On the Nature of “Palladium Hydrogen”

Extract

Ever since the remarkable discovery by Graham in 1866 that palladium possesses the power of occluding hydrogen gas in large quantity, various views have from time to time been put forward to explain the true nature of the phenomenon. Whilst some observers regard hydrogenised palladium as an alloy or solid solution, others again consider it to be, or at least to contain, a definite chemical compound or hydride. Those who hold the latter opinion, however, are not agreed as to which compound or hydride is formed, as is proved by the fact that different formulae have been ascribed to it. Graham himself recognised the possibility that a definite chemical compound might be formed, for he says (Researches, 287) that in fully-charged palladium there exists one equivalent of palladium to 0·772 equivalent of hydrogen, or an approximation to single equivalents which would be represented by the formula PdH. His opinion was, nevertheless, opposed to the idea of such a definite chemical combination, one of his chief objections being that no visible change is occasioned to metallic palladium by its association with hydrogen. He regarded the product simply as an alloy of the volatile metal hydrogenium, in which the volatility of the one element is restrained by its union with the other, and which owes its metallic aspect equally to both constituents.

Considerations of a purely chemical character have up to the present time proved insufficient to decide which of these views is correct.