The Cloudy photoionization codes have been employed to study a spherically distributed cloud, around an arbitrary planetary nebula, with core temperature 105 K. The ionization factor ${\chi (H)}$
is close to unity, in the inner face of the dusty plasma (DP) cloud, which follows a monotonic declining trend, afterwards. For hydrogen density ${n_H} = 10\;\textrm{c}{\textrm{m}^{ - 3}}$
, an exponentially falling trend of temperature could be noticed. A grain charging$\setminus$
discharging process is also witnessed, which is very common in a DP environment. For ${n_H} = 10\;\textrm{c}{\textrm{m}^{ - 3}}$
, photoionization of grains is more common due to higher photon density; compared with ${n_H} > 10\;\textrm{c}{\textrm{m}^{ - 3}}$
, where the grain–electron acquiring probability is maximum, because of significant electron density. Owing to the electrostatic interactions between the charged grain and the electrons, an unusual trend in temperature has been observed.