Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-28T03:04:24.083Z Has data issue: false hasContentIssue false

Effects of Growth Parameters on Surface-morphological, Structural, Electrical and Optical Properties of AZO Films by RF Magnetron Sputtering

Published online by Cambridge University Press:  31 January 2011

Shou-Yi Kuo
Affiliation:
[email protected], Chang Gung University, Department of Electronic Engineering, 259 Wen-Hwa 1st Road, Kweishan, Taoyuan 333, Taiwan, Tao-Yuan, 33302, Taiwan, Province of China
Wei-Ting Lin
Affiliation:
[email protected]@mail.cgu.edu.tw
Liann-Be Chang
Affiliation:
[email protected], Chung-Sung institute of Science & Technology, Chemical Systems Research Division, Tao-Yuan, Taiwan, Province of China
Ming-Jer Jeng
Affiliation:
[email protected], Chang Gung University, Department of Electronic Engineering, 259 Wen-Hwa 1st Road, Kweishan, Taoyuan 333, Taiwan, Tao-Yuan, 33302, Taiwan, Province of China
Yong-Tian Lu
Affiliation:
[email protected], Chung-Sung institute of Science & Technology, Chemical Systems Research Division, Tao-Yuan, Taiwan, Province of China
Sung-Cheng Hu
Affiliation:
[email protected], Chung-Sung institute of Science & Technology, Chemical Systems Research Division, Tao-Yuan, Taiwan, Province of China
Get access

Abstract

500 nm-thick aluminum-doped zinc oxide (ZnO:Al) thin film is usually used as a front transparent conductive oxide (TCO) contact on photovoltaic devices, and for this application is often deposited by a reactive radio-frequency (r.f.) magnetron sputtering system from a ceramic target. This work reports on the preparation and characterization of AZO thin films on Corning 1737 glass substrates grown by reactive r.f.-magnetron sputtering from a ZnO ceramic target with 2 wt% Al content. It was found that the growth parameters, such as chamber pressure, working power, and deposition temperature, have significant influences on the properties of AZO films. According to the experimental results: (1) Films were polycrystalline showing a strong preferred c-axis orientation. (2) With increasing working power, the resistivity decreased, and mobility and the carrier concentration increased. (3) Lower deposition temperature leads to a decrease in resistivity, with 2.5×10-4 Ω-cm representing the lowest resistivity reached.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Granqvist, C. G., Solar Energy Mater. Solar Cells 91, 1529 (2007).10.1016/j.solmat.2007.04.031Google Scholar
2 Lee, Jae-Hyeong, Song, Jun-Tae, Thin Solid Films 516, 1377 (2008).10.1016/j.tsf.2007.03.078Google Scholar
3 Latz, R., Michael, K., Scherer, M., Jpn. J. Appl. Phys. 30 (2A), L149 (1991).10.1143/JJAP.30.L149Google Scholar
4 Mandal, S., Singha, R.K., Dhar, A., Ray, S.K., Mater. Res. Bull. 43, 244 (2007).10.1016/j.materresbull.2007.05.006Google Scholar
5 Lee, Jaehyeong, Lee, Dongjin, Lim, Donggun, Yang, Keajoon, Thin Solid Films 515, 6094 (2007).10.1016/j.tsf.2006.12.099Google Scholar
6 Szörényi, T., Laude, L.D., Bertóti, I., Kántor, Z., Geretovsky, Zs., J. Appl. Phys. 78, 6211 (1995).10.1063/1.360567Google Scholar
7 Kluth, O., Schöpe, G., Rech, B., Menner, R., Oertel, M., Orgassa, K., Schock, H.W., Thin Solid Films 502, 311 (2006).10.1016/j.tsf.2005.07.313Google Scholar
8 Nunes, P., Costa, D., Fortunato, E., Martins, R., Vacuum 64, 293 (2002).10.1016/S0042-207X(01)00323-2Google Scholar
9 Lu, Y. M., Hwang, W. S., Liu, W. Y., Yang, J. S., Mater. Chem. Phys. 72, 269 (2001).10.1016/S0254-0584(01)00450-3Google Scholar
10 Liu, W. F., Du, G. T., Sun, Y. F., Bian, J. M., Chang, Y., Yang, T. P., Chang, Y. C., Xu, Y. B., Applied Surface Science 253, 2999 (2007).10.1016/j.apsusc.2006.06.049Google Scholar
11 Cullity, B.D., Elements of X-ray Diffraction, second ed., Addison Wesley, Reading, MA, 1978.Google Scholar