In 2001, five French public organizations (CNRS, CEA, IRD, IRSN, and the Ministère de la Culture) signed an agreement to purchase a new accelerator mass spectrometer to provide radiocarbon dating services at the national level. The Laboratoire de Mesure du Carbone 14 (LMC14) was set up in Saclay (France) around ARTEMIS, an AMS system based on a 3MV Pelletron from NEC and installed in early 2003. In 2015, the LMC14 joined the Laboratoire des Sciences du Climat et de l’Environnement, making it possible to develop research projects in addition to the service activity and since 2021, the LMC14 has been a member of the IAEA Collaborating Centre “Atoms for Heritage” at the Université Paris-Saclay. Since 2003, 70,000 samples have been measured. Two-thirds of the samples have been prepared on site and one-third in two associated laboratories in Paris and Lyon. Over the past years, the LMC14 has participated in several international inter-comparisons and has continuously improved its capabilities by developing new protocols for preparation and measurement. In this paper, the radiocarbon dating services of the last 20 years for research institutions, museums and environmental monitoring are reviewed and recent results from environmental and archaeological research programs are highlighted.

Extensively worked in antiquity, Skouriotissa remains the only active copper mine on the island of Cyprus. The modern, open-cast operation, however, has almost completely obliterated the earlier mining landscape. Here the authors report the results of investigations, including dating, of the ancient topography of the mine. They incorporate spatial data derived from archival sources, recent fieldwork and absolute dating into a geographical information system to reconstruct the ancient mining landscape around Skouriotissa. Their approach holds promise for understanding other mining regions in Cyprus and beyond, by providing an example of how diverse source material can be used to reconstruct landscapes now destroyed or buried by open-cast mining operations.

The extraction and smelting of the rich copper ore deposits of Cyprus and the manufacture of copper objects on the island are thought to have begun during the Philia phase (c. 2400–2200 BC). Here, the authors present the results of lead isotope analysis undertaken on Late Chalcolithic (2900–2400 BC) metal objects from the site of Chlorakas-Palloures. The results facilitate a reassessment of the timing of the start of transformative copper technologies on Cyprus and the re-evaluation of contemporaneous copper artefacts from Jordan and Crete previously suggested to have been consistent with Cypriot ores. They conclude that there is no compelling evidence for transformative metallurgy in Chalcolithic Cyprus.

The Old Copper Complex (OCC) refers to the production of heavy copper-tool technology by Archaic Native American societies in the Lake Superior region. To better define the timing of the OCC, we evaluated 53 (eight new and 45 published) radiocarbon (14C) dates associated with copper artifacts and mines. We compared these dates to six lake sediment-based chronologies of copper mining and annealing in the Michigan Copper District. 14C dates grouped by archaeological context show that cremation remains, and wood and cordage embedded in copper artifacts have ages that overlap with the timing of high lead (Pb) concentrations in lake sediment. In contrast, dates in stratigraphic association and from mines are younger than those from embedded and cremation materials, suggesting that the former groups reflect the timing of processes that occurred post-abandonment. The comparatively young dates obtained from copper mines therefore likely reflect abandonment and infill of the mines rather than active use. Excluding three anomalously young samples, the ages of embedded organic material associated with 15 OCC copper artifacts range from 8500 to 3580 cal BP, confirming that the OCC is among the oldest known metalworking societies in the world.

The Great Orme Bronze Age copper mine in Wales is one of Europe's largest, although its size has been attributed to a small-scale, seasonal labour force working for nearly a millennium. Here, the authors report the results of interdisciplinary research that provides evidence that Great Orme was the focus of Britain's first mining boom, c. 1600–1400 BC, probably involving a full-time mining community and the wide distribution of metalwork from Brittany to Sweden. This new interpretation suggests greater integration than previously suspected of Great Orme metal into the European Bronze Age trade/exchange networks, as well as more complex local and regional socio-economic interactions.

Luristan Iron Mask Swords have been recovered mostly from illegal diggings in the 1920s. The about 90 known objects are characterized by a disk-shaped pommel on the top of the handle with two mounted bearded heads on two sides. According to the similarity in form and radiocarbon (14C) measurements on two swords from museum collections, an overall short production period was assumed around 1000 BC (Moorey 1991; Rehder 1991). Here we present the results of metallurgical analysis and 14C measurements for three newly acquired Luristan swords, which were donated to the Royal Museums of Art & History, Brussels. Metallurgical analysis indicates an iron production via the bloomary furnace technique. Analyzed samples show large slag inclusions (Fayalite, Wüstite, glass) within a mostly ferritic and pearlitic iron. The carbon contents varied between 0.2 wt% to around 0.8 wt%). 14C measurements on thermally extracted carbon give 14C ages between 2800 BP–3360 BP (calibrated ∼1745 BC–900 BC). The reliability of the 14C measurements are discussed with respect to external (contamination during handling) and intrinsic contamination (e.g. fossil carbon sources during manufacture).

Meroe is one of Africa's most famous archaeological sites, renowned not least for its evidence of ironworking. Yet, the extensive slagheaps that characterise the site have received little archaeological attention. To illuminate the chronology and distribution of these remains, this article combines extant excavation data with the results of recent site-wide surface and geoprospection survey, and ongoing slagheap excavation and radiocarbon dating. The slagheaps date predominantly to either the Early (Napatan) or Late (late/post-Meroitic) periods, with little evidence for activity between c. 300 BC and AD 300—precisely when Meroe was the capital of the Kingdom of Kush—indicating significant reorganisation of the city's industrial base at this time.

The technique of depletion gilding is well evidenced in pre-Columbian Andean gold work. Artefacts from the Nahuange period in Colombia (c. AD 100–1000) were subject to metallographic, chemical and microscopic analyses to provide regional comparative data on metalworking traditions. Results suggest that depletion gilding may have been an accidental discovery and, contrary to widespread assumptions, not always a desirable feature. This research illustrates how technological innovation may not always be immediately adopted, and considers how the life-history of gold artefacts may affect their appearance and microstructure. It also offers directions for future studies of depletion gilding elsewhere.

The large number of iron-laden wrecked ships discovered off Saintes-Maries-de-la-Mer (south of France) since the 1990s has enriched our knowledge of both maritime trade in the Mediterranean and the ferrous bars used during antiquity. This exceptional corpus has spawned numerous studies in the fields of archaeology, history, and archaeometallurgy, but, despite a relatively well-documented context, the chronology of wrecks is still to be clarified. Until recently, the chronology of the corpus was mainly supported by the archaeological remains found in the cargo of the wrecks, resulting in a chronological range from the 1st century BC to the 1st century AD. However, the 14C dating of an iron bar from Saintes-Maries-de-la-Mer, older by more than a century from the expected chronological range, has revived discussions about the chronology of all the wrecks. Thanks to the development of a new protocol for dating ferrous alloys, based on an extensive study of the ferrous material, 34 samples of iron extracted from 13 ferrous bars constituting the cargo of seven ships could be 14C dated. The 14C results and the archaeological and historical data were subjected to Bayesian analysis to build a chronological framework for the antique shipwrecks of Saintes-Maries-de-la-Mer. It appears that all these ships could belong to a larger phase than the one deduced from archaeological remains alone. Consequently, this study helps to support a new vision of the trade between the northeastern Mediterranean and western Europe.

Bivalve bronze moulds were used for casting bronze and lead objects – mainly axes – during the Middle and Late Bronze Age. These remarkable artefacts, which were sometimes beautifully decorated, have been surprisingly little studied. This paper discusses the bronze moulds from Britain, outlining the range of possibilities that existed for the life courses of these objects during the three broad stages of manufacture, use, and deposition. Two points will be emphasised. First, it will be shown that the biographical pathways available to bronze moulds differed significantly from those of moulds made from stone or clay, which may relate to the differing properties and conceptual associations of these three materials. Secondly, the relationships between the life courses of bronze moulds and the artefacts cast in them will be explored, focusing particularly on cases in which moulds and their castings were deposited together in the same hoard. It will be suggested that the ‘genealogical’ link between a mould and its ‘offspring’ could have formed a significant element of the biography of both objects.

Early Iron Age pastoralists of the Eurasian steppes relied heavily on copper for weapons and ornaments, and new analysis of metal composition enables long-distance networks to be identified. Primary circulation from source areas where copper was mined can be distinguished alongside the secondary circulation of alloy types with high proportions of tin-bronze or leaded tin-bronze. The relative presence of trace elements, depleted during recycling events, provides a proxy for the flow of metal between regions. The localised seasonal movements characteristic of these mobile steppe societies underlie some of these patterns, but the evidence also indicates more extensive transfers, including the direct movement of finished objects over considerable distances.

For many years, archaeologists and archaeometallurgists have suggested that recycled copper might have constituted a significant component of the metal in circulation in Britain during the first millennium AD. They have generally failed, however, to suggest a way of observing and quantifying this phenomenon. Here the authors propose a new methodology to rectify this. A large new database of chemical analyses of British copper alloys dating from the late Iron Age to the early medieval period demonstrates the potential of their approach; it shows that significant and measureable changes occur in metal circulation at the beginning of the first century AD and in the early Saxon period.

Studies on cultural metal artifacts can benefit greatly from microscopy techniques. The examination of microstructural features can provide relevant information about ancient manufacturing techniques, as well as about corrosion/degradation processes. In the present work, advantages of the use of multifocus imaging techniques in optical microscopy for the study of archaeological metals are presented. An archaeometallurgical study of a large collection of bronzes demonstrates the possibility of a microstructural study with no need for sample removal, which is a great advantage in the study of cultural objects. In addition, the study of mounted samples illustrates the advantages of the multifocus technique in the examination of particular corrosion features, with the possibility of three-dimensional reconstructions.

Chemical analysis of the stunning Muisca metalwork shows that the alloys of copper and gold were especially composed for each offering. Traditionally, the Muisca objects have been collected and studied as works of art. Our authors show that when it comes to drawing understanding of people from the objects they have left us, context is all. The results have much to reveal to metallurgists and students of symbolic metalwork everywhere.

Recent excavations in southern Jordan have revealed the largest Early Bronze Age (c. 3600-2000 BC) metal manufactory in the ancient Near East. On-site Geographic Information Systems (GIS) analyses of the finds provide new evidence concerning the scale and organization of metal production at a time when the first cities emerged in this part of the Near East. Materials and lead isotope analyses of the metallurgical finds provide important data for reconstructing ancient metal processing and for identifying trade networks.