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The synthesis of birnessite, cryptomelane, and some other oxides and hydroxides of manganese

Published online by Cambridge University Press:  05 July 2018

R. M. McKenzie*
Affiliation:
C.S.I.R.O., Division of Soils, Glen Osmond, South Australia, 5064

Summary

Detailed methods are described for the laboratory preparation of the manganese minerals manganosite, hausmannite, manganite, partridgeite, birnessite, cryptomelane, pyrolusite, and todorokite. New data are presented on the conversion of birnessite to cryptomelane, and on the exchange properties of potassium in these two minerals. It was found that the upper limit of potassium in cryptomelane is about 7 % K, while the lower limit lies between 0·25 % and 2·2 % K.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1971

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References

Bricker, (O.), 1965. Amer. Min. 50, 1296-1354.Google Scholar
Buser, (W.), Graf, (P.), and Feitknecht, (W.), 1954. Helv. Chim. Acta. 37, 2322-33.CrossRefGoogle Scholar
Byström, (A.) and BYSTROM (ANN MARIE), 1950. Acta cryst. 3, 146-54.CrossRefGoogle Scholar
Cole, (W.F.), Wadsley, (A.D.), and Walkley, (A.), 1947. Trans. Electrochem. Soc. 92, 133-58.CrossRefGoogle Scholar
Feitknecht, (W.) and Marti, (W.), 1945. Helv. Chim. Acta. 28, 129-48.CrossRefGoogle Scholar
Jones, (L. H. P.) and MILNE (ANGELA A.), 1956. Min. Mag. 31, 283-8.Google Scholar
McKENZIE, (R.M.), 1970. Aust. Journ. Soil Res. 8, 97.IO6.CrossRefGoogle Scholar
Moore, (T.E.), ELLIS (MARYLIN), and Selwood, (P.W.), 1950. Journ. Amer. Chem. Soc. 72, 856-66.CrossRefGoogle Scholar
Taylor, (R.M.), McKenzie, (R.M.), and NORR1Sh, (K.), 1964. Aust. Journ. Soil Res. 2, 235-48.CrossRefGoogle Scholar
Wadsley, (A.D.), 1950. Journ. Amer. Chem. Soc. 72, 1781-84.CrossRefGoogle Scholar
Wadsley, (A.D.), and Walkley, (B.A.), 1951. Rev. pure appl. Chem. 1, 203-13.Google Scholar
Zwicker, (W.K.), MEIJER (W. O. J, G.), and Jaefe, (H.W.), 1962. Amer. Mitt. 47, 246-66.Google Scholar