The Alto dos Quintos Mine, Rio Grande do Norte, northeast region of Brazil, is one of the few mines where a LCT (Li-Cs-Ta-enriched) pegmatite is exploited for the deep blue gemstone called “Paraiba Tourmaline (PT)”. Blue cuprian elbaite, a fault-bound pink montmorillonite bearing some relict apatite and newly-formed Ca-Al-phosphate of the Al-P-sulphate group (APS minerals) also occur in the underground mine. The montmorillonite was studied using extended clay mineralogical tools (XRD, IR spectroscopy, XRF, SEM-EDX, cation exchange capacity (CEC), DTA). The structural formula method for calculation of the smectite formula based on EDX data yielded an extremely Fe-poor montmorillonite: (Ca0.22+)(Al1.7Fe0.0Mg0.4)(Si3.8Al0.2). The charge on the tetrahedral sheets accounts for approximately 30% of the total permanent negative charge. However, based on the more precise Hofmann & Klemen test, tetrahedral charge values of 11% to 13% were calculated. This is indicative of the dominance of montmorillonite rather than beidellite among the smectite minerals, which is independently proved by a pronounced IR band at 630 cm-1. The formation of pink montmorillonite is not directly related to the emplacement of the Li-bearing PT pegmatite. The sheet silicate developed after a considerable hiatus (Mesozoic?), when the Neoproterozoic pegmatites had already undergone different stages of hypogene (cookeite) and supergene (illite, kaolinite) alteration, during which Li was flushed out to a degree that formation conditions of expandable Li-bearing phyllosilicates were no longer favoured. The nature of the pinkish tint is not yet clarified. The montmorillonite formed in a temperature regime close to 250°C, when apatite was transformed into Ca-bearing APS minerals under acidic conditions. Cainozoic volcanic activity and the reactivation of deep-seated fault zones are considered to be responsible for the formation of this pink P-bearing montmorillonitic clay.

Cretaceous and Cainozoic granites and rhyolites in the northwestern U.S.A. provide a record of silicic magmatism related to diverse tectonic settings and large-scale variations in crustal structure. The Late Cretaceous Idaho Batholith is a tonalitic to granitic Cordilleran batholith that was produced during plate convergence. Rocks of the batholith tend to be sodic (Na2O > K2O), with fractionated HREE, negligible Eu anomalies, and high Sr contents, suggesting their generation from relatively mafic sources at a depth sufficient to stabilise garnet. In contrast, Neogene rhyolites of the Snake River Plain, which erupted in an extensional environment, are potassic (K2O > Na2O), with unfractionated HREE patterns, negative Eu anomalies, and low Sr contents, suggesting a shallower, more feldspathic source with abundant plagioclase. Eocene age volcanic and plutonic rocks have compositions transi- tional between those of the Cretaceous batholith and the Neogene rhyolites. These data are consistent with a progressively shallowing locus of silicic magma generation as the tectonic regime changed from convergence to extension.