Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-24T19:55:04.825Z Has data issue: false hasContentIssue false
  • English
  • Français

A review of the crystallography and crystal chemistry of compounds in the BaO-CuOx system

Published online by Cambridge University Press:  10 January 2013

Winnie Wong-Ng  and
Lawrence P. Cook
Winnie Wong-Ng
Affiliation:
Ceramics Division, NIST, Gaithersburg, Maryland 20899
Lawrence P. Cook
Affiliation:
Ceramics Division, NIST, Gaithersburg, Maryland 20899
Get access Rights & Permissions [Opens in a new window]

Abstract

Literature data pertaining to the crystal chemistry, crystallography, and X-ray powder-diffraction properties of phases reported in the system BaO-CuOx are compiled. Reported phases include BaCuO2−2.12, BaCuO2.26−2.39, BaCuO2.5, Ba2CuO3+x, Ba2Cu3O5+x, BaCu2O2+x, Ba3Cu5O8, Ba3CuO4, BaCu3O4, Ba3Cu2O4+x, Ba5Cu3O6+x, and BaCu2O3. The existence of some of these phases, however, still has to be verified. Most of these compounds are nonstoichiometric in oxygen. Their oxygen content, and in some cases even their crystal structures, vary with oxygen partial pressure. There are also reported indications that the cations Ba and Cu are not stoichiometric in the cubic BaCuO2-type compounds.

Type
Research Article
Information
Powder Diffraction , Volume 9 , Issue 4 , December 1994 , pp. 280 - 289
Copyright
Copyright © Cambridge University Press 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Abbattista, R., Brisi, C., Lucco-Borlera, M., and Vallino, M. (1988a). “New phases in the most basic zone of the system Ba-Cu-O,” Nuovo Cimento, 10, 611–614.CrossRefGoogle Scholar
Abbattista, P., Vallino, M., Brisi, C., and Lucco-Borlera, M. (1988b). “Some equilibrium relationships in the barium rich part of the BaO-CuO-O system,” Mater. Res. Bull. 23, 1509–1520.CrossRefGoogle Scholar
Abbattista, R., Delmastro, A., Mazza, D., and Vallino, M. (1991). “The ternary system BaO-CaO-CuO-O,” Mater. Chem. Phys. 28, 33–41.CrossRefGoogle Scholar
Arjomand, M., and Machin, D. J. (1975). “Oxide chemistry. Part II. Ternary oxides containing copper in oxidation state, -I, -II, -III, and -IV,” J. Chem. Soc. Dalton Trans. 1061–1066.CrossRefGoogle Scholar
Bazuev, G. V., and Krasilnikov, V. N. (1991). “The synthesis and properties of barium oxocuprate Ba2Cu3O5+δ',” Zh. Neorga. Khim. 36, 2195–2199.Google Scholar
Bertinotti, A., Hammann, J., Luzet, D., and Vincent, E. (1989). “Structure of a new type of satellite phase in YBa2Cu307−δ',” Physica C 160, 227–234.CrossRefGoogle Scholar
Bykov, A. B., Demianets, L. N., Zibrov, I. P., Kanunnikov, G. V., Melnikoe, O. K., and Stishov, S. M. (1988). “Crystallization of high temperature superconductors from non-stoichiometric melts,” J. Cryst. Growth 91, 302–313.CrossRefGoogle Scholar
Cava, R. J., Batlogg, B., van Dover, R. B., Murphy, D. W., Sunshine, S., Siegriest, T., Remeika, J. R., Rietman, E. A., Zahurak, S., and Espinosa, G. P. (1987). “Bulk superconductivity at 91 K in single-phase oxygen deficient pervoskite Ba2YCu3O9−x,” Phy. Rev. Lett. 58, 1676–1679.CrossRefGoogle Scholar
Deleeuw, D. W., Mutsaer, C. A. H. A., Langereis, C., Smoorenburg, H. C. A., and Rommers, P. J. (1988). “Compounds and phase compatibilities in the system Y2O3-BaO-CuO at 950 °C,” Physica C 152, 39–49.CrossRefGoogle Scholar
Dube, D., Champagne, B., Lambert, P., and LePage, Y. (1990). “Occurrence of BaCu2O2 in plasma-sprayed YBaCuO coatings,” Mater. Lett. 9, 353–356.CrossRefGoogle Scholar
Eriksson, S., Johansson, L.-G., Boerjesson, L., and Kakihana, M. (1989). “Oxygen content and structural properties of some Ba-Cu oxides,” Physica C 162, 59–60.CrossRefGoogle Scholar
Frase, K. G., Liniger, E. G., and Clarke, D. R. (1987). “Phase compatibilities in the system Y2O3-BaO-CuO at 950 °C,” J. Am. Ceram. Soc. 70, C204–205.CrossRefGoogle Scholar
Gatau, W., and Muller-Buschbaum, Hk. (1989). “Korrektur an BaCuO2,” J. Less-Common Met. 152, L11–L13.CrossRefGoogle Scholar
Halasz, I., Fulop, V., Kirschner, I., and Porjesz, T. (1988). “Thermoanalytical and X-ray diffraction investigations of Ba2Cu3O5+d for preparation of Y-Ba-Cu-0 superconductors,” J. Cryst. Growth 91, 444–449.CrossRefGoogle Scholar
Hodorowicz, S. A., Lasocha, W., Lasocha, A., and Eick, H. A., J., (1988). “The preparation and magnetic behavior of EuBa2Cu3-y,MyO6.5+x (M=Ni, Co, Al and Zn) and some related compounds,” J. Solid State Chem. 77, 148–155.CrossRefGoogle Scholar
JCPDS-ICDD, publisher of the Powder Diffraction File (PDF), Newton Square Corporate Square Campus, 12 Campus Blvd., Newton Square, PA 19073-3273.Google Scholar
Kipka, R., and Muller-Buschbaum, HK. (1977). “Uber oxocuprate, XX. Ein erdalkalioxocuprat (II) mit geschlossenen naugruppen:BaCuO2,” Z. Naturforsch Teil B 32, 121–123.CrossRefGoogle Scholar
Klinkova, L. A., Soikina, I. V., Zver'kova, I. I., Zver'kov, S. A., Ganovich, N. I., and Shevchenkolzv, S. A. (1989). “Phase transformation in the system BaO-CuO,” Akad. Nauk SSSR, Neorg. Mater. 25, 2033–2036.Google Scholar
Klinkova, L. A., Soikina, I. V., and Romanenko, I. M. (1990). “Phase transformation in the Y-Ba-Cu-O System,” Zh. Neorgan. Khim. 35, 253–257.Google Scholar
Klinkova, L. A. (1994a). “The non-equilibrium diagram of the BaCuO2−CuOx state and the specific role of the liquid phase at the formation YBa2Cu3Oy, oxide” (unpublished).Google Scholar
Klinkova, L. A. (1994b). “On the mobility of yttrium relative to the Ba2Cu3Oy, matrix in superconducting oxide YBa2Cu30y. (unpublished).Google Scholar
Klockow, E., and Eysel, W. (1988). JCPDS-ICDD Grants-in-Aid report.Google Scholar
Lander, J. J. (1951). “The crystal structures of NiO.3BaO, NiO.BaO, BaNiO3 and intermediate phases with composition near Ba2Ni2O5; with a note on NiO,” Acta Crystallogr. 4, 148–156.CrossRefGoogle Scholar
Lee, B. J., and Lee, D. E. (1989). “Calculation of phase diagrams for the YO1.5-BaO-CuOx system,” J. Am. Ceram. Soc. 72, 314–319.CrossRefGoogle Scholar
Lialikova, R. Ju., Radauzan, S. I., and Saluev, D. P. (1989). “Interaction of components in the BaO-CuO (Cu2O) system,” Dok. Acad. Nauk. SSSR 307, 1154–1157.Google Scholar
Machida, M., Yasuoka, K., Eguchi, K., and Arai, H. (1991). “Formation and decomposition of BaCuO2.5 prepared from a mixture of nitrates,” J. Solid State Chem. 91, 176–179.CrossRefGoogle Scholar
Maeda, M., Kadoi, M., and Ikeda, T. (1989). “The phase diagram of the YO1.5-BaO-CuO ternary system and growth of YBa2Cu3O7 single crystals,” Jpn. J. Appl. Phys. 28, 1417–1420.CrossRefGoogle Scholar
Maiorova, A. F., Mudretsova, S. N., Kovba, M. L., Monaenkova, A. S., and Popova, A. A. (1993). “Thermochemical characteristics of nonstoichiometric Ba2Cu3O5. II. Thermal transformation,” Physica C 218, 137–140.CrossRefGoogle Scholar
Migeon, H. N., Jeannot, F., Zanne, M., and Aubry, J. (1976). “Preparation et etude d'un oxyde de baryum-cuivre BaCuO2,” Rev. Chim. Miner. 13, 440–445.Google Scholar
Migeon, H. N., Zanne, M., Jeannot, F., and Gleitzer, C. (1977). “Etude de la non-stoechiometrie et des proprietes de BaCuO2+x (avec 0<x<0.12),” Rev. Chim. Miner. 14, 498–502.Google Scholar
Nevriva, M., Pollert, E., Matejkova, L., and Triska, A. (1988). “On the determination of the CuO-BaCuO2 and CuO-YCuO2.5 binary phase diagrams,” J. Cryst. Growth 91, 434–442.CrossRefGoogle Scholar
Nomura, S., Yoshino, H., and Ando, K. (1988). “Phase diagram of the system YBa2Cu3O7−δBaCuO2-CuO,” J. Cryst. Growth 92, 682–686.CrossRefGoogle Scholar
Pashin, S. F., Antipov, E. V., Koba, L. M., and Skolis, Y. Y. (1989). “Phase diagrams, X-ray diffraction, and thermodynamic properties of certain phases in the YO1.5-BaO-CuO system,” Sverkhprovodimost: fiz. khim. tekh 2, 116–122.Google Scholar
Paulus, E. F., Miehe, G., Fuess, H., Yehia, I., and Lochner, U. (1991). “The crystal structure of BaCuO2,” J. Solid State Chem. 90, 17–26.CrossRefGoogle Scholar
Petricek, S., Bukovec, N., and Bukovec, P. (1992). “On the synthesis and characterization of BaCuO2+x (0≤x≤0.5),” J. Solid State Chem. 99, 58–62.CrossRefGoogle Scholar
Roth, R. S., Davis, K. L., and Dennis, J. R. (1987). “Phase equilibria and crystal chemistry in the system Ba-Y-Cu-O,” Adv. Ceram. Mater. 2, 303–312.CrossRefGoogle Scholar
Roth, R. S. (1990). “User aspects of phase equilibria in high Tc ceramic superconductors,” Proceedings of the User Aspects of Phase Equilibria, Joint Research Centre, Petten, Netherlands, June 25-27 (Institute of Metals, London).Google Scholar
Sestak, J. (1989). “Binary and ternary compounds, phase diagrams and contaminations in the TO1.5-BaO-CuO system auxiliary to superconducting ceramics,” Thermochim. Acta 148, 235–248.CrossRefGoogle Scholar
Sestak, J., Kamarad, J., Holba, P., Triska, A., Pollert, E., and Nevriva, M. (1991). “Charge distribution, pressure and composition effects of CuOx based superconductors,” Thermochim. Acta 174, 99–114.CrossRefGoogle Scholar
Shitova, V. I., Mikirticheva, G. A., Chigareva, O. G., Grabovenko, L. Yu., Kuchaeva, S. K., and Grebenshchikov, R. G. (1989). “Phase diagrams of the two polythermal cuts of Y2O3-Cu0(Cu20) and BaCuO2-CuO(Cu2O) in the Y2O3-BaO-CuO system,” Sverkhprovodimost: Fiz., Khim., Tekh., 2, 69–75.Google Scholar
Skolis, Ju. Ja., Pashin, S. F., and Kovba, M. L. (1990). “Thermodynamic properties of barium cuprate BaCuO2+σ,” Superconductivity 3, 1984–1989.Google Scholar
Skolis, Ju. Ja., Pashin, S. F., Kitsenko, S. V., Kovba, M. L., and Fomichev, D. V. (1991). “13th All-Union Conference on Chemical Thermodynamics and Calorimetry, Abstracts, Pt. 1,” p. 62. Krasnoyarsk.Google Scholar
Teske, Chr. L., and Muller-Buschbaum, Hk. (1970). “Alkaline earth metal oxocuprates. IV. On SrCu2O2,” Z. Anorg. Allg. Chem. 379, 113–121.CrossRefGoogle Scholar
Teske, Chr. L., and Muller-Buschbaum, Hk. (1972). “Alkaline earth metal oxocuprates. VI. On BaCu2O2,” Z. Naturforsch Teil B 27, 296–301.CrossRefGoogle Scholar
Thompson, J., Fitz Gerald, J. D., Withers, R. L., Barlov, P. J., and Anderson, J. S. (1989). “The synthesis and structures of Ba2Cu3O5+δ,” Mater. Res. Bull. 24, 505–515.CrossRefGoogle Scholar
Voronin, G. F. (1992). “Thermodynamics of high-temperature superconducting materials,” Pure Appl. Chem. 64, 27–36.CrossRefGoogle Scholar
Voronin, G. F., and Degterev, S. A. (1994). “Solid state equilibria in the Ba-Cu-O system,” J. Solid State Chem. 110, 50–57.CrossRefGoogle Scholar
Weller, M. T., and Lines, D. R. (1989a). “Structure and stoichiometry in BaCuO2+x,” J. Chem. Soc. Chem. Commun. 484, 484–485.CrossRefGoogle Scholar
Weller, M. T., and Lines, D. L. (1989b). “Structure and oxidation state relationship in ternary copper oxide,” J. Solid State Chem. 82, 21–29.CrossRefGoogle Scholar
Wong-Ng, W., McMurdie, H., Paretzkin, B., Hubbard, C., and Dragoo, A. (1987). “Standard X-ray diffraction powder patterns of fifteen ceramic phases,” Powder Diffr. 2, 257–265.CrossRefGoogle Scholar
Wong-Ng, W., Davis, K., and Roth, R. S. (1988a). “Powder X-ray characterization of Ba2CuO3,” J. Am. Ceram. Soc. 71, C64–C66.CrossRefGoogle Scholar
Wong-Ng, W., McMurdie, H., Paretzkin, B., Hubbard, C., and Dragoo, A. (1988b). “Standard X-ray diffraction powder patterns of fifteen ceramic phases,” Powder Diffr. 3, 113–121.CrossRefGoogle Scholar
Wong-Ng, W., and Cook, L. P. (1991). “Oxidation/reduction melting equilibria in the system BaO-1/2Y2O3-CuOx. II. Powder X-ray analysis,” Adv. X-ray Anal. 35A, 633–639.Google Scholar
Wong-Ng, W., and Cook, L. P. (1992). “Oxidation/reduction melting reactions in the system BaO-Y2O3-CuOx. I. Method,” Superconductivity and ceramic superconductors II, Ceramic Trans., Am. Ceram. Soc., Westerville, OH, 18, 73–83.Google Scholar
Wong-Ng, W., and Cook, L. P. (1994). “Eutectic minimum melting in the system BaO-1/2Y2-CuO3-cuOx in air,” J. Am. Ceram. Soc. 77, 1883–1888.CrossRefGoogle Scholar
Wu, M. K., Ashburn, L. R., Torng, C. J., Hov, P. H., Meng, L. R., Gao, L., Huang, Z. J., Wang, Y. Q., and Chu, C. W. (1987). “Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure,” Phys. Rev. Lett. B 58, 908–910.CrossRefGoogle Scholar
Wu, M., Su, Q., Hu, G., Ren, Y., and Wang, H. (1994). “Preparation and properties of BaCuO2.5 and its related oxides,” J. Solid State Chem. 110, 389–392.Google Scholar
Zhang, W., Osmura, K., and Ochiai, S. (1990). “Phase diagram of the BaO-CuO binary system,” J. Am. Ceram. Soc. 73, 1958–1964.CrossRefGoogle Scholar
Zhang, W., and Osamuro, K. (1990). “Phase transition and crystal structure of Ba2Cux oxide,” Jpn. J. Appl. Phys. 29, L1092–1095.CrossRefGoogle Scholar