Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-28T08:15:53.812Z Has data issue: false hasContentIssue false
  • English
  • Français

Elucidating the evolution of silicon anodes in lithium based batteries

Published online by Cambridge University Press:  17 July 2020

Wenzao Li ,
Mallory N. Vila ,
Esther S. Takeuchi ,
Kenneth J. Takeuchi  and
Amy C. Marschilok Open the ORCID record for Amy C. Marschilok [Opens in a new window]
Wenzao Li
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Mallory N. Vila
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794
Esther S. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy and Photon Sciences Directorate, Brookhaven National Laboratory, UptonNY11973
Kenneth J. Takeuchi
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794
Amy C. Marschilok*
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, NY11794 Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY11794 Energy and Photon Sciences Directorate, Brookhaven National Laboratory, UptonNY11973
*
*Corresponding author:[email protected]
Get access

Abstract

Silicon has attracted particular attention as a potential high capacity material for lithium based batteries. However, the application of Si-based electrodes remains challenging, in major part due to its significant irreversible energy loss during cycling. Here isothermal microcalorimetry (IMC) is demonstrated to be a precise and operando characterization method for tracking a battery's thermal behaviour and deconvoluting the contributions from electrochemical polarization, entropy change, and parasitic reactions. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and x-ray powder diffraction (XRD) further elucidate the Si reactivity in conjunction with the IMC.

Type
Articles
Information
MRS Advances , Volume 5 , Issue 48-49: Energy, Storage and Conversion , 2020 , pp. 2525 - 2534
Copyright
Copyright © Materials Research Society 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

┼

equal contributions by W. Li and M. Vila.

References

Mills, A. and Al-Hallaj, S.: Simulation of passive thermal management system for lithium-ion battery packs. Journal of Power Sources 141, 307 (2005).CrossRefGoogle Scholar
Abdul-Quadir, Y., Laurila, T., Karppinen, J., Jalkanen, K., Vuorilehto, K., Skogström, L. and Paulasto-Kröckel, M.: Heat generation in high power prismatic Li-ion battery cell with LiMnNiCoO2 cathode material. International Journal of Energy Research 38, 1424 (2014).CrossRefGoogle Scholar
Barkholtz, H.M., Preger, Y., Ivanov, S., Langendorf, J., Torres-Castro, L., Lamb, J., Chalamala, B. and Ferreira, S.R.: Multi-scale thermal stability study of commercial lithium-ion batteries as a function of cathode chemistry and state-of-charge. Journal of Power Sources 435, 226777 (2019).CrossRefGoogle Scholar
Shurtz, R.C., Preger, Y., Torres-Castro, L., Lamb, J., Hewson, J.C. and Ferreira, S.: Perspective—From Calorimetry Measurements to Furthering Mechanistic Understanding and Control of Thermal Abuse in Lithium-Ion Cells. Journal of The Electrochemical Society 166, A2498 (2019).CrossRefGoogle Scholar
Krause, L.J., Jensen, L.D. and Dahn, J.R.: Measurement of parasitic reactions in Li ion cells by electrochemical calorimetry. Journal of The Electrochemical Society 159, A937 (2012).CrossRefGoogle Scholar
Huie, M.M., Bock, D.C., Bruck, A.M., Tallman, K.R., Housel, L.M., Wang, L., Thieme, J., Takeuchi, K.J., Takeuchi, E.S. and Marschilok, A.C.: Isothermal Microcalorimetry: Insight into the Impact of Crystallite Size and Agglomeration on the Lithiation of Magnetite, Fe3O4. ACS Applied Materials & Interfaces 11, 7074 (2019).CrossRefGoogle ScholarPubMed
Huie, M.M., Bock, D.C., Wang, L., Marschilok, A.C., Takeuchi, K.J. and Takeuchi, E.S.: Lithiation of Magnetite (Fe3O4): Analysis Using Isothermal Microcalorimetry and Operando X-ray Absorption Spectroscopy. The Journal of Physical Chemistry C 122, 10316 (2018).CrossRefGoogle Scholar
Li, J., Downie, L.E., Ma, L., Qiu, W. and Dahn, J.R.: Study of the failure mechanisms of LiNi0. 8Mn0. 1Co0. 1O2 cathode material for lithium ion batteries. Journal of The Electrochemical Society 162, A1401 (2015).Google Scholar
Downie, L.E., Hyatt, S.R., Wright, A.T.B. and Dahn, J.R.: Determination of the time dependent parasitic heat flow in lithium ion cells using isothermal microcalorimetry. The Journal of Physical Chemistry C 118, 29533 (2014).CrossRefGoogle Scholar
Assat, G., Glazier, S.L., Delacourt, C. and Tarascon, J.-M.: Probing the thermal effects of voltage hysteresis in anionic redox-based lithium-rich cathodes using isothermal calorimetry. Nature Energy 4, 647 (2019).CrossRefGoogle Scholar
Downie, L.E. and Dahn, J.R.: Determination of the voltage dependence of parasitic heat flow in lithium ion cells using isothermal microcalorimetry. Journal of The Electrochemical Society 161, A1782 (2014).CrossRefGoogle Scholar
Downie, L. and Dahn, J.: Determination of the Voltage Dependence of Parasitic Heat Flow in Lithium Ion Cells Using Isothermal Microcalorimetry. Journal of The Electrochemical Society 161, 1782 (2014).CrossRefGoogle Scholar
Xu, C., Lindgren, F., Philippe, B., Gorgoi, M., Björefors, F., Edström, K. and Gustafsson, T.: Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive. Chemistry of Materials 27, 2591 (2015).CrossRefGoogle Scholar
Zuo, X., Zhu, J., Müller-Buschbaum, P. and Cheng, Y.-J.: Silicon based lithium-ion battery anodes: A chronicle perspective review. Nano Energy 31, 113 (2017).CrossRefGoogle Scholar
Su, X., Wu, Q., Li, J., Xiao, X., Lott, A., Lu, W., Sheldon, B.W. and Wu, J.: Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review. Advanced Energy Materials 4, 1300882 (2014).CrossRefGoogle Scholar
Housel, L.M., Li, W., Quilty, C.D., Vila, M.N., Wang, L., Tang, C.R., Bock, D.C., Wu, Q., Tong, X., Head, A.R., Takeuchi, K.J., Marschilok, A.C. and Takeuchi, E.S.: Insights into Reactivity of Silicon Negative Electrodes: Analysis Using Isothermal Microcalorimetry. ACS Applied Materials & Interfaces 11, 37567 (2019).CrossRefGoogle ScholarPubMed
Chattopadhyay, S., Lipson, A.L., Karmel, H.J., Emery, J.D., Fister, T.T., Fenter, P.A., Hersam, M.C. and Bedzyk, M.J.: In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode. Chemistry of Materials 24, 3038 (2012).CrossRefGoogle Scholar
Balbuena, P.B. and Wang, Y.: Lithium-ion batteries: solid-electrolyte interphase, (Imperial college press 2004).CrossRefGoogle Scholar
Guerin, K.: Effect of Graphite Crystal Structure on Lithium Electrochemical Intercalation. Journal of The Electrochemical Society 146, 3660 (1999).CrossRefGoogle Scholar
Cho, J.-H. and Picraux, S.T.: Silicon Nanowire Degradation and Stabilization during Lithium Cycling by SEI Layer Formation. Nano Letters 14, 3088 (2014).CrossRefGoogle ScholarPubMed
Li, J. and Dahn, J.R.: An in situ X-ray diffraction study of the reaction of Li with crystalline Si. Journal of The Electrochemical Society 154, A156 (2007).CrossRefGoogle Scholar
Al Hallaj, S., Venkatachalapathy, R., Prakash, J. and Selman, J.R.: Entropy changes due to structural transformation in the graphite anode and phase change of the LiCoO2 cathode. Journal of the Electrochemical Society 147, 2432 (2000).CrossRefGoogle Scholar
Reynier, Y., Graetz, J., Swan-Wood, T., Rez, P., Yazami, R. and Fultz, B.: Entropy of Li intercalation in Li x CoO 2. Physical Review B 70, 174304 (2004).CrossRefGoogle Scholar
de la Hoz, J.M.M. and Balbuena, P.B.: Reduction mechanisms of additives on Si anodes of Li-ion batteries. Physical Chemistry Chemical Physics 16, 17091 (2014).CrossRefGoogle Scholar
Liu, W.-R., Guo, Z.-Z., Young, W.-S., Shieh, D.-T., Wu, H.-C., Yang, M.-H. and Wu, N.-L.: Effect of electrode structure on performance of Si anode in Li-ion batteries: Si particle size and conductive additive. Journal of Power Sources 140, 139 (2005).CrossRefGoogle Scholar
Chen, L.B., Xie, J.Y., Yu, H.C. and Wang, T.H.: An amorphous Si thin film anode with high capacity and long cycling life for lithium ion batteries. Journal of Applied Electrochemistry 39, 1157 (2009).CrossRefGoogle Scholar
Shobukawa, H., Alvarado, J., Yang, Y. and Meng, Y.S.: Electrochemical performance and interfacial investigation on Si composite anode for lithium ion batteries in full cell. Journal of Power Sources 359, 173 (2017).CrossRefGoogle Scholar
Hou, T., Yang, G., Rajput, N.N., Self, J., Park, S.-W., Nanda, J. and Persson, K.A.: The influence of FEC on the solvation structure and reduction reaction of LiPF6/EC electrolytes and its implication for solid electrolyte interphase formation. Nano Energy 64, 103881 (2019).CrossRefGoogle Scholar
Shen, B.H., Wang, S. and Tenhaeff, W.E.: Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability. Science advances 5, eaaw4856 (2019).CrossRefGoogle ScholarPubMed
Choudhury, S. and Archer, L.A.: Lithium fluoride additives for stable cycling of lithium batteries at high current densities. Advanced Electronic Materials 2, 1500246 (2016).CrossRefGoogle Scholar