Hostname: page-component-745bb68f8f-l4dxg Total loading time: 0 Render date: 2025-02-05T06:11:33.733Z Has data issue: false hasContentIssue false
  • English
  • Français

Nickel Substituted Skutterudites: Synthesis and Physical Properties

Published online by Cambridge University Press:  10 February 2011

L. Chapon ,
D. Ravot  and
J. C. Tedenac
L. Chapon
Affiliation:
Laboratoire de Physicochimie de la Matière Condensée. Université Montpellier II, UMR 5617 Place Eugene Bataillon 34095 MONTPELLIER, FRANCE
D. Ravot
Affiliation:
Laboratoire de Physicochimie de la Matière Condensée. Université Montpellier II, UMR 5617 Place Eugene Bataillon 34095 MONTPELLIER, FRANCE
J. C. Tedenac
Affiliation:
Laboratoire de Physicochimie de la Matière Condensée. Université Montpellier II, UMR 5617 Place Eugene Bataillon 34095 MONTPELLIER, FRANCE
Get access

Abstract

Starting to CeFe4Sb12 and trying to obtain low gap semiconductors with very low thermal conductivity, we have performed in this compound the substitution of Ni for Fe.This substitution induces a reject of cerium from the structure. In this paper we present synthesis and physical properties of CeyFe4-xNixSb12 in which a relationship is existing between x and y to retain the electronic account giving semiconducting character.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 545: Symposium Z – Thermoelectric Materials 1998 - The Next Generation… , 1998 , 321
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Sharp, J.W., Jones, E.C., Williams, R.K., Martin, P.M., Sales, B.C., J. Appl. Phys. 78,1013 (1995).CrossRefGoogle Scholar
[2] Zhuravlev, N. N., Zhdanov, G. S., Kristallogr. 1 (1956) 509.Google Scholar
[3] Sales, B. C., Mandrus, D., Williams, R. K., Science 272 (1996) 1325.CrossRefGoogle Scholar
[4] Grandjean, F., Gérard, A., Braun, D. J., Jeitschko, W., J Phys. Chem. Solids 45 (1984) 877.CrossRefGoogle Scholar
[5] Morelli, D. T., Meisner, G. P., J. Appl. Phys. 77 (1995) 3777.CrossRefGoogle Scholar
[6] Meisner, G. P., Morelli, D. T., Hu, S., Yang, J., Uher, C., Phys. Rev. Letters 80 (1998) 3551.CrossRefGoogle Scholar
[7] Nolas, G. S., Slack, G. A., Morelli, D. T., Tritt, T. M., Erlich, A. C., J. Appl. Phys. 79 (1996) 4002.CrossRefGoogle Scholar
[8] Chapon, L., Ravot, D., Tedenac, J. C., J. All. Comp. (accepted and to be published).Google Scholar
[9] Fullprof software freely distributed by Rodriguez-Carjaval, J. (llb CEA-Saclay, France)Google Scholar
[10] Braun, D. J., Jeitschko, W., J Less. Com. Metals 51 (1980) 148.Google Scholar
[11] Sales, B. C., Mandrus, D., Chakoumakos, B. C., Keppens, V., Thompson, J. R., Phvs. Rev B 56 (1997) 15081.CrossRefGoogle Scholar
[12] Caillat, T., Fleurial, J.P., Borshchevsky, A., J. Cryst. Growth 166 (1996) 722.CrossRefGoogle Scholar
[13] Richter, K. W., Ipser, H., Journal of Phase Equilibria 18 (1997) 1476 CrossRefGoogle Scholar
[14] Jones, E. D., Phys. Letters 22 (1956) 266 CrossRefGoogle Scholar
[15] Ravot, D., Mauger, A., Achard, J. C., Bartholin, M., Rossat-Mignod, J., Phys. Rev. B 28(2) (1983) 4558 CrossRefGoogle Scholar
[16] Nieuwenhuys, G. J. in “Handbook of Magnetic Materials”, Buschow, K. H. J. ed, Elsevier Science B. V. (1995).Google Scholar