Published online by Cambridge University Press: 22 February 2011
The implementation of a wet oxidation process in an RTP system using a bubbler with deionized water is described. A special process related calibration in a wet atmosphere, by means of pyrometer and thermocouple readings, allows one to improve the temperature accuracy during the oxidation to an offset of only + 1 to 2°C. High oxide growth rates, up to a factor of 1.8 above literature data have been achieved. Wet and dry RTO oxides are compared and related to the expectations from growth models. Effects of growth time (10 s to 4 min), growth temperature (675°C-950°C), substrate orientation (100,111), preparation (e.g. HF) and bubbler temperature (20°C-90°C) are presented. The uniformity of oxides on 4 and 6 inch diameter wafers are discussed. Preferentially by the use of a silicon guard ring and by adjusting lamp power and gas flow rates excellent results concerning uniformity (standard deviations 2σ: 1-2 %) and reproducibility (variation of 0.5 to 0.75 % at least over 12 wafers) are obtained.