Chemical activity diagrarns, prepared to illustrate the properties expected if mixed-layer mont-morillonite/illite is regarded as a solid solution, are compared to those derived from a treatment of these materials as a mixture of two phases. If the system is a solid solution, the coexisting aqueous solution should range from higher dissolved silica contents in the presence of kaolinite and a montmorillonite end member to lower dissolved silica in the presence of kaolinite and an illitic end member. Silica concentration in the aqueous solution might vary by a factor of as much as six. If the system is two phase, the silica content of a solution in equilibrium with kaolinite and both phases would be fixed at a given T and P, as would a solution equilibrated with both phases and K-feldspar. In the absence of a third phase, silica in equilibrium with both phases should be nearly constant, but increase with increasing ratio of K+/H+ in solution. Available data on coexisting aqueous solutions apparently are more nearly consistent with two phases than with a solid solution.

This paper presents a novel concept in the thermodynamic derivation of phase diagrams for clay minerals that incorporates fuzzy transition zones. This new technique yields phase diagrams that have graded (fuzzy) zones of mineral occurrences and includes compositional variability within mineral groups. For the construction of these diagrams, 170 minerals belonging to nine different subgroups were used, based on a fuzzy mathematical description of their ‘grades’ or ‘belonging-ness’. Standard free energies of formation of all the minerals were derived and all possible pairs of mineral equilibria were evaluated. Relative intensities of mineral occurrences were determined and membership values of each type of mineral at various zones in a 2D or 3D space were graphically represented. Computations and graphical representations were carried out using programs developed in Mathematica. Diagrams were derived for 25°C, 1 bar with a solution phase containing Si(OH)4, K+, Na+, H+, Ca2+ and Mg2+ under conditions of gibbsite, goethite and ferrous oxide saturation. The resulting diagrams, unlike conventional phase diagrams, show multimineral assemblages, with varying occurrences of different minerals and provide a realistic representation of clay mineral occurrences formed by surface geochemical processes. They show that on the Earth’s surface, only montmorillonite can almost completely predominate the inorganic phase followed by kaolinite, illite and beidellite. Nontronite, glauconite, celadonite and vermiculite would not be neoformed in substantial amounts. A general conformity of derived phase equilibria with experimentally observed equilibria is also observed.

The recent observation of spectacular photocatalytic activity enhancements generated tremendous interest in the synthesis, properties, and potential applications of black titania. Most black titania are core–shell structures consisting of a perfect crystalline core surrounded by a defective surface shell. Because the properties are attributed to the defective shell, it is particularly important, but very challenging, to obtain atomic structure information of the core, the shell, and the core–shell relationship on a single particle level. While the role of various synthesis approaches for producing black titania with different properties has been extensively reviewed, this review focuses on understanding the structure–functionality relationship in black titania on a single particle level. We start by introducing the crystal and electronic band structure of different TiO2 phases, followed by the discussion of particle size effects, the origin of lattice distortions, and phase control by synthesis, and concluding with the discussion of crystalline order formation and evolution creating the defective shell.

The present paper is concerned with a historical puzzle: the changing position of the marker si in the extant Baltic languages, Lithuanian and Latvian. Si appears before the root in prefixed verbs and verb-finally in prefixless verbs in Lithuanian and dialectal Latvian, as opposed to a consistently verb-final position in standard Latvian and in Slavic languages, specifically Russian. This ordering is examined within a larger picture of morpheme linearization – focusing primarily on Lithuanian, but also bringing in Latvian and Latgalian data – to account for the Baltic paradigm. Historically a pronoun, si is argued to have incorporated into the verbal structure, and to maintain nowadays a binding relation with the subject of the sentence. The placement of si within the verb is shown to depend on two factors: the type of the antecedent and the morphosyntactic composition of the verb. The findings presented here also provide new evidence against the Lexicalist Hypothesis.

Downsizing as a systematic reduction of employees is frequently utilized in order to increase productivity, efficiency, profitability, and competitiveness of organizations. As a strategy of choice for many firms around the world, downsizing produces far-reaching financial, organizational, and social consequences. Despite the large body of literature, there is inconclusive evidence as to whether downsizing is effective and whether it generates the widely anticipated benefits. Employee downsizing as a change management strategy has been actively adopted for more than three decades. This downsizing article presents a phase typology of job cutting including three distinct phases and three levels of argument. As a conceptual paper, it aims to examine, update, and extend Littler and Gandolfi's (2008) seminal work. The research paper culminates with a discussion of current downsizing practices, and posits that the downsizing phenomenon has remained a popular restructuring.

The electron energy loss spectroscopy (EELS) technique was applied to investigate the local variation in the phase of barium titanate (BaTiO3) ceramics. It was found that the fine structure of the titanium L2,3 edge and their satellite peaks were sensitively varied with the tetragonal–cubic phase transition. The peak splitting of Ti-L3 edge of tetragonal-phased BaTiO3 ceramics was widened because of the increased crystal field effect compared with that of cubic-phased BaTiO3. In case of nanoscale BaTiO3 powders, the L3 edge splitting of the core region was found to be smaller than that of the shell region. The energy gap between peaks t2g and eg varied from 2.36 to 1.94 eV with changing the probe position from 1 to 20 nm from the surface. These results suggest that the EELS technique can be used to identify the local phase of sintered BaTiO3 ceramics.

The ‘coupon collection problem’ refers to a class of occupancy problems in which j identical items are distributed, independently and at random, to n cells, with no restrictions on multiple occupancy. Identifying the cells as coupons, a coupon is ‘collected’ if the cell is occupied by one or more of the distributed items; thus, some coupons may never be collected, whereas others may be collected once or twice or more. We call the number of coupons collected exactly r times coupons of type r. The coupon collection model we consider is general, in that a random number of purchases occurs at each stage of collecting a large number of coupons; the sample sizes at each stage are independent and identically distributed according to a sampling distribution. The joint behavior of the various types is an intricate problem. In fact, there is a variety of joint central limit theorems (and other limit laws) that arise according to the interrelation between the mean, variance, and range of the sampling distribution, and of course the phase (how far we are in the collection processes). According to an appropriate combination of the mean of the sampling distribution and the number of available coupons, the phase is sublinear, linear, or superlinear. In the sublinear phase, the normalization that produces a Gaussian limit law for uncollected coupons can be used to obtain a multivariate central limit law for at most two other types — depending on the rates of growth of the mean and variance of the sampling distribution, we may have a joint central limit theorem between types 0 and 1, or between types 0, 1, and 2. In the linear phase we have a multivariate central limit theorem among the types 0, 1,…, k for any fixed k.

The electroretinographic response to L- and M-cone isolating stimuli was measured at different luminance levels to study the effect of retinal illuminance on amplitude and phase, and how this may influence estimates of L:M ratios in the retina. It was found that the amplitude of L- and M-cone driven responses increases differently with increasing retinal illuminance: L-cone responses increase more quickly than those of M-cones. The L:M ratio does not change strongly with retinal illuminance. The phase of both L- and M-cone driven responses advances with increasing retinal illuminance. There is considerable interindividual variability in the phase difference between the two, but generally M-cone driven responses are phase advanced.

The traditional feeding programmes and nutrient requirements of broilers, as established by the NRC, are usually based upon age and fixed growing duration. This is despite the fact that broiler growth pattern characteristics have changed enormously over last decade. Such classical approaches have been questioned as to their effectiveness, and it has been argued the NRC recommendations are no longer applicable to the present methods of production, and need to be re-evaluated. The short comings of traditional or classical fixed duration of feeding phases have led many investigators to suggest and introduce alternative feeding programmes in replacement, including alternative, phase, sequential, choice, dual and subsequent feeding. The effectiveness and shortcomings of such methods are analysed in this review.

The levels of lipophorin, the principal insect haemolymph lipoprotein, were estimated during the development of solitary and gregarious phases of Schistocerca gregaria using single radial immunodiffusion. In the gregarious phase, lipophorin titres ranged from 6.69 ± 0.57 mg/ml in the 3rd nymphal instar to 14.42 ± 2.04 mg/ml in mature adults. The titres in the solitary phase were 3.33 ± 0.59 mg/ml in the 3rd nymphal instar and 8.44 ± 0.67 mg/ml in mature adults. Peak lipophorin titres occurred in mature adults (14.42 ± 2.04 mg/ml) and 5th nymphal instar (8.75 ± 0.25 mg/ml) for gregarious and solitary locusts, respectively. Gregarious locusts had significantly (P< 0.05) higher lipophorin titres than their solitary counterparts during the 3rd and 4th nymphal instars as well as in the adult stage (P< 0.01). Estimation of the haemolymph protein levels over the same period showed a general increase from the 3rd nymphal instar to mature adult stage in both phases. It is proposed that the higher lipophorin titre in gregarious locusts is a physiological adaptation that ensures high lipid reserves that are necessary to cope with the high metabolic requirements of this phase.

The influence of the level of prestimulus alpha phase synchronicity on the N100 component and reaction time (RT) was examined, in target auditory oddball data from 25 normal subjects. Alpha phase synchronicity is a new measure consisting (for a given stimulus presentation) of the angular or circular variance of the alpha phase at stimulus onset across the parieto-occipital sites. The lower the angular variance, the higher the phase synchronicity (the more closely in phase the alpha activity across these sites) and vice versa. Subaveraged event-related potentials (ERPs) were formed for high and low prestimulus alpha phase synchronicity stimulus presentations. N100 amplitude was significantly greater in the high than the low phase synchronicity subaverages. In addition, RT was significantly reduced in the high prestimulus alpha phase synchronicity cases. Alpha phase synchronicity reflects an aspect of brain state that influences subsequent stimulus processing.

A linear process is generated by applying a linear filter to independent, identically distributed random variables. Only the modulus of the frequency response function can be estimated if only the linear process is observed and if the independent identically distributed random variables are Gaussian. In this case a number of distinct but related problems coalesce and the usual discussion of these problems assumes, for example, in the case of a moving average that the zeros of the polynomial given by the filter have modulus greater than one. However, if the independent identically distributed random variables are non-Gaussian, these problems become distinct and one can estimate the transfer function under appropriate conditions except for a possible linear phase shift by using higher-order spectral estimates.