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Conjugated Polymers Containing Pendant Terpyridine Complexes as Photoactive Sensors

Published online by Cambridge University Press:  10 February 2011

Biwang Jiang ,
Shailesh Sahay  and
Wayne E. Jones Jr.
Biwang Jiang
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
Shailesh Sahay
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
Wayne E. Jones Jr.
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
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Abstract

We have synthesized a novel conjugated polymer containing terpyridine receptors. This conjugated, polymer-based fluorescent chemosensory system exhibits unusually high sensitivity toward transition metal ions (∼-10−9 M). The fluorescence quenching response of the terpyridine containing conjugated polymer to transition metal ions is related to a facile energy migration in which energy from absorption of a photon, can migrate through the conjugated polymer system and be quenched by trapping sites. Terpyridine receptors can readily bind to transition metal ions and create a low lying Metal to Ligand Charge Transfer (MLCT) state which can act as an excitation trap.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 671
Copyright
Copyright © Materials Research Society 1998

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References

1. (a) Czarnik, A. W., Fluorescent Chemosensory for Ion and Molecular Recognition, Ed. (ACS Symposium Series 538; ACS: Washington, DC, 1993). (b) A. Prasanna de Silva, H. Q. Nimal Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, and T. E. Rice, Chem. Rev. 97, 1515 (1997). (c) Omowunmi A. Sadik, Anallytical Methods and Instrumentation, 2, 293 (1995).Google Scholar
2. (a) Zhou, Q., Swager, T. M., J. Am. Chem. Soc. 117, 12593 (1995);(b) M. J. Marsella, P. J. Carrol, T. M. Swager, ibid. 117, 9832 (1995); (c) M. J. Marsella, P. J. New land, P. J. Carrol, T. M. Swager, ibid, 117, 9842 (1995); (d) T. M. Swager, M. J. Marsella, Adv. Mater 6, 595 (1994).Google Scholar
3. Wang, B., Wasielewski, M. R., J. Am. Chem. Soc. 119, 12 (1997).Google Scholar
4. Brockmann, T. W., Tour, J. S., J. Am. Chem. Soc. 117, 4437 (1995).Google Scholar
5. McCullough, R. D., Williams, S. P., Chem. Mater. 7, 2001 (1995).Google Scholar
6. Swager, T. M., Gil, C. J., Wrighton, M. S., J. Phys. Chem. 99, 4886 (1995).Google Scholar
7. (a) Barigelletti, F., Flamigni, L., Balzani, V., Collin, J. P., Sauvage, J. P., Sour, A., Constable, E. C., and Thompson, A. M. W. C., J. Am. Chem. Soc. 116, 7692, (1994). (b) E. C. Constable, P. Harverson and M. Oberholzer, Chem. Commun. 1821, (1996).Google Scholar
8. For reviews see (a) Balzani, V., Juris, A., Venturi, M., Chem. Rev. 96, 759 (1997). (b) J. P. Sauvage, J. P. Collin, J. C. Chambron, S. Guillerez, and C. Coudret, Chem. Rev. 94, 993, (1994).Google Scholar
9. Jiang, Biwang, Jones, Wayne E. Jr. Manuscript in preparation.Google Scholar
10. Jiang, B., Yang, S., Jones, W.E. Jr. Chem. Materials, 9, 2031 (1997).Google Scholar