1. When the univalent anions (of potassium salts) are arranged according to their precipitation concentration for a ferric hydroxide sol the sequence is lyotrope:
A, CNS, Cl, Br, NO3, ClO3, I.
The concentrations range from 0·01 for acetate to 0·093 for iodide; thiocyanate alone is in an unusual position.
The order for kations is also lyotrope:
Li, Na, Mg, K, Rb, NH4, Ca. The concentration range is much smaller, from 0·037 for lithium to 0·055 for ammonium.
2. The pairs of univalent-bivalent kations—Li. and Mg¨, K. and Ca¨—show no trace of antagonistic action in the precipitation of Fe(OH)3 sol—the results being strictly ADDITIVE.
3. The pair of univalent-bivalent anions—ClO3′ and SO4″—on the contrary, show a well-marked ADJUVANT action, which amounts to 50 per cent.
4. The effect of salts on the opalescence temperature of a phenol-water system (10 to 11 per cent, phenol) is lyotrope, and is very marked at a concentration of 0·04 n. The order is—
Anions … C1, Br, NO3, I, CNS
Kations ‥ Na, Li, K, NH4
The effect of the valency of the ion is slight, or non-existent.
5. A preliminary account is given of a method which promises to provide a simple and reliable means of determining the amount of “free” and “bound” water in a solution (applicable to electrolytes and nonelectrolytes, and apparently to colloidal solutions, as e.g. gum arabic).
6. An explanation of the Lyotrope Effect is put forward.