Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-27T06:07:13.810Z Has data issue: false hasContentIssue false

Chemical Synthesis of Fine Powders

Published online by Cambridge University Press:  29 November 2013

Get access

Extract

Interest in the synthesis of submicron monodispersed powders is increasing. Such powders find applications in the ceramic industry when high performance materials are required. Sintering time and temperature can be significantly reduced with powders of narrow particle-size distribution. Fine colloidal particles can be made by a variety of methods, from the vapor phase or the liquid phase.

The sol gel process offers new approaches to the synthesis of fine powders. Starting from molecular precursors, such as metal alkoxides or aqueous solutions, an oxide network is obtained via inorganic polymerization reactions. These reactions occur in solution, and the term “sol-gel processing” is often used to describe the synthesis of inorganic oxides by wet chemical methods. It offers many advantages compared to the conventional powder route. One unique advantage is the ability to go all the way from the molecular precursor to the solid material, permitting better control of the entire process and allowing synthesis of “tailor-made” powders.

Type
Fine Particles Part II
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Zelinski, B.J.J. and Uhlmann, D.R., J. Phys. Chem. Solids 45 (1984) p. 1069.CrossRefGoogle Scholar
2.Woodhead, J.L., J. Physique C1-47 (1986) p. 1.Google Scholar
3.Livage, J., Henry, M., and Sanchez, C., Prog. Solid State Chem. 18 (1988) p. 259.CrossRefGoogle Scholar
4.Nielsen, A.E., in “Kinetics of Precipitation,” (Pergamon Press, Oxford, 1964).Google Scholar
5.Overbeek, J.Th.G., Adv. Colloid Interface Sci. 15 (1982) p. 251.CrossRefGoogle Scholar
6.LaMer, V.K. and Digenar, R.H., J. Am. Chem. Soc. 72 (1950) p. 4847.CrossRefGoogle Scholar
7.Nielsen, A.E., in Crystal Growth, edited by Peiser, H.S. (Pergamon Press, Oxford, 1967) p. 419.Google Scholar
8.Bell, A. and Marijević, E., J. Phys. Chem. 78 (1974) p. 2621.CrossRefGoogle Scholar
9.Matijević, E., Ann. Rev. Mater. Sci. 15 (1985) p. 483.CrossRefGoogle Scholar
10.Segal, D.L., J. Chem. Tech. Biotechnol. 34A (1984) p. 25.CrossRefGoogle Scholar
11.Ayral, A., Phalippou, J., and Droguet, J.C., in Better Ceramics Through Chemistry III, edited by Brinker, C. Jeffrey, Clark, David E., and Ulrich, Donald R. (Mater. Res. Soc. Symp. Proc. 121, Pittsburgh, PA, 1988) p. 239.Google Scholar
12.Haruta, M. and Delmon, B., J. Chem. Phys. 83 (1986) p. 859.Google Scholar
13.Livage, J. and Henry, M., in Ultrastructure Processing of Advanced Ceramics, edited by Mackenzie, J.D. and Ulrich, D.R. (Wiley, New York, 1988) p. 183.Google Scholar
14.Henry, M., Jolivet, J.P., and Livage, J., 4th Int. Conf. “Ultrastructure Processing of Ceramics, Glasses, and Composites,” (Tuckson, 1989)in press.Google Scholar
15.Little, E.J. and Jones, M.M., J. Chem. Educ. 37 (1960) p. 231.CrossRefGoogle Scholar
16.Ardon, M. and Bino, A., Structure and Bonding 65 (1987) p. 1.CrossRefGoogle Scholar
17.Beukenkamp, J. and Herrington, K.D., J. Am. Chem. Soc. 82 (1960) p. 3025.CrossRefGoogle Scholar
18.Limar, T.F. and Artyushenko, A.I., Russ. J. Inorg. Chem. 14 (1969) p. 1628.Google Scholar
19.Bekkerman, L.I., Dobrovol'skii, I.P. and Ivakin, A.A., Russ. J. Inorg. Chem. 21 (1976) p. 223.Google Scholar
20.Narita, E., Takenchi, H., Horiguchi, N., and Okabe, T., Bull. Chem. Soc. Jpn. 57 (1984) p. 1388.CrossRefGoogle Scholar
21.Matijević, E., Budnik, M., and Meites, L., J. Colloid Interface Sci. 61 (1977) p. 302.CrossRefGoogle Scholar
22.Duncan, J.F. and Richards, R.G., New Zealand J. Sci. 19 (1976) p. 179.Google Scholar
23.Duncan, J.F. and Richards, R.G., New Zealand J. Sci. 19 (1976), p. 185.Google Scholar
24.Blesa, M.A., Maroto, A.J.G., Passagio, S.I., Figliolia, N.E., and Rigotti, G., J. Mater. Sci. 20 (1985) p. 4601.CrossRefGoogle Scholar
25.De Hek, H., Stol, R.J., and De Bruyn, P.L., J. Colloid Interface Sci. 64 (1978) p. 72.CrossRefGoogle Scholar
26.Matijević, E., Sapieszko, R.S., and Melville, J.B., J. Colloid Interface Sci. 50 (1975) p. 567.CrossRefGoogle Scholar
27.Larson, R.I., Fulman, E.F., Lindsay, A.D., and Matijevic, E., AIChE J. 19 (1973) p. 602.CrossRefGoogle Scholar
28.Barringer, E.A. and Bowen, H.K., Langmuir 1 (1985) p. 414.CrossRefGoogle Scholar
29.Barringer, E.A. and Bowen, H.K., J. Amer. Ceram. Soc. 65 (1982) p. C199.CrossRefGoogle Scholar
30.Babonneau, F., Doeuff, S., Leaustic, A., Sanchez, C., Cartier, C., and Verdaguer, M., Inorg. Chem. 27 (1988) p. 3166.CrossRefGoogle Scholar
31.Hartel, R.W. and Berglund, K.A., in Better Ceramics Through Chemistry II, edited by Brinker, C. Jeffrey, Clark, David E., and Ulrich, Donald R. (Mater. Res. Soc. Symp. Proc. 73, Pittsburgh, PA, 1986) p. 633.Google Scholar
32.Harris, M.T. and Byers, C.H., J. Non-Cryst. Solids 103 (1988) p. 49.CrossRefGoogle Scholar
33.Bradley, D.C., Mehrotra, R.C., and Gaur, D.P., in Metal Alkoxides (Academic Press, London, 1978).Google Scholar
34.Ogihara, T., Ikemoto, T., Mizutami, N., Kato, M., and Mitarai, Y., J. Mater. Sci. 21 (1986) p. 2771.CrossRefGoogle Scholar
35.Ogihara, T., Mizutami, N., and Kato, M., J. Amer. Ceram. Soc. 72 (1989) p. 421.CrossRefGoogle Scholar
36.Doeuff, S., Henry, M., Sanchez, C., and Livage, J., J. Non-Cryst. Solids 89 (1987) p. 206.CrossRefGoogle Scholar
37.Sanchez, C., Babonneau, F., Doeuff, S., and Leaustic, A., in Ultrastructure Processing of Advanced Ceramics, edited by Mackenzie, J.D. and Ulrich, D.R. (Wiley, New York, 1988) p. 77.Google Scholar
38.Leaustic, A., Babonneau, F., and Livage, J., Chemistry of Materials 1 (1989) p. 240.CrossRefGoogle Scholar
39.Rinn, G. and Schmidt, H., in Ceramic Transactions 1A, edited by Messing, G.L. and Fuller, E.R. (Amer. Ceram. Soc, Westerville, 1988) p. 23.Google Scholar
40.Sanchez, C., Livage, J., Henry, M., and Babonneau, F., J. Non-Cryst. Solids 100 (1988) p. 65.CrossRefGoogle Scholar
41.Stol, R.J. and De Bruyn, P.L., J. Colloid Interface Sci. 75 (1980) p. 185.CrossRefGoogle Scholar
42.Botet, R. and Jullien, R., J. Phys. A: Math Gen. 17 (1984) p. 2517.CrossRefGoogle Scholar