The Turiy Massif, on the southern coast of the Kola Peninsula, consists of five intrusive complexes containing a variety of carbonatites, phoscorites, melilitolites, ijolites and pyroxenites. Petrographic and mineralogical studies of the different rocks show that the samples are texturally heterogeneous. Minerals including apatite, garnet, magnetite, melilite, mica and pyroxene, show systematic variations in composition relating to the rock type in which they occur. Compositional similarities and/or distinct trends are seen in the mineral compositions within the each of the pyroxenite-melilitolite, and melteigite-ijolite rock series, indicating linked petrogenetic histories within each of the two series. The carbonatites from the northern complex may be related to nearby melilitolites, but the central complex carbonatites and phosocorites do not bear any mineralogical (or isotopic) similarities to any of the silicate rocks within the massif.

Laser Raman spectroscopy is particularly well suited for routine characterization of the crystalline and the better ordered paracrystalline silica phases occurring in silica sinters: opal-C, quartz and moganite. The non-crystalline and poorly ordered paracrystalline silica phases (opal-CT and opal-A) are identified with difficulty, partly as a result of the high level of fluorescence exhibited by the younger sinters that are dominated by these phases, and partly as a result of the ill-defined nature of the broad phonon scattering bands produced by them. Nonetheless, given the limited number of phases present and the high level of phonon scattering from the better ordered phases, judicious use of a Raman microprobe enables the character of most siliceous microtextural sinter components to be determined readily. Microprobe examination of a series of New Zealand sinters, ranging from Late Quaternary to Pliocene in age shows that a silica phase inhomogeneity that exists in some outcrops reflects an underlying phase heterogeneity obtaining in the microstructure of the sinter; it is a consequence of the phase transformation process. In the older sinters, quartz, moganite and opaline cristobalite may be present in a single fabric element but in quite different proportions to their abundance in adjacent elements. Identification of opaline lepispheres partially pseudomorphed by quartz+moganite and the association of quartz+moganite in microcrystals exhibiting common quartz forms, cautions against the use of morphology as a means of identifying silica phases at the microstructural level.

The crystal structure of sahlinite [Pb14(AsO4)2O9Cl4] from Lågban (Sweden) has been refined up to R = 0.071 using single-crystal diffraction data collected at the Elettra synchrotron facility. Sahlinite is monoclinic, space group C2/c, with a = 12.704(4), b = 22.576(5), c = 11.287(4) Å, β = 118.37(3)°. Sahlinite is isostructural with kombatite, its vanadium counterpart. Both are derivatives of the litharge form of PbO. In the structure of sahlinite there are seven independent Pb atoms, which are linked to Cl and/or O atoms, with coordination number ranging from V to VIII. The coordination polyhedra are irregularly shaped, due to the 6s2 lone-pair effect displayed by Pb2+.

Basalts from the volcano-sedimentary Eriksfjord Formation (Gardar Province, South Greenland) were erupted at around 1.2 Ga into rift-related graben structures. The basalts have compositions transitional between tholeiite and alkaline basalt with MgO contents <7 wt.% and they display LREE-enrichment relative to a chondritic source. Most of the trace element and REE characteristics are similar to those of basalts derived from OIB-like mantle sources. Initial 87Sr/86Sr ratios of clinopyroxene separates range from 0.70278 to 0.70383 and initial ϵNd values vary from –3.2 to +2.1. The most unradiogenic samples overlap with the field defined by carbonatites of similar age and can be explained by mixing of isotopically depleted and enriched mantle components. Using AFC modelling equations, the Sr-Nd isotope data of the more radiogenic basalts can successfully be modelled by addition of <5% lower crustal granulite-facies gneisses as contaminants. δ18Ov-smow values of separated clinopyroxene range from +5.2 to +6.0% and fall within the range of typical mantle-derived rocks. However, up to 10% mixing with an average lower crustal component are permitted by the data.

Native palladium is rare and occurs in oxidizing environments (hematite stability field) and consistently has very low contents of other metals. On the other hand, gold may contain significant amounts of alloyed palladium. A nugget of palladian gold, obtained from a specularite-rich auriferous vein (‘jacutinga’) of the Gongo Soco iron ore mine, Quadrilátero Ferrífero, Minas Gerais, allows the definition of a paragenetic sequence of native palladium formation. The cm-sized nugget is brecciated and consists of fragments of palladian gold [Au0.79Pd0.09Cu0.07Ag0.04Hg0.01] with inclusions of isomertieite [Pd11Sb2As2], cemented by kaolinite-hematite-palladian gold infill. The isomertieite inclusions are preferentially fractured and display various degrees of alteration to a Pd-O phase. Native palladium occurs as a crystallized component within the Pd-O phase, with microstructural and chemical features suggesting a desiccation process. It is proposed that native palladium forms by (1) oxidation of a pre-existent palladium mineral to a Pd-O phase, and (2) subsequent crystallization of native palladium from the Pd-O phase, by oxygen loss and dehydration. This process operates in a low-temperature hydrothermal or weathering environment and leads to strong fractionation of palladium and gold.

This review details a selection of occupational lung diseases, particularly fibrosis (scarring) and tumours that can arise following exposure to mineral dusts. Also described are the sequential repair processes of the lung including oedema, inflammation, epithelial changes and finally scarring. The features by which a dust can be considered bioreactive including shape, size, surface area, durability and surface chemistry is discussed together with the importance of the mass deposited in the lung and particle clearance, particularly through lymphatic drainage. Emphasis is given to the importance of surface chemistry in that crystalline minerals, especially silicas, are often highly bioreactive whereas amorphous silicas or crystalline forms that have aged in the laboratory have lesser activity. Nevertheless, all forms of crystalline silica are particularly hazardous with the long-term ability to produce irreversible disease (fibrosis) when administered to experimental animals.

In the Earth’s lithosphere, fungi are of fundamental importance as decomposer organisms, animal and plant pathogens and symbionts (e.g. lichens and mycorrhizas), being ubiquitous in sub-aerial and subsoil environments. The ability of fungi to interact with minerals, metals, metalloids and organic compounds through biomechanical and biochemical processes, makes them ideally suited as biological weathering agents of rock and building stone. They also play a fundamental role in biogeochemical cycling of nutrients, (e.g. C, N, P and S) and metals (e.g. Na, Mg, Ca, Mn, Fe, Cu, Zn, Co and Ni) essential for the growth of living organisms in the biosphere. In addition they play an integral role in the mobilization and immobilization of non-essential metals (e.g. Cs, Al, Cd, Hg and Pb). Most studies on mineral-microbe interactions and microbial involvement in geological processes have concentrated on bacteria and archaea (Prokaryota): fungi (Eukaryota) have, to a certain extent, been neglected. This article addresses the role of fungi in geomicrobiological processes, emphasizing their deteriorative potential on rock, building stone and mineral surfaces and involvement in the formation of secondary mycogenic minerals. Such roles of fungi are also of importance for the global carbon reservoir and have potential biotechnological applications, e.g. in the bioremediation of xenobiotic-, metal- and/or radionuclide-contaminated soils and wastes, and metal/radionuclide recovery.

A thorough assessment of the secondary minerals on 796 Chinese Pb-Cu-Sn-Zn bronze coins from ∼1100 BC to AD 1911 has been made. Malachite is found on more than 80% of the coins irrespective of their dynasties, but a botryoidal texture is only observed on the coins of the Song dynasty or older. Azurite, however, is seen in microscopic quantities on a single coin of ∼AD 1800, but is clearly visible on the Ming dynasty or older coins. Cerussite is a common secondary mineral of the Qin dynasty and older coins, though it has not been found on the Qing dynasty or younger coins. Cuprite is observed on the Song dynasty and older coins.

Carbonatite magmas are considered to be ultimately derived from mantle sources, which may include lithospheric and asthenospheric reservoirs. Isotopic studies of carbonatite magmatism around the globe have typically suggested that more than one source needs to be invoked for generation of the parental melts to carbonatites, often involving the interaction of asthenosphere and lithosphere.

In the rift-related, Proterozoic Gardar Igneous Province of SW Greenland, carbonatite occurs as dykes within the Igaliko Nepheline Syenite Complex, as eruptive rocks and diatremes at Qassiarsuk, as a late plug associated with nepheline syenite at Grønnedal-Íka, and as small bodies associated with ultramafic lamprophyre dykes. The well-known cryolite deposit at Ivittuut was also rich in magmatic carbonate. The carbonatites are derived from the mantle with relatively little crustal contamination, and therefore should provide important information about the mantle sources of Gardar magmas. In particular, they are found intruded both into Archaean and Proterozoic crust, and hence provide a test for the involvement of lithospheric mantle.

A synthesis of new and previously published major and trace element, Sr, Nd, C and O isotope data for carbonatites and associated lamprophyres from the Gardar Province is presented. The majority of Gardar carbonatites and lamprophyres have consistent geochemical and isotopic signatures that are similar to those typically found in ocean island basalts. The geochemical characteristics of the two suites of magmas are similar enough to suggest that they were derived from the same mantle source. C and O isotope data are also consistent with a mantle derivation for the carbonatite magmas, and support the theory of a cogenetic origin for the carbonatites and the lamprophyres. The differences between the carbonatites and lamprophyres are considered to represent differing degrees of partial melting of a similar source.We suggest that the ultimate source of these magmas is the asthenospheric mantle, since there is no geochemical or isotopic evidence for their having been derived directly from ancient, enriched sub-continental lithospheric mantle. However, it is likely that the magmas actually formed through a two-stage process, with small-degree volatile-rich partial melts rising from the asthenospheric mantle and being ‘frozen in’ as metasomites, which were then rapidly remobilized during Gardar rifting.

Experiments were undertaken to determine the toxicity in the lung of dust generated by opencast coal mining. Since it was impractical to collect the large mass of actual opencast respirable dust required for the toxicity experiment, a surrogate dust with the same size distribution was manufactured (PSW). This surrogate dust had the same basic mineralogical composition as mineralogically characterized airborne dust collected from the welsh coal opencast pit at Park Slip West. Diesel exhaust particles (DEP), generated from mining vehicular and mechanical activity, contribute towards opencast particulate matter. Therefore, a second dust comprising of a 50/50 by weight mixture of the surrogate mineral dust and diesel soot was also examined (PSW + DEP). These dusts and DEP (weak biological reactivity) and a-quartz (high biological reactivity) were instilled into the lungs of healthy rats. The animals were sacrificed at 1, 6 and 11 weeks. Assessments of potential toxicity included lung to body weight ratios, acellular protein in lung lavage (markers of lung permeability) and total free cells (marker of inflammation). The surrogate opencast dust with or without DEP caused no significant increases in any of the parameters studied and as such was very similar to the weak biological effects of DEP alone. These effects contrasted sharply with those observed for the bioreactive mineral, quartz that induced rapid increases in permeability and a progressive inflammation. The use of a surrogate is less desirable then the real opencast mine dust, however, if as believed, the surrogate material is a representative mixture of the actual airborne dust around this opencast site, then these particles should show little or no short-term lung toxicity following inhalation.

Scheelite mineralization in the granulite-facies supracrustal sequences of the Kerala Khondalite Belt, southern India is reported. The supracrustal sequences where the mineralization is found comprise granulite-grade metasediments which underwent metamorphism at ∼550 Ma. The mineralization is assumed to have formed by late-stage metasomatism that overprinted the regional metamorphism of the country rock (garnet-biotite gneiss) and occurs along a quartz vein that intrudes the regional foliation. The paragenetic data from the vein demonstrate unambiguously a separate cycle of hydrothermal activity, resulting in metasomatism and mineralization. Scheelite is found in both the altered host rock along the foliation plane and in the quartz vein. Fluid inclusions preserved in the vein suggest that the mineralizing fluids were saline-aqueous in composition, while those in the country rocks were predominantly CO2-rich. The mineral chemistry and bulk-rock chemical composition of the mineralized domain reveal the unusual enrichment of Ca in the mineralised zone with the depletion of K. We propose that fluid discharging from a crystallizing deep-seated magma, mixing with deep circulating Ca-bearing palaeo-groundwater gave rise to the deposition of scheelite. The scheelite mineralization and the quartz vein emplacement occurred after the Pan-African regional metamorphism.

A series of titanium silicate glasses along the composition joins TiO2-SiO2, TiO2-Na2SiO3, TiO2-K2SiO3 and TiO2-CaSiO3, has been examined using oxygen K-edge X-ray absorption near edge structure spectroscopy (XANES) confined to the near-surface region. Sharp pre-edge features in the spectra can be used to determine the Ti coordination in the glasses. The presence of [4]Ti is indicated by a pre-edge peak at ∼534 eV while [5]Ti is indicated by a peak at ∼533 eV. Titanium exists in all these glasses as [4]Ti and [5]Ti with no [6]Ti being present. For alkali-containing glasses the [5]Ti site becomes more prevalent with increasing TiO2. TiO2-K2SiO3 compositions contain a greater proportion of [4]Ti than comparable Na2O compositions. This is consistent with earlier Ti L-edge findings. The TEY spectra for the TiO2-CaSiO3 compositions indicate the presence of significant amounts of [5]Ti at high TiO2 contents; however, comparison of TEY (near surface) and FY (bulk sample) XANES shows that the [5]Ti is confined to the surface of the glass sample with the bulk of the glass containing [4]Ti.

The chemical and structural alteration of metamict zircon crystals from a 619 ±17 (2σ) Ma old, posttectonic granite in the southern part of the Eastern Desert, Egypt was studied. The crystals show simple oscillatory growth zones with metamictization–induced fractures, which provided pathways for fluid infiltration. Electron and ion microprobe analyses reveal that metamict, i.e. U and Th–rich, areas are heavily enriched in Ca, Al, Fe, Mn, LREE, and a water species, and have lost Zr and Si as well as radiogenic Pb. These chemical changes are the result of an intensive reaction with a low–temperature (120—200°C) aqueous solution. The chemical reactions probably occurred within the amorphous regions of the metamict network. During the zircon–fluid interactions the metamict structure was partially recovered, as demonstrated by micro-Raman and -infrared measurements. A threshold degree of metamictization, as defined empirically by an α–decay dose, Dc, was necessary for zircons to undergo hydrothermal alteration. It is proposed that Dc marks the first percolation point, where the amorphous domains start to form percolating clusters in the metamict network and where bulk chemical diffusion is believed to increase dramatically. The time of the hydrothermal alteration is determined by a lower intercept age of a U-Pb SHRIMP discordia of 17.9 (2σ) Ma, which is in good agreement with an apatite fission track age of 22.2 (2σ) Ma. The hydrothermal alteration event occurred contemporaneously with the main rifting phase of the Red Sea and widespread low- temperature mineralizations along the Red Sea coast.

The exact nature of tripuhyite remains controversial more than 100 years after the first description of the mineral. Different stoichiometries and crystal structures (rutile or tri-rutile types) have been suggested for this Fe-Sb-oxide. To address these uncertainties, we studied tripuhyite from Tripuhy, Minas Gerais, Brazil (type material) and Falotta, Grisons, Switzerland using single-crystal and powder X-ray diffraction (XRD), optical microscopy and electron microprobe analysis.

Electron microprobe analyses showed the Fe/Sb ratios to be close to one in tripuhyite from both localities. Single crystal XRD studies revealed that tripuhyite from the type locality and from Falotta have the rutile structure (P42mnm, a = 4.625(4) c = 3.059(5) and a = 4.6433(10) c= 3.0815(9) Å, respectively). Despite careful examination, no evidence for a tripled c parameter, characteristic of the tri-rutile structure, was found and hence the structure was refined with the rutile model and complete Fe-Sb disorder over the cationic sites in both cases (type material: R1 = 3.61%; Falotta material: R1 = 3.96%). The specular reflectance values of type material tripuhyite and lewisite were measured and the following refractive indices calculated (after Koenigsberger): tripuhyite nmin = 2.14, nmax = 2.27; lewisite (cubic) n = 2.04.

These results, together with those of 57Fe and 121Sb Mössbauer spectroscopy on natural and synthetic tripuhyites reported in the literature, indicate that the chemical formula of tripuhyite is Fe3+Sb5+O4 (FeSbO4). Thus, tripuhyite can no longer be attributed to the tapiolite group of minerals of general type AB2O6. A comparison of the results presented with the mineralogical data of squawcreekite suggests that tripuhyite and squawcreekite are identical. In consequence, tripuhyite was redefined as Fe3+Sb5+O4 with a rutile-type structure. Both the proposed new formula and unit cell (rutile-type) of tripuhyite as well as the discreditation of squawcreekite have been approved by the Commission on New Mineral and Mineral Names (CNMMN) of the International Mineralogical Association (IMA).