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Major Advances in the Synthesis of POSS Monomers

Published online by Cambridge University Press:  01 February 2011

Frank J. Feher ,
Raquel Terroba ,
Ren-Zhi Jin ,
Sabine Lücke ,
Frank Nguyen ,
Richard Brutchey  and
Kevin D Wyndham
Frank J. Feher
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Raquel Terroba
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Ren-Zhi Jin
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Sabine Lücke
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Frank Nguyen
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Richard Brutchey
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
Kevin D Wyndham
Affiliation:
Department of Chemistry, University of California Irvine, CA 92697–2025, U.S.A.
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Abstract

Several new methods have been developed for the synthesis of POSS monomers from fully condensed [RSiO3/2]n and [ROSiO3/2]n (n = 6 or 8) frameworks. These methods, which all rely on highly selective base-catalyzed reactions of Si/O frameworks, provide unprecedented access to new POSS monomers and the means for manufacturing useful POSS monomers on a large scale from readily available silane monomers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC2.1
Copyright
Copyright © Materials Research Society 2000

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References

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