Hostname: page-component-745bb68f8f-mzp66 Total loading time: 0 Render date: 2025-02-03T09:18:38.068Z Has data issue: false hasContentIssue false
  • English
  • Français

Dipolar Organic/Ferroelectric Oxide Hybrids

Published online by Cambridge University Press:  15 February 2011

Eric Pascal Bescher ,
Edward Hong ,
Yu-Huan Xu  and
John D. Mackenzie
Eric Pascal Bescher
Affiliation:
Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles CA, 90095- 1595
Edward Hong
Affiliation:
Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles CA, 90095- 1595
Yu-Huan Xu
Affiliation:
Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles CA, 90095- 1595
John D. Mackenzie
Affiliation:
Department of Materials Science and Engineering, University of California, Los Angeles, Los Angeles CA, 90095- 1595
Get access

Abstract

Organic-inorganic hybrids in which both constituents exhibit electrical dipolar properties have been fabricated. The inorganic constituent was either LiNbO3 or BaTiO3, and the organic constituent was triethoxysilyl 2,4-dinitrophenylaminosilane (TDP) cross-linked with SiO2 Transparent films were made in a 1:1 organic:inorganic ratio. The films were characterized optically. Preliminary indication of interactions between organic and inorganic constituents, particularly in the case of BaTiO3-TDP-SiO2, has been observed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 605
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Xu, Yuhuan and Mackenzie, John D., “Ferroelectric Thin Films Prepared by Sol-Gel Processing”, Integrated feroelectrics, 1992 Vol.1, pp. 17–42 Google Scholar
[2] Proceedings of the First European Workshop on Hybrid Organic-Inorganic Materials (Synthesis, Properties, Applications), Sanchez, C. and Editors, F. Ribot, November 8–10 1993,France Google Scholar
[3] Bescher, Eric, Mackenzie, J.D., Ohtsuki, T. and Peyghambarian, N., ”Rare earth/Organic dye nanocomposites by the sol-gel method”, Mat. Res. Soc. Symp. Proc. Vol.351, 1994, 135–139 Google Scholar
[4] Kim, J. and Plawsky, J., ”Second Harmonic Generation in Organically Modified Sol-gel Film”, Chem. Mat. 1992,4, 249–252 Google Scholar
[5] Toussaere, E., Zyss, J., Griesmar, P. and Sanchez, C., Non Linear Optics, 1991, 3 Google Scholar
[6] Griesmar, P., Sanchez, C., Puccetti, G., Ledoux, I. and Zyss, J., Molecular Engineering, 1991, 1, 205 Google Scholar
[7] Lebeau, B., Maquet, J., Sanchez, C., Toussaere, E., Hierle, R., Zyss, J., J. Mater. Chem., 4 (12) 1994, 1855.Google Scholar
[8] Kim, Jongsung and Plawsky, Joel, “Non-Linear Optical Material Fabrication via Sol-Gel Processing”, Mat. Res. Soc. Symp. Proc. Vol.247, 1992, pp 135–140.Google Scholar
[9] Kim, Jongsung, Plawsky, Joel L., Van Wagenen, Elizabeth and Korenowski, Gerald, “Effect of Processing Parameters and Polymerization on the Non-Linear Optical Response of Sol-Gel Materials”, Chem. Mater., 5, 1993, pp. 1118–1125 Google Scholar
[10] Lebeau, B., PhD Thesis, Universite Pierre et Marie Curie, Paris, France, 1996.Google Scholar
[11] Hartman, F.H., ”Light Absorption of Organic Colorants. Theoretical treatment and Empirical rules”, Reactivity and Structure Concepts in Organic Chemistry”,Volume 12; K. HafnerSpringer-Verlag Publ., 1980, pp. 83–36.Google Scholar
[9] “Synthesis of Bimetallic Barium Titanium Alkoxides as Precursors for Electrical Ceramics”, Inorg. Chem. 1991, 30, 3244–3245 Google Scholar