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Comparison of Different Soil Leaching Techniques with Four Herbicides

Published online by Cambridge University Press:  12 June 2017

Chu-Huang Wu  and
P. W. Santelmann
Chu-Huang Wu
Affiliation:
Dep. Agron., Oklahoma State Univ., Stillwater, OK 74074
P. W. Santelmann
Affiliation:
Dep. Agron., Oklahoma State Univ., Stillwater, OK 74074
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Abstract

Herbicide mobility in soils was compared by three laboratory methods. The Rf values calculated from soil thin-layer chromatography correlated closely with those obtained from soil thick-layer chromatography (r = 0.96). Herbicides leached slightly further in slotted column chromatography as compared with the other methods. The working hours required to conduct a study with each method were in the increasing order of thin-layer, thick-layer, and column chromatography. However, the thin-layer method required the longest waiting times, followed by the column and thick-layer chromatography. If radioactive herbicides are not available or obtainable, the thick-layer chromatography is simplest and quickest. The relative mobility of herbicides studied was fluometuron [1,1-dimethyl-3-(α,α,α-trifluoro-m-tolyl)urea] > napropamide [2-(α-naphthoxy)-N,N-diethylpropionamide] > terbutryn [2-(tert-butyl-amino)-4-(ethylamino)-6-(methylthio)-s-triazine] > trifluralin (α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine). Less herbicide mobility was observed in heavier soil than in sandy soil.

Type
Research Article
Information
Weed Science , Volume 23 , Issue 6 , November 1975 , pp. 508 - 511
Copyright
Copyright © 1975 by the Weed Science Society of America 

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References

Literature Cited

1. Anderson, W.P., Richards, A.B., and Whitworth, J.W. 1968. Leaching of trifluralin, benefin, and nitralin in soil columns. Weed Sci. 16:165–168.CrossRefGoogle Scholar
2. Bardsley, C.E., Savage, K.E., and Walker, J.C. 1968. Trifluralin behavior in soil. II. Volatilization as influenced by concentration, time, soil moisture content and placement. Agron. J. 60:89–92.CrossRefGoogle Scholar
3. Chapman, T., Gabbott, P.A., and Osgerby, J.M. 1970. Technique for measuring relative movement of herbicides in soil under leaching conditions. Pestic. Sci. 1:56–58.CrossRefGoogle Scholar
4. Eshel, Y. and Warren, G.F. 1967. A simplified method for determining phytotoxicity, leaching and adsorption of herbicide in soils. Weeds 15:115–118.CrossRefGoogle Scholar
5. Eshel, Y. 1969. Phytotoxicity, teachability, and site of uptake of 2-chloro-2′,6′-diethyl-N-(methoxymethyl) acetanilide. Weed Sci. 17:441–444.CrossRefGoogle Scholar
6. Gerber, H.R., Ziegler, P., and Dubach, P. 1970. Leaching as a tool in the evaluation of herbicides. Proc. 10th Brit. Weed Conf. 10:118–125.Google Scholar
7. Gray, R.E. and Weierich, A.J. 1968. Leaching of five thiocarbamate herbicides in soils. Weed Sci. 16:77–79.CrossRefGoogle Scholar
8. Harris, C.I. 1967. Movement of herbicides in soil. Weeds 15:214–216.CrossRefGoogle Scholar
9. Helling, C.S. 1971. Pesticide mobility in soils. I. Parameters of thin-layer chromatography. II. Applications of soil thin-layer chromatography. Soil Sci. Soc. Amer. Proc. 37:732–743.CrossRefGoogle Scholar
10. Helling, C.S. and Turner, B.C. 1968. Pesticide mobility: Determination by soil thin-layer chromatography. Science 162:562–563.CrossRefGoogle ScholarPubMed
11. Helling, C.S., Kaufman, D.D., and Dieter, C.T. 1971. Algae bioassay detection of pesticide mobility in soils. Weed Sci. 19:685–690.CrossRefGoogle Scholar
12. Lambert, S.M., Porter, P.E., and Schieferstein, R.H. 1965. Movement and sorption of chemicals applied to the soil. Weeds 13:185–190.CrossRefGoogle Scholar
13. Murray, D.S. and Santelmann, P.W. 1975. Environmental and soil factors affecting the dissipation, phytotoxicity and mobility of Dipropetryn. J. Agr. Food Chem. 23(3):(in press).Google Scholar
14. Rodgers, E.G. 1968. Leaching seven s-triazines. Weed Sci. 16:117–120.CrossRefGoogle Scholar