Hostname: page-component-745bb68f8f-b6zl4 Total loading time: 0 Render date: 2025-01-27T02:47:09.910Z Has data issue: false hasContentIssue false
  • English
  • Français

Enhancement of Third Order Nonlinearity on Phthalocyanine Compounds

Published online by Cambridge University Press:  21 February 2011

Masahiro Hosoda ,
Tatsuo Wada ,
Akira Yamada ,
Anthony F. Garitoa  and
Hiroyuki Sasabe
Masahiro Hosoda
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Tatsuo Wada
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Akira Yamada
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Anthony F. Garitoa
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Hiroyuki Sasabe
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Get access

Abstract

The third order optical susceptibilities (−3ω; ω, ω ω,) for soluble metallophthalocyanine derivatives were determined by optical third harmonic generation measurements of molecularly doped polymer films at a wavelength of 1907nm. The X(3) value of tetra-tert-butylvanadylphthalocyanine is larger than that of metal-free derivative. We demonstrate experiment on modes of propagating light wave in molecularly doped films which exhibit excellent optical quality. The enhancement of third order optical nonlinear susceptibilities in phthalocyanine compounds are discussed in terms of molecular structure and molecular packing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 175: Symposium S – Multifunctional Materials , 1989 , 89
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Sauteret, C., Hermann, J.P., Fey, R., Pradere, F., Ducuing, J., Baughman, R.H., and Chance, R.R., Phys. Rev. Lett., 36, 956 (1976).Google Scholar
[2] Agrawal, G.P., Cojan, C., and Flytzanis, C., Phys. Rev. B 17, 776 (1978).Google Scholar
[3] Wada, T., Ojima, J., Yamada, A., Garito, A.F., and Sasabe, H., Proceedings of SPIE, 1147, in press.Google Scholar
[4] Wada, T., Matsuoka, Y., Shigehara, K., Yamada, A., Gari, A.F. to, and Sasabe, H., Photoresponsive Materials, edited by Tazuke, S.(Proceedings of the MRS International Meeting on Advanced Materials, 12, 1989).Google Scholar
[5] Wada, T., Yamada, S., Matsuoka, Y., Grossman, C.H., Shigehara, K., Sasabe, H., Yamada, A., and Garito, A.F., Nonlinear Optics of Organics and Semiconductors, edited by T. Kobayashi(Springer Proceedings in Physics, 36, 1989).Google Scholar
[6] Law, K-Y, Inorg. Chem., 24, 1778 (1985).Google Scholar
[7] Mikhalenko, S.K., Barkanova, S.V., Lebedev, O.L., and Luk'yanets, E.A., J. Gen. Chem. USSR, 81, 2770 (1971).Google Scholar
[8] Sharp, J.H. and Lardon, M., J. Phys. Chem., 72, 3230 (1968).Google Scholar
[9] Griffiths, C.H., Walker, M.S., and Goldstein, P., Mol. Cryst. Liq. Cryst., 33, 149 (1976).Google Scholar
[10] Meredith, G.M., Buchalter, B., Hanzlick, C., J. Chem. Phys.,78, 553 (1978).Google Scholar
[11] Kajzar, F. and Messier, J., Thin Solid Films, 132, 11 (1985).Google Scholar
[12] Shirk, J.S., Lindle, J.R., Bartoli, F.J., Hoffman, C.A., Kafafi, Z.H., and Snow, A.W., Appl. Phys. Lett., 13, 1287 (1989).Google Scholar
[13] Robertson, J.M., J. Chem. Soc., 1195 (1936).Google Scholar
[14] Ziolo, R.Z. and Griffiths, C.H., J. Chem. Soc. Dalton Trans., 2300 (1980).Google Scholar
[15] Hosoda, M., Wada, T., Yamada, A., and Sasabe, H., to be published.Google Scholar