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ESR Studies of the Anion Radicals of the Fullerene: C60 n- (n = 1, 2, and 3).

Published online by Cambridge University Press:  25 February 2011

Dominique Dubois ,
M. Thomas Jones  and
Karl M. Kadish
Dominique Dubois
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204–5641.
M. Thomas Jones
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204–5641.
Karl M. Kadish
Affiliation:
Department of Chemistry, University of Houston, Houston, TX 77204–5641.
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Abstract

The results of ESR studies on several anion radicals of the fullerene C60, C60 n-(n = 1, 2, and 3), in the solvents benzonitrile, dichloromethane, pyridine and tetrahydrofuran containing 0.1 M TBAClO4 are reported and discussed. The samples are prepared by electrochemical reduction techniques which allow the preparation of samples which contain, quantitatively, the desired anionie species. The results of ESR spectral studies on the anions in frozen solutions as a function of temperature are presented. The ESR lineshapes and linewidths are dependent upon the solvent and the temperature. The g-values are weakly dependent upon temperature. The results obtained from this study are presented and discussed in terms of the unique physical structure and properties of C60.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 345
Copyright
Copyright © Materials Research Society 1992

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References

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