We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.
To save content items to your account,
please confirm that you agree to abide by our usage policies.
If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account.
Find out more about saving content to .
To save content items to your Kindle, first ensure [email protected]
is added to your Approved Personal Document E-mail List under your Personal Document Settings
on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part
of your Kindle email address below.
Find out more about saving to your Kindle.
Note you can select to save to either the @free.kindle.com or @kindle.com variations.
‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi.
‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.
Kinetic theory is defined as a branch of statistical mechanics that attempts to describethe non-equilibrium properties of macroscopic systems in terms of microscopic propertiesof the constituent particles or quantum excitations. The history of kinetic theory is summarizedfrom the first understandings of the connections of temperature and pressure ofperfect gases with their average kinetic energy and with the average momentum transferto the walls by particle-wall collisions. The history continues with a discussion of the contributionsof Maxwell and Boltzmann, and the development of the Boltzmann transportequation. Modern developments include extending the Boltzmann equation to moderatelydense gases, formulation of kinetic theory for hard sphere systems, discovery of long timetail contributions to the Green-Kubo expressions for transport coefficients, applications ofkinetic theory to fluctuations in gases, to quantum gases and to granular particles. Thecontents of each chapter are then summarized.
Boltzmann’s transport equation for a dilute gas with particles interacting with central, short range forces, and with bounding walls, is derived in detail, with emphasis on the use of the Stosszahlansatz. Boltzmann’s H–theorem is presented as a microscopic derivation of the law of entropy increase in non–equilibrium processes, and the Maxwell–Boltzmann equilibrium distribution is derived. Zermelo’s and Loschmidt’s arguments that the H–theorem is incompatible with the laws of mechanics are given and discussed. The Kac ring model is presented and used as a simple way to understand the application and the limitations of the Stosszahlansatz. It is concluded that the Boltzmann equation is statistical, rather than strictly mechanical, in nature, providing a description of the most probable non–equilibrium behavior of a dilute gas.
Recommend this
Email your librarian or administrator to recommend adding this to your organisation's collection.