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Electrical and Electrochemical Properties of Nanocomposite Thin Films Formed by Exchange-Precipitation Route from Nanocrystals and Organic Cross-Linkers

Published online by Cambridge University Press:  21 March 2011

Frank L. Leibowitz ,
Wenxia Zheng ,
Mathew M. Maye ,
Nam K. Ly  and
Chuan-Jian Zhong
Frank L. Leibowitz
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
Wenxia Zheng
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
Mathew M. Maye
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
Nam K. Ly
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
Chuan-Jian Zhong
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902, [email protected]
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Abstract

The structural, electrical and electrochemical properties of nanoparticle thin films derived by a one-step exchange-crosslinking-precipitation route were characterized by microscopic, spectroscopic and electrochemical techniques. Thiolate-encapsulated gold nanocrystals of 2-nm and 5-nm core sizes and alkyldithiol crosslinkers were studied as a model system. The mixing of the two components in solutions allowed sequential exchanging, crosslinking and precipitation of dithiol-crosslinked nanocrystal thin films. The films were specularly reflecting and electronically continuous, and have potential applications in catalysis and molecular recognition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 598: Symposium BB – Electrical, Optical, & Magenetic Properties...V , 1999 , BB3.63
Copyright
Copyright © Materials Research Society 1999

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References

1. Hostetler, M. J. and Murray, R. J., Curr. Opin. Colloid Interface Sci., 2, 42 (1997), (and refes. therein.)Google Scholar
2. Brust, M., Walker, M., Bethell, D., Schiffrin, D. J. and Whyman, R., J. Chem. Soc., Chem. Commun., 801 (1994).Google Scholar
3. Hoetetler, M. J., Wingate, J. E., Zhong, C. J., Harris, J. E., Vachet, R. W., Clark, M. R., Londono, J. D., Green, S. J., Stokes, J. J., Wignall, G. D., Glish, G. L., Porter, M. D., Evans, N. D. and Murray, R. W., Langmuir, 14, 17 (1998).Google Scholar
4. Whetten, R. L., Khoury, J. T., Alvarez, M. M., Murthy, S., Vezmar, L., Wang, Z. L., Stephens, P. W., Cleveland, C. L., Luedtke, W. D. and Landman, U., Adv. Mater. 8, 428 (1996).Google Scholar
5. (a) Brust, M., Bethell, D., Kiely, C. J. and Schiffrin, D. J., Langmuir, 14, 5425 (1998), (b) D. Bethell, M. Brust, D. J. Schiffrin and C. J. Kiely, J. Electroanal. Chem. 409, 137 (1996).Google Scholar
6. Musick, M. D., Pena, D. J., Botsko, S. L., McEvoy, T. M., Richardson, J. N. and Natan, M. J., Langmuir, 15, 844 (1999).Google Scholar
7. Templeton, A. C., Hostetler, M. J., Warmoth, E. K., Chen, S. W.. Hartshorn, C. M.. Krishnamurthy, V. M., Forbes, M. D. E. and Murray, R. W., J. Amer. Chem. Soc. 120, 4845 (1998).Google Scholar
8. (a) Zhong, C. J., Zheng, W. X. and Leibowitz, F. L., Electrochem. Commun., 1, 72 (1999). (b) F.L Leibowitz, W. X. Zheng, M. M. Maye and C. J. Zhong, Anal. Chem., (in press).Google Scholar
9. (a) Zhong, C. J., Zheng, W. X., Leibowitz, F. L., Eichelberger, H. H., Chem. Commun., 13, 1211 (1999). (b) M. M. Maye, W. X. Zheng, F. L. Leibowitz, N. K. Ly, C. J. Zhong, Langmuir, (in press).Google Scholar
10. Mirkin, C., Letsinger, R. L., Mucic, R. C., Storhoff, J. J., Nature. 382, 607.(1996).Google Scholar
11. Terrill, R. H., Postlethwaite, T. A., Chen, C. H., Poon, C. D., Terzis, A., Chen, A. D., Hutchison, J. E., Clark, M. R., Wignall, G., Londono, J. D, Superfine, R., Falvo, M., Johnson, C. S., Samulski, E. T. and Murray, R. W., J. Amer. Chem. Soc. 117, 12537 (1995).Google Scholar
12. (a) Zhong, C. J., Zak, J. and Porter, M. D., J. Electroanal. Chem., 421, 9 (1997). (b) C. A. Widrig, C. Chung and M. D. Porter, J. Electroanal. Chem., 310, 335 (1991).Google Scholar