Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-30T16:16:04.186Z Has data issue: false hasContentIssue false
  • English
  • Français

Titrimetric analysis for silicon

Published online by Cambridge University Press:  05 July 2018

G. I. Z. Kalocsai  and
J. J. Hockley
G. I. Z. Kalocsai
Affiliation:
Department of Geology, University of New England, Armidale, New South Wales, 2351, Australia
J. J. Hockley
Affiliation:
Department of Geology, University of New England, Armidale, New South Wales, 2351, Australia
Get access Rights & Permissions [Opens in a new window]

Summary

Rapid, accurate silica determinations have been made titrimetrically following decomposition by HClO4-HF in a ‘Teflon’ vessel, the volatilized silicon tetrafluoride being precipitated as K2SiF6 in a HF-KF-glycerol-alcohol mixture. After filtration and washing with alcohol the precipitate is dissolved in boiling water, then titrated with NaOH. This method has many advantages over conventional gravimetric or spectrophotometric procedures.

Type
Research Article
Information
Mineralogical Magazine , Volume 38 , Issue 297 , March 1972 , pp. 618 - 622
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1972

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Flanagan, (F.J.), 1969. Geochimica Acta, 33, 81-120.CrossRefGoogle Scholar
Hillebrand, (W.F.) and LUNDELL (G. E. F.), 1953. Applied Inorganic Analysis, 2nd edn, New York (John Wiley & Sons).Google Scholar
Katz, (A.), 1968. Amer. Min. 53, 283-9.Google Scholar
Langmyhr, (F.J.) and Graff, (P.R.), 1965. Norges Geol. Undersök. no. 230 , 1–128.Google Scholar
Shapiro, (L.) and Brannock, (W.W.), 1956. U.S. Geol. Surv. Bull. 1036-C.Google Scholar
Smales, (A.A.) and Wager, (L.R.), 1960. Methods in Geochemistry. New York (Interscience Publishers).CrossRefGoogle Scholar
Stevens, (R.E.) and Niles, (W.W.), 1960. U.S. Geol. Surv. Bull. 1113. Part I. Chemical Analyses of the Granite and the Diabase, 3-43.Google Scholar
Story-MASKELYNE, (N.), 1870. Phil. Trans. 160, 198; Chem. News, 21, 27.Google Scholar
Washington, (H.S.), 1930. The Chemical Analysis of Rocks, 4th edn, New York (John Wiley & Sons).Google Scholar