Palaeotethyan realm.

The clay mineralogical composition of a 552 cm long sediment core from Lake Terrasovoje in Amery Oasis, East Antarctica, was analysed and compared with that in surface sediments from other locations in the vicinity. The lower part of the sediment core is formed by sub- and proglacial sediments with a dominance of smectite and illite, and lower amounts of kaolinite and chlorite. The upper part of the core is deposited after 12 500 cal yr bp and mainly composed of illite and kaolinite, with low amounts of smectite and chlorite, such as found in samples from rock outcrops and covering sediments throughout Amery Oasis. The clay composition in the lower section of core Lz1005 suggest that the basin of Lake Terrasovoje was filled by a 150–200 m thickened Nemesis Glacier prior to 12 500 cal yr bp rather than by local ice caps.