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Age Constraints on Gulf of Mexico Deep Water Ventilation as Determined by 14C Measurements

Published online by Cambridge University Press:  18 September 2017

Piers Chapman*
Affiliation:
Department of Oceanography, Texas A&M University, College Station, TX 77843-3146, USA
Steven F DiMarco
Affiliation:
Department of Oceanography, Texas A&M University, College Station, TX 77843-3146, USA
Robert M Key
Affiliation:
Program in Atmospheric and Oceanic Sciences, Princeton University, Princeton, NJ 08544, USA
Connie Previti
Affiliation:
Department of Oceanography, Texas A&M University, College Station, TX 77843-3146, USA
Shari Yvon-Lewis
Affiliation:
Department of Oceanography, Texas A&M University, College Station, TX 77843-3146, USA
*
*Corresponding author. Email: [email protected].

Abstract

While the exchange of water through Yucatan Strait is reasonably well known, the age of the deep water in both the Caribbean Sea and Gulf of Mexico is not. We recently measured the radiocarbon (14C) concentrations in deep water in the Gulf of Mexico from a line of stations along 90°30′W. The mean apparent age of water below 900 m, the depth of the Florida Strait sill, was found to be about 740 yr relative to the 1950 14C standard. Depending on how the corrections for biological activity in the upper water are applied, this converts to a “true” age of between 231 ± 28 and 293 ± 74 yr. These ages agree with a previous estimate of the age of the deep water in the Gulf of Mexico based on heat flows, put upper limits on the age of the deep water in the Caribbean Sea, and provide constraints on modelers for the return of deep water from the Gulf of Mexico to the Caribbean. This might be important in the event of a future deep water oil or other chemical spill in the region.

Type
Research Article
Copyright
© 2017 by the Arizona Board of Regents on behalf of the University of Arizona 

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References

REFERENCES

Alvera-Azcarate, A, Barth, A, Weisberg, RH. 2009. The surface circulation of the Caribbean Sea and the Gulf of Mexico as inferred from satellite altimetry. Journal of Physical Oceanography 39:640657.Google Scholar
Badan, A, Candela, J, Sheinbaum, J, Ochoa, J. 2005. Upper-layer circulation in the approaches to Yucatan Channel. In: Sturges W, Lugo-Fernandez A, editors. Circulation in the Gulf of Mexico: Observations and Models. Geophysical Monographs 161. American Geophysical Union. p 5769.Google Scholar
Brewer, PG, Goldman, JC. 1976. Alkalinity changes generated by phytoplankton growth. Limnology and Oceanography 21:108117.Google Scholar
Broecker, WS. 1979. A revised estimate for the radiocarbon age of North Atlantic Deep Water. Journal of Geophysical Research 84:32183226.Google Scholar
Broecker, WS, Blanton, S, Smethie, WM Jr. 1991. Radiocarbon decay and oxygen utilization in the deep Atlantic Ocean. Global Biogeochemical Cycles 5:87117.CrossRefGoogle Scholar
Broecker, WS, Sutherland, S, Smethie, W, Peng, T-H, Östlund, G. 1995. Oceanic radiocarbon: separation of the natural and bomb components. Global Biogeochemical Cycles 9:263288.Google Scholar
Broecker, WS, Peacock, SL, Walker, S, Weiss, R, Fahrbach, E, Schroeder, M, Mikolajewic, U, Heinze, C, Key, R, Peng, T-H, Rubin, S. 1998. How much deep water is formed in the Southern Ocean? Journal of Geophysical Research 103:15,833844.Google Scholar
Bunge, L, Ochoa, J, Badan, A, Candela, J, Sheinbaum, J. 2002. Deep flows in the Yucatan channel and their relation to changes in the Loop Current extension. Journal of Geophysical Research 107:3233. DOI: 10.1029/2001JC001256.Google Scholar
Candela, J, Tanahara, S, Crepon, M, Barnier, B, Sheinbaum, J. 2003. Yucatan Channel flow: observations versus CLIPPER ATL6 and MERCATOR PAM models. Journal of Geophysical Research 108:3385. DOI: 10.1029/2003JC001961.Google Scholar
Cherrier, J, Sarkodee-Adoo, J, Guilderson, TP, Chanton, JP. 2014. Fossil carbon inmparticulate organic matter in the Gulf of Mexico following the Deepwater Horizon event. Environmental Science and Technology Letters 1:108112.Google Scholar
Cherubin, LM, Sturges, W, Chassignet, EP. 2005. Deep flow variability in the vicinity of the Yucatan Straits from a high-resolution numerical simulation. Journal of Geophysical Research 110:C04009. DOI: 10.1029/2004JC002280.Google Scholar
DeHann, CJ, Sturges, W. 2005. Deep cyclonic circulation in the Gulf of Mexico. Journal of Physical Oceanography 35:18011812.Google Scholar
Dickson, AG. 1981. An exact definition of total alkalinity and a procedure for the estimation of alkalinity and total inorganic carbon from titration data. Deep-Sea Research 28A:609623.Google Scholar
Dickson, AG, Afghan, JD, Anderson, GC. 2003. Reference materials for oceanic CO2 analysis: a method for the certification of total alkalinity. Marine Chemistry 80:185197.Google Scholar
Druffel, ERM. 2002. Radiocarbon in corals: records of the carbon cycle, surface circulation and climate. Oceanography 15(1):122127. DOI: 10.5670/oceanog.2002.43.CrossRefGoogle Scholar
Elder, KL, McNichol, A, Gagnon, AR. 1998. Reproducibility of seawater, inorganic carbon 14C results at NOSAMS. Radiocarbon 40(1):223230.Google Scholar
Fratantoni, DM, Zantopp, RJ, Johns, WE, Miller, JL. 1997. Updated bathymetry of the Anagada-Jungfern Passage complex and implications for Atlantic inflow to the abyssal Caribbean Sea. Journal of Marine Research 55:847860.Google Scholar
Graven, HD, Gruber, N, Key, R, Khatiwala, S, Giraud, X. 2012. Changing controls on oceanic radiocarbon:New insights on shallow-to-deep ocean exchange and anthopogenic CO2 uptake. Journal of Geophysical Research 117:C10005. DOI: 10.1029/2012JC008074.Google Scholar
Hamilton, P. 1990. Deep currents in the Gulf of Mexico. Journal of Physical Oceanography 20:10871104.Google Scholar
Hamilton, P, Singer, JJ, Waddell, E, Donohue, K. 2003. Deepwater observations in the northern Gulf of Mexico from in-situ current meters and PIES. OCS Study MMS 2003-049, Final Report to U.S. Minerals Management Service, Vol. 2, Gulf of Mexico OCS Region. 95 p.Google Scholar
Hamilton, P, Bower, A, Furey, H, Leben, R, Perez-Brunius, P. 2016. Deep Circulation in the Gulf of Mexico: A Lagrangian Study. U.S. Dept. of the Interior, Bureau of Ocean Energy Management, Gulf of Mexico OCS Region, New Orleans, LA. OCS Study BOEM 2016-081. 289 p.Google Scholar
Hua, Q, Barbetti, M, Rakowski, AZ. 2013. Atmospheric radiocarbon for the period 1950–2010. Radiocarbon 55(4):20592072.Google Scholar
Jochens, AE, DiMarco, SF. 2008. Physical oceanographic conditions in the deepwater Gulf of Mexico in summer 2000–2002. Deep-Sea Research II 55:25412554.Google Scholar
Jochens, AE, Bender, LC, DiMarco, SF, Morse, JW, Kennicutt, MC II, Howard, MK, Nowlin, WD Jr. 2005. Understanding the Processes that Maintain the Oxygen Levels in the Deep Gulf of Mexico: Synthesis Report. U.S. Dept. of the Interior, Minerals Management Service, Gulf of Mexico OCS Region, New Orleans, LA. OCS Study MMS 2005-032. 142 p.Google Scholar
Johns, WE, Townsend, TL, Fratantoni, DM, Wilson, WD. 2002. On the Atlantic inflow to the Caribbean Sea. Deep-Sea Research I 49:211243.Google Scholar
Johnson, K, Key, R, Millero, F, Sabine, C, Wallace, D, Winn, C, Arlen, L, Erickson, K, Friis, K, Galanter, M, Goen, J, Rotter, R, Thomas, C, Wilke, R, Takahashi, T, Sutherland, S. 2003. Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the R/V Knorr Cruises in the North Atlantic Ocean on WOCE Sections AR24 (November 2–December 5, 1996) and A24, A20, and A22 (May 30–September 3, 1997). In: Kozyr A, editor. ORNL/CDIAC-143, NDP-082. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee. DOI: 10.3334/CDIAC/otg.ndp082.Google Scholar
Key, RM, Kozyr, A, Sabine, CL, Lee, K, Wanninkhof, R, Bullister, JL, Feely, RA, Millero, FJ, Mordy, C, Peng, T-H. 2004. A global ocean carbon climatology:Results from Global Data Analysis Project (GLODAP). Global Biogeochemical Cycles 18:GB4031. DOI: 10.1029/2004GB002247.Google Scholar
Koltermann, KP, Gouretski, VV, Jancke, K. 2011. Hydrographic Atlas of the World Ocean Circulation Experiment (WOCE). Volume 3: Atlantic Ocean. Sparrow M, Chapman P, Gould J, editors). International WOCE Project Office, Southampton, UK. ISBN 090417557X.Google Scholar
Ledwell, JR, He, R, Xue, Z, DiMarco, SF, Spencer, L, Chapman, P. 2016. Dispersion of a tracer in the deep northern Gulf of Mexico. Journal of Geophysical Research 121:11101132. DOI: 10.1002/2015JC011405.Google Scholar
MacDonald, IR, Guinasso, NL Jr, Ackleson, G, Amos, JF, Duckworth, R, Sassen, R, Brooks, JM. 1993. Natural oil slicks in the Gulf of Mexico visible from space. Journal of Geophysical Research 98:1635116364.CrossRefGoogle Scholar
MacDonald, I, Reilly, JF Jr, Best, SR, Venkataramaiah, R, Sassen, R, Amos, J, Guinasso, NL Jr. 1996. A remote-sensing inventory of active oil seeps and chemosynthetic communities in the northern Gulf of Mexico. In: Schumacher D, Abrams MA, editors. Hydrocarbon Migration and its Near-Surface Expression. AAPG Memoir 66:2737. Tulsa, OK: American Association of Petroleum Geologists.Google Scholar
MacDonald, IR, Leifer, I, Sassen, R, Stine, P, Mitchell, R, Guinasso, N. 2002. Transfer of hydrocarbons from natural seeps to the water column and atmosphere. Geofluids 2:95107.Google Scholar
Matsumoto, K. 2007. Radiocarbon-based circulation age of the world oceans. Journal of Geophysical Research 112:C09004. DOI: 10.1029/2007JC004095.Google Scholar
Matsumoto, K, Key, RM. 2004. Natural radiocarbon distribution in the deep ocean. In: Shiyomi M, et al., editors. Global Environmental Change in the Ocean and on Land. p 4558.Google Scholar
Matthews, TD, Fredericks, AD, Sackett, WM. 1973. The geochemistry of radiocarbon in the Gulf of Mexico. Report IAEA-SM-158148. Vienna: International Atomic Energy Agency. p 725–34.Google Scholar
Maul, GA, Mayer, DA, Baig, SR. 1985. Comparisons between a continuous 3-year current-meter observation at the sill of the Yucatan Strait, measurements of Gulf Loop Current area, and regional sea level. Journal of Geophysical Research 90:90899096.Google Scholar
Molinari, RL, Mayer, D. 1980. Physical oceanographic conditions at a potential OTEC site in the Gulf of Mexico; 27.5°N, 85.5°W. NOAA Tech. Memo ERL-AOML-42. 100 p.Google Scholar
Morrison, JM, Nowlin, WD Jr. 1977. Repeated nutrient, oxygen and density sections through the Loop Current. Journal of Marine Research 35:105128.Google Scholar
Morrison, JM, Merrill, WJ, Key, RM, Key, TC. 1983. Property distributions and deep chemical measurements within the western Gulf of Mexico. Journal of Geophysical Research 88:26012608.Google Scholar
Nowlin, WD Jr, McClellan, H. 1967. A characterization of the Gulf of Mexico waters in winter. Journal of Marine Research 25:2959.Google Scholar
Nowlin, WD Jr, Jochens, AE, DiMarco, SF, Reid, RO, Howard, MK. 2001. Deepwater physical oceanography reanalysis and synthesis of historical data:Synthesis report. OCS Study MMS 2001-064, U.S. Dept. of the Interior, Minerals Management Service, Gulf of Mexico OCS Region, New Orleans, LA. 528 p.Google Scholar
Ochoa, J, Sheinbaum, J, Badan, A, Candela, J, Wilson, D. 2001. Geostrophy via potential vorticity inversion in the Yucatan Channel. Journal of Marine Research 59:725747.Google Scholar
Östlund, HG, Rooth, CGH. 1990. The North Atlantic tritium and radiocarbon transients 1972–1983. Journal of Geophysical Research 95:2014720165.Google Scholar
Östlund, HG, Dorsey, HG, Rooth, CGH. 1974. GEOSECS North Atlantic radiocarbon and tritium results. Earth and Planetary Science Letters 23:6986.CrossRefGoogle Scholar
Ribbat, B, Roether, W, Münnich, KO. 1976. Turnover of eastern Caribbean deep water from 14C measurements. Earth and Planetary Science Letters 32:331341.Google Scholar
Rivas, D, Badan, A, Ochoa, J. 2005. The ventilation of the deep Gulf of Mexico. Journal of Physical Oceanography 35:17631781.Google Scholar
Roemmich, D. 1981. Circulation of the Caribbean Sea: a well-resolved inverse problem. Journal of Geophysical Research 86:79938005.Google Scholar
Romanou, A, Chassignet, EP, Sturges, W. 2004. Gulf of Mexico circulation within a high-resolution numerical simulation of the North Atlantic Ocean. Journal of Geophysical Research 109:C01003. DOI: 10.1029/2003JC001770.Google Scholar
Rousset, C, Beal, LK. 2010. Observations of the Florida and Yucatan currents from a Caribbean cruise ship. Journal of Physical Oceanography 40:15751581. DOI: 10.1175/2010JPO4447.1.CrossRefGoogle Scholar
Rubin, SI, Key, RM. 2002. Separating natural and bomb-produced radiocarbon in the ocean: the potential alkalinity method. Global Biogeochemical Cycles 16:1105. DOI: 1029/2001GB001432.Google Scholar
Schmitz, WJ. 2005. Cyclones and westward propagation in the shedding of anticyclonic rings from the Loop Current. In: Sturges W, Lugo-Fernandez A, editors. Circulation in the Gulf of Mexico: Observations and Models. Geophysical Monographs 161:241261. Washington DC: American Geophysical Union.Google Scholar
Schroeder, WW, Berner, L Jr, Nowlin, WD Jr. 1974. The oceanic waters of the Gulf of Mexico and Yucatan Strait during July 1969. Bulletin of Marine Science 24:119.Google Scholar
Sheinbaum, J, Candela, J, Badan, A, Ochoa, J. 2002. Flow structure and transport in the Yucatan Channel. Geophysical Research Letters 29:1040. DOI: 10.1029/2001GL013990.Google Scholar
Stuiver, M. 1980. Workshop on 14C data reporting. Radiocarbon 22(3):964966.Google Scholar
Stuiver, M, Polach, HA. 1977. Discussion: reporting of 14C data. Radiocarbon 19(3):355363.Google Scholar
Stuiver, M, Quay, PD, Ostlund, HG. 1983. Abyssal water carbon-14 distribution and the age of the world oceans. Science 219:849851.Google Scholar
Sweeney, C, Gloor, E, Jacobson, AJ, Key, RM, McKinley, G, Sarmiento, JL, Wanninkhof, R. 2007. Constraining global air-sea gas exchange for CO2 with recent bomb 14C measurements. Global Biogeochemical Cycles 21:GB2015. DOI: 10.1029/2006GB002784.Google Scholar
Toggweiler, JR, Key, RM. 2002. Ocean circulation: thermohaline circulation. In: Steel J, Thorpe S, Turekian K, editors. Encyclopedia of Ocean Sciences. London: Academic Press, Ltd. p 29412947. 2001; also published in Holton JR, Pyle J, Curry JA, editors. Encyclopedia of Atmospheric Sciences. London: Academic Press. p 15491555.Google Scholar
Wade, TL, Sericano, JL, Sweet, ST, Knap, AH, Guinasso, NL. 2016. Spatial and temporal distribution of water column total polycyclic aromatic hydrocarbons (PAH) and total petroleum hydrocarbons (TPH) from the Deepwater Horizon (Macondo) incident. Marine Pollution Bulletin 103:286293.Google Scholar
Weatherly, GL, Wienders, N, Romanou, A. 2005. Intermediate-depth circulation in the Gulf of Mexico estimated from direct measurements. In: Sturges W, Lugo-Fernandez A, editors. Circulation in the Gulf of Mexico: Observations and Models. Geophysical Monographs 161:315324. Washington DC: American Geophysical Union.Google Scholar
WHPO. 1994. WHP Operations and Methods. WOCE Hydrographic Office Report 91/1, as revised, WOCE Hydrographic Program Office, Woods Hole, MA.Google Scholar