Clay minerals were used as indicators for determining the source of sediment in recently dredged harbors along the north shore of Long Island Sound. Amount and characteristics of clay minerals in sediments from the dredged channels were compared to their amount and characteristics in the surrounding soils and in sediments from Long Island Sound. Clay minerals in sediments from the channels were similar in amount and characteristics to clay minerals in sediments from Long Island Sound but differed from those in the surrounding soils in the watershed. Thus, the main source of deposits in the channels is the bottom sediment of Long Island Sound which is transported to the channels by tidal action. These conclusions are supported by recent studies of the bottom currents in the Sound.

Oxygen isotope ratios of <0.1-μm smectite in bottom sediments of the Mississippi River and the Gulf of Mexico near the mouth of the river have been determined to investigate diagenesis of land-derived clay minerals during sedimentation in the sea. No difference was detected in δ18O (SMOW) between the river and the Gulf samples indicating that no smectite alteration or addition of neoformed smectite to the river samples took place during sedimentation. Thus, authigenic minerals in the river sediments cannot make up more than a few tenths of a percent of the bulk sediments.

Similar results were obtained from 3 × 106-yr b.p. sediments buried to 80 to 600 m at Deep Sea Drilling Project site 323, Bellingshausen Abyssal Plain. No significant change with depth was noted in the δ18O of the <0.3-μm size fraction, mostly smectite, of these land-derived sediments. On the basis of the δ18O of the deepest sample, the maximum amount of authigenic minerals in the land-derived sediments during burial in the sea cannot be more than one or two percent of the bulk sediments. Hence, the alteration at seafloor temperatures of 25-45% of the <0.1-μm size clays in 3 × 106 yr b.p. sediments reported in a previous study is not substantiated. The data demonstrate that land-derived smectite is stable in the sea, and that oxygen isotopes can be used to investigate the modes and the temperatures of formation of authigenic smectites in marine sediments that are younger than 25 × 106 yr and that formed below 25°C.

The Upper Pliocene sediments near Lebrija in southern Spain contain commercial deposits of palygorskite and sepiolite. These sediments of continental origin consist chiefly of carbonate, marl, and clay resting on marine Pliocene quartzose sand. The lowest unit, the “Marly-Calcareous Bed,” consists of sepiolite-rich marl associated with concretions and irregular layers of chert, <0.5 m thick, and local diatomite layers, as well as limestone, sandy limestone, marl, and clayey sandstones. This unit has a maximum thickness of 30 m and contains three clay-mineral suites as follows: (1) bottom—sepiolite ± palygorskite; (2) center—sepiolite and palygorskite ± illite; (3) top—palygorskite and illite, ± sepiolite and smectite. Sepiolite decreases and palygorskite and illite increase toward the top, reflecting the composition of detrital material supplied to the basin. Beds 0.5–1 m thick locally and containing 50 to 60% sepiolite have been called “Tierra del Vino” (wine earth) because the material formerly was used to clarify and purify wine. The sepiolite-rich beds are as much as 15 m thick in the eastern part of the area. The upper unit is called the “Palygorskite Bed” because certain layers, 0.3 to 3 m thick, contain 35 to 75% palygorskite. The palygorskite-rich layers are interbedded with limestone and marl, and the entire unit is 15 m thick. The total resource of palygorskite is estimated at about 9 million tonnes.

The sediments are believed to have been deposited in a brackish, lacustrine environment. Originally, tectonic stability and an arid climate favored the formation of sepiolite at about pH 8. Later, after significant weathering of the source rocks, detrital illite was transformed to palygorskite in the Mg- and Si-rich waters. Here, palygorskite was also precipitated directly.

The Porters Creek Formation is mined as an absorbent clay in Illinois, Mississippi, Missouri, and Tennessee. The absorptive properties of the Porters Creek Formation are due to the high content of smectite which constitutes >50% of the minerals present. Analyses of 220 samples of the Porters Creek collected in Illinois, Missouri, and Tennessee indicate that the smectite content is highest on the western side of the Mississippi embayment and that the kaolinite content is highest on the northeastern side. The major influx of detritral clays appears to have entered the embayment from a large river on the northeast side. A major control of the distribution of clay minerals during the time of Porters Creek deposition was differential flocculation of kaolinite, illite, and smectite, as evidenced by the numerous syneresis cracks on bedding planes in the area of greatest kaolinite content. Estimates of the smectite, illite, and kaolinite contents suggest both horizontal and vertical variations among these clay minerals. In certain localities the oxidation of pyrite has created acid conditions, which apparently were conducive to the formation of authigenic halloysite.

Kelps (Phaeophyceae, Laminariales) are ecosystem engineers along Arctic rocky shores. With ongoing climate change, the frequency and intensity of marine heatwaves are increasing. Further, extensive meltwater plumes darken Arctic fjords. Assessing the effect of a sudden temperature increase at the cold-distribution limit of cold-temperate kelp species, we compared the responses of two kelp species (Agarum clathratum, Saccharina latissima) to realistic Arctic summer heatwave scenarios (4–10°C) under low- and high-light conditions (3; 120 μmol photons m−2 s−1) for 12 days. We found high-light causing physiological stress in both species (e.g., lower photosynthetic efficiency of photosystem II), which was enhanced by cold and mitigated by warm temperatures. Under low-light conditions, we found no temperature response, probably due to light limitation. Both species acclimated to light variations by adjusting their chlorophyll a concentration, meeting cellular energy requirements. A. clathratum had ~150% higher phlorotannin concentrations than S. latissima, possibly acting as herbivore-deterrent. Our findings suggest competitive advantages of kelps on different Arctic coasts with ongoing warming: A. clathratum has advantages in future areas, with low-light intensities, and possibly high grazing pressure and S. latissima in areas with high-light intensities and low grazing pressure. Species composition changes might have cascading consequences on ecosystem functioning.

Fine kaolinite suspensions were mixed with unaged or aged FeCl3 in this experiment. The interaction between clay particles and Fe3+ hydrolysis products was studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The proportion of Fe adsorbed was measured and the electrical charge on the clay particles was determined by electrophoresis. The effect of this interaction on flocculation of clay suspensions was investigated in a series of sedimentation tests. The Fe3+ ions acted as counterions when their concentration was low and when unaged FeCl3 solution was used. Otherwise, their hydrolysis complexes acted as a bonding agent between kaolinite particles. The dispersion-flocculation behavior of kaolinite suspensions was found to be in agreement with the theory of Derjaguin, Landau, Verwey and Overbeek (DLVO), as the sedimentation behavior could be predicted from the data of zeta potentials (ζ).

The sedimentation behavior of a fine kaolinite, comprising a substantial proportion of colloidal particles as well as non-colloidal ones, has been studied when fresh FeCl3 or F2(SO4)3 electrolytes are added. The sedimentation behavior depends on the pH and the nature of electrolytes and can be explained qualitatively, in our study, by the theory of Derjaguin, Landau, Verwey, and Overbeek (DLVO theory). Fe helps also to aggregate the kaolinite particles in flocs. Two extreme kinds of qualitative sedimentation have been observed: flocculation-sedimentation and accumulation-sedimentation. However, the transition between the two kinds of sedimentation is quite progressive. The present results are discussed in reference to the DLVO theory and the hydrolysis behavior of Fe electrolytes.

The behavior of fine-grained mineral systems is dependent on pore-fluid characteristics. The systematic analysis of previously published studies supports the development of a fabric map in the pH and ionic concentration space as a working hypothesis. This conceptual study is complemented with an extensive battery of tests where surface charge and particle interactions are controlled through pore-fluid characteristics. The macro-scale tests include sedimentation, viscosity and liquid limit, and involve a wide range of solid volume fractions (suspension to sediment) and strain levels. Experimental results permit the development of an updated fabric map on the pH-ionic concentration space which takes into consideration all experimental results. The fabric map is structured around a critical pH level and a threshold ionic concentration beyond which van der Waals attraction prevails.

The behavior of mineral mixtures can be significantly different from the behavior of the individual components of the mixture due to differences between the mechanical and chemical properties of the individual minerals, and their ensuing effects on interparticle interactions and fabric formation. This study examines mixtures of kaolinite and calcium carbonate at different mass fractions using sedimentation, viscosity, and liquid-limit tests. These macroscale tests represent a wide range of solid-volume fractions and strain levels, with emphasis on high water-content conditions to magnify the effects of electrical forces. The results demonstrate that interparticle interactions depend on mineral surface-fluid effects, particle geometry, relative particle size, and solids content. With small solids contents, the kaolinite/calcium carbonate mixture behavior is a function of electrostatic interactions between oppositely charged mineral particles that promote flocculation; however, with large solids contents, the specific surface area of the minerals is the controlling factor. These results are relevant to many natural soil environments and to the possible development of engineered mineral mixtures for industrial applications.

Eurytrematosis is a disease caused by flukes of the genus Eurytrema. These parasites infect the pancreatic ducts of a wide variety of species, including cattle, sheep and humans. Diagnosing eurytrematosis through the analysis of faecal samples can be difficult because most of the available techniques are considered of low sensitivity. In this context, a modification of the Dennis, Stone and Swanson technique (Belem Sedimentation Technique, BST) was previously developed to increase the probability of detecting infected animals; nevertheless, the values of eggs per gram obtained using the modified technique are generally low. We proposed a modification of the this technique (MBST), to increase the sensitivity and detection rate of infected animals. The objective of this work was to describe MBST and compare it with BST. Faecal samples of 212 clinically healthy animals (174 from cattle and 38 from sheep) from 20 farms were taken by the intra-rectal route and stored at 4°C. The samples were processed using BST and MBST. Positive samples amounted to 55 (25.9%) using BST and 121 (57.1%) using MBST. In the simples from cattle, 52 (29.8%) and 107 (61.4%) were positive in BST and MBST, respectively. In sheep, three (7.8%) and 14 (36.8%) positive samples were obtained in BST and MBST, respectively.The results obtained using the two methods were significantly different, indicating a lack of agreement between their findings. The results suggest that MBST is a more sensitive method to detect Eurytrema spp. eggs in faeces than BST.

A recent survey in the western foothills of the Zagros Mountains has located five new Neolithic sites. We present here the occupational features and finds of this period in the Sar Pol-e Zahāb region, along with an interpretation of their distribution and associated settlement patterns. Our research indicates that the visible distribution of Neolithic sites is highly influenced by geomorphological factors. All sites are located on natural outcrops or on the edge of alluvial plains. Many others have certainly been buried beneath layers of later sedimentation. All of the sites identified by our survey are small and of modest elevation, with cultural remains, particularly ceramics, similar to Neolithic sites such as Guran and Sarāb in the central Zagros region and Jarmo and Tamarkhan in Mesopotamia. Based on the ceramic evidence and the location of the region, between the central Zagros mountains on the east and Mesopotamia on the west, we suggest that this vast area maintained an integrated ceramic tradition, which suggests an overall cultural homogeneity of these areas during the seventh and early sixth millennia B.C. In other words, these recent discoveries indicate that similarities in Neolithic material culture in the Māhidasht, Kermanshāh and Hulailan plains with material culture of regions in Mesopotamia are not accidental or random but indicative of a large coherent zone with unique ceramic and cultural traditions (the patterned ceramic tradition of Sarāb-Jarmo), extending from Iraqi Kurdistan east into the central Zagros range. Regarding the lack of eighth and seventh millennium B.C. sites in the northern reaches of the Iranian part of the Zagros range, we may consider the pathway of Sar Pol-e Zahāb a primary route for transporting obsidian to upland areas of the central Zagros. This also suggests a lasting network of cross-regional communications, since archaeological discoveries prove this pathway was the main node connecting these two cultural regions for a long period of time.

The White Sea being connected with the Arctic Ocean via the Barents Sea has an influence on its water temperature/salinity structures and biological processes and thus has an indirect impact on the Eurasian climate system. In this work, we have managed to find a correspondence between the climate fluctuation in the Holocene and changes in the geochemical and microfossil properties in the sediment core of the White Sea. For the first time, the element speciation in the sediment core covering about 10,000 cal yr BP period was investigated. The cooling periods (the early Holocene and the Subboreal stage) were characterized by a trend of increase in Si, Al, and Ti contents and Ti/Al ratios, which reflect lithogenous contribution, and decrease in geochemically labile forms of trace elements. A significant increase in the content of organic-bound trace elements and biogenic components (Сorg, BSi, and chlorin) was observed during periods of Holocene climatic optimums. The evident relationship between the metal speciation and indicators of the sedimentation paleoenvironment is observed at the stage of the active phase of early diagenesis after the slowing down of the biogeochemical processes. Down-core decrease in the Mn oxyhydroxide content exhibited a weakening of diagenesis processes at the ~130–150 cm depth.

The Wadden Sea is a unique coastal wetland containing an uninterrupted stretch of tidal flats that span a distance of nearly 500km along the North Sea coast from the Netherlands to Denmark. The development of this system is under pressure of climate change and especially the associated acceleration in sea-level rise (SLR). Sustainable management of the system to ensure safety against flooding of the hinterland, to protect the environmental value and to optimise the economic activities in the area requires predictions of the future morphological development.

The Dutch Wadden Sea has been accreting by importing sediment from the ebb-tidal deltas and the North Sea coasts of the barrier islands. The average accretion rate since 1926 has been higher than that of the local relative SLR. The large sediment imports are predominantly caused by the damming of the Zuiderzee and Lauwerszee rather than due to response to this rise in sea level. The intertidal flats in all tidal basins increased in height to compensate for SLR.

The barrier islands, the ebb-tidal deltas and the tidal basins that comprise tidal channels and flats together form a sediment-sharing system. The residual sediment transport between a tidal basin and its ebb-tidal delta through the tidal inlet is influenced by different processes and mechanisms. In the Dutch Wadden Sea, residual flow, tidal asymmetry and dispersion are dominant. The interaction between tidal channels and tidal flats is governed by both tides and waves. The height of the tidal flats is the result of the balance between sand supply by the tide and resuspension by waves.

At present, long-term modelling for evaluating the effects of accelerated SLR mainly relies on aggregated models. These models are used to evaluate the maximum rates of sediment import into the tidal basins in the Dutch Wadden Sea. These maximum rates are compared to the combined scenarios of SLR and extraction-induced subsidence, in order to explore the future state of the Dutch Wadden Sea.

For the near future, up to 2030, the effect of accelerated SLR will be limited and hardly noticeable. Over the long term, by the year 2100, the effect depends on the SLR scenarios. According to the low-end scenario, there will be hardly any effect due to SLR until 2100, whereas according to the high-end scenario the effect will be noticeable already in 2050.

This paper presents new geological data from two terp excavations at Englum and Ezinge, in the Dutch province of Groningen, and compares them to similar data from the western part of Friesland, in particular from the terp of Wijnaldum-Tjitsma. This terp is situated at a salt marsh ridge of the same height and thickness as Englum and Ezinge, although habitation started 650 years later at Wijnaldum. The measured levels of the tidal-flat/salt-marsh boundary underneath these terps make it possible to reconstruct palaeo-Mean High Water (MHW) levels. These sea-level index points show that palaeo-MHW in the Groningen part of the Wadden Sea was at the upper limit of the range of palaeo-MHW that has been reconstructed for the Dutch Wadden Sea on the basis of data from its western part. The deviating levels indicate that there are differences between regions of the Wadden Sea; this has earlier been established for the German section of the Wadden Sea. In the eastern part of the Dutch Wadden Sea, MHW nowadays is considerably higher than in the western part of the Wadden Sea; the data suggest that this may have been the case already in the 1st millennium BC. Salt marsh levels under dated terp layers make it possible to establish the rate of sedimentation of the developing salt marsh, at 23–91 cm per century for the pioneer zone and low marsh. This rate of development slowed to 4–5 cm per century for the middle marsh and 3–4 cm per century for the high salt marsh.