The identification and quantification of molecules in interstellar space and atmospheres of planets in the solar systems and in exoplanets rely on spectroscopic methods and laboratory work is essential to provide the community with the spectral features needed to analyse cosmological observations. Rotational spectroscopy in particular, with its intrinsic high resolution, allows the unambiguous identification of biomolecular building blocks and biosignature gases which can be correlated with the origin of life or the identification of habitable planets. We report the extension of the measured rotational transition frequencies of dimethylsulphoxide and its 34S and 13C isotopologues in the millimetre wave range (59.6–78.4 GHz) by use of an absorption spectrometer based on the supersonic expansion technique. Hyperfine patterns related to the methyl group internal rotation were analysed in the microwave range region (6–18 GHz) with a Pulsed Jet Fourier Transform spectrometer at extremely high resolution (2 kHz) and reliable predictions up to 116 GHz are provided. The focus on sulphur-bearing molecules is motivated by the fact that sulphur is largely involved in the intra- and inter-molecular hydrogen bonds in proteins and although it is the 10th most abundant element in the known Universe, understanding its chemistry is still a matter of debate. Moreover, sulphur-bearing molecules, in particular dimethylsulphoxide, have been indicated as possible biosignature gases to be monitored in the search of habitable exoplanets.

Planets orbiting young, active stars are embedded in an environment that is far from being as calm as the present solar neighbourhood. They experience the extreme environments of their host stars, which cannot have been without consequences for young stellar systems and the evolution of Earth-like planets to habitable worlds. Stellar magnetism and the related stellar activity are crucial drivers of ionization, photodissociation, and chemistry. Stellar winds can compress planetary magnetospheres and even strip away the outer layers of their atmospheres, thus having an enormous impact on the atmospheres and the magnetospheres of surrounding exoplanets. Modelling of stellar magnetic fields and their winds is extremely challenging, both from the observational and the theoretical points of view, and only ground breaking advances in observational instrumentation and a deeper theoretical understanding of magnetohydrodynamic processes in stars enable us to model stellar magnetic fields and their winds – and the resulting influence on the atmospheres of surrounding exoplanets – in more and more detail. We have initiated a national and international research network (NFN): ‘Pathways to Habitability – From Disks to Active Stars, Planets to Life’, to address questions on the formation and habitability of environments in young, active stellar/planetary systems. We discuss the work we are carrying out within this project and focus on how stellar evolutionary aspects in relation to activity, magnetic fields and winds influence the erosion of planetary atmospheres in the habitable zone. We present recent results of our theoretical and observational studies based on Zeeman Doppler Imaging (ZDI), field extrapolation methods, wind simulations, and the modeling of planetary upper atmospheres.

Stellar X-ray and extreme ultraviolet (XUV) radiation is an important driver of the escape of planetary atmospheres. Young stars emit high XUV fluxes that decrease as they age. Since the XUV emission of a young star can be orders of magnitude higher compared to an older one, this evolution has to be taken into account when studying the mass-loss history of a planet. The temporal decrease of activity is closely related to the operating magnetic dynamo, which depends on rotation and convection in Sun-like stars. Using a sample of nearby M dwarfs, we study the relations between age, rotation and activity and discuss the influence on planets orbiting these low-mass stars.

The cometary nature of the 1908 Tunguska cosmic body is compatible with the predictions of an analytical theory of the 1908 Tunguska explosion developed in 1976–1979. The theory takes into account the three simultaneously occurring processes, namely aerodynamic destruction of the cosmic body in the Earth's atmosphere, transversal expansion of the crushed mass under the action of pressure gradient on the frontal surface of the body, and an aerodynamic deceleration of crushed expanding mass. The use, for the mechanical parameters of the Tunguska cosmic body, of the characteristics of a cometary nuclei such as that of comet Halley 1986 III and comet Shoemaker – Levy 9 1994, gives parameters of the Tunguska explosion derived from observations of Tunguska event in the Siberian taiga in 1908.

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a greater need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a ‘universal pigment’, it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth-like planets.