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Metalorganic Chemical Vapour Deposition of CuInSe2 From Copper and Indium Diselenocarbamates for Solar Cell Devices

Published online by Cambridge University Press:  10 February 2011

John McAleese
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
David J. Otway
Affiliation:
Department of Chemistry, Imperial College of Science, Technology and Medicine, Exhibition Road, London, SW7 2AZ, UK
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Abstract

Thin film(s) of chalcopyrite CulnSe2 have been grown by low-pressure metal-organic chemical vapour deposition (LP-MOCVD) using the precursors In(Se2CNMenHexyl)3 and precursors Cu(Se2CNMenHexyl)2. The precursors were prepared from carbon diselenide. Films were grown on glass between 400 – 450 °C, and characterized by X-ray diffraction, optical spectroscopy (UV/Vis), EDAX and scanning electron microscopy.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

1. See for example : Nadenau, V., Braunger, D., Hariskos, D., Kaiser, M., Koble, Ch., Ruckh, M., Ruhle, U., Schaffer, R., Schmid, D., Walter, T., Zwergart, S. and Schock, H. W., Prog. Photo. Res. Appl., 3, p.363 (1995).Google Scholar
2. Igarashi, O., J. Cryst. Growth, 130, p.343 (1993).Google Scholar
3. Sagnes, V., Salesse, A., Artaud, M. C., Duchemin, S., Bougnot, J. and Bougnot, G., J. Cryst. Growth, 124, p.620 (1992).Google Scholar
4. Ouchin, F., Gallon, P., Artaud, M. C., Bougnot, J. and Duchemin, S., Crystal Res. Technol., 31, p.S513 (1996).Google Scholar
5. Jones, P. A., Jackson, A. D., Lickiss, P. D., Pilkington, R. D. and Tomlinson, R. D., Thin Solid Films, 238, p.4 (1994).Google Scholar
6. Chichibu, S., Appl. Phys. Lett., 70, p. 1840 (1997).Google Scholar
7. Hursthouse, M. B., Malik, M. A., Motevalli, M. and O'Brien, P. J. Mat. Chem., 2, p. 949 (1992).Google Scholar
8. Motevalli, M., O'Brien, P., Walsh, J. R. and Watson, I. M., Polyhedron, 15, p.2801 (1996).Google Scholar
9. O'Brien, P., Walsh, J. R., Watson, I. M., Hart, L. and Silva, S. R. P., J. Cryst. Growth, 167, p. 133 (1996).Google Scholar
10. O'Brien, P. and Chunggaze, M., unpublished results (1997).Google Scholar
11. O'Brien, P., Otway, D. J. and Walsh, J. R., Adv. Mater., Chem. Vap. Dep., 3, p.227 (1997).Google Scholar
12. McAleese, J., O'Brien, P., and Otway, D. J., Adv. Mater., Chem. Vap. Dep., accepted for publication (1997).Google Scholar
13. Malik, M. A. and O'Brien, P., Adv. Mater. Opt. Elect, 3, p. 171 (1994).Google Scholar
14. O'Brien, P., Otway, D. J. and Walsh, J. R., unpublished results (1997).Google Scholar