Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-15T03:23:45.677Z Has data issue: false hasContentIssue false
  • English
  • Français

Characteristics of halloysite associated with rectorite from Hubei, China

Published online by Cambridge University Press:  05 July 2018

H.-L. Hong  and
J.-X. Mi
H.-L. Hong*
Affiliation:
Faculty of Earth Sciences, China University of Geosciences, Wuhan, Hubei, 430074, P.R. China
J.-X. Mi
Affiliation:
Department of Materials Science and Engineering, Xiamen University, Xiamen, Fujian, 361005, P.R. China
*
*E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

The mineralogical characteristics of halloysite in rectorite pelite in the Zhongxiang area, Hubei, China, were investigated using X-ray diffraction, scanning electron microscopy and high-resolution transmission electron microscopy methods. The results show that halloysite crystals exhibit euhedral lamellar, tubular or club-like, and needle-like or fibre-like morphologies, indicating that they crystallized from a significantly water-saturated environment. The mineral assemblage of the rectorite pelite is rectorite, halloysite, illite, gypsum, pyrite and rutile, suggesting a weak supergene alteration. Several features related to crystallization of halloysite were noted. Growth of halloysite on rectorite edge surfaces in voids and twins of halloysite on a nanometer scale with composition plane (110) were found in the Zhongxiang rectorite pelite, and, in particular, the tapered ends of tubes suggest that halloysite crystallized from solution. Disaggregation of lamellar halloysite particles into parallel clusters of single tubular halloysite crystals suggests that because of significant [H2O] activity in the environment, halloysite may have been derived from the alteration of rectorite.

Keywords

halloysitetwinsrectoritealteration
Type
Research Article
Information
Mineralogical Magazine , Volume 70 , Issue 3 , June 2006 , pp. 257 - 264
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Adamo, P., Violante, P. and Wilson, M.J. (2001) Tubular and spheroidal halloysite in pyroclastic deposits in the area of the Roccamonfina vocano (Southern Italy). Geoderma, 99, 295–316.CrossRefGoogle Scholar
Askenasy, P.E., Dixon, J.B. and McKee, T.R. (1973) Spheroidal halloysite in a Guatemalan soil. Soil Science Society of America Journal, 37, 799–803.CrossRefGoogle Scholar
Bailey, S.W., Brindley, G.W., Kodama, H. and Martin, R.T. (1982) Report of the Clay Minerals Society Nomenclature Committee 1980–1981: Nomenclature for regular interstratification. Clays and Clay Minerals, 30, 76–78.CrossRefGoogle Scholar
Bates, T.F., Hildebrand, F.A. and Swineford, A. (1950) Morphology and structure of endellite and halloysite. American Mineralogist, 35, 463–484.Google Scholar
Birrell, K.S., Fieldes, M. and Williamson, K.I. (1955) Unusual forms of halloysite. American Mineralogist, 40, 122–124.Google Scholar
Burtner, R.I. and Warner, M.A. (1986) Relationship between illite/smectite diagenesis and hydrocarbon generation in Lower Cretaceous Mowry and Skull Creek shales of the northern Rocky Mountain area. Clays and Clay Minerals, 34, 390–402.CrossRefGoogle Scholar
Chang, H.K., Mackenzie, F.T. and Schoonmaker, J. (1986) Comparisons between the diagenesis of dioctahedral and trioctahedral smectite, Brazilian offshore basins. Clays and Clay Minerals, 34, 407–423.CrossRefGoogle Scholar
Churchman, G.J. and Gilkes, R.J. (1989) Recognition of intermediates in the possible transformation of halloysite to kaolinite in weathering profile. Clay Minerals, 24, 579–590.CrossRefGoogle Scholar
Delvaux, B., Tessier, D., Herbillon, A.J., Burtin, G., Jaunet, A.M. and Vielvoye, L. (1992) Morphology, texture and microstructure of halloysite soil clays as related to weathering and exchangeable cation. Clays and Clay Minerals, 40, 446–456.CrossRefGoogle Scholar
Giese, R.F. Jr. (1988) Kaolin minerals: structures and stabilities. Pp. 29–66 in: Hydrous Phyllosilicates (exclusive of micas)(Bailey, S.W., editor). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C. CrossRefGoogle Scholar
Gilkes, R.J., Suddhiprakarn, A. and Armitage, T.M. (1980) Scanning electron microscope morphology of deeply weathered granite. Clays and Clay Minerals, 28, 29–34.CrossRefGoogle Scholar
Hower, J., Eslinger, E.V., Hower, M.E. and Perry, E.A. (1976) Mechanism of burial metamorphism of argillaceous sediment. 1. Mineralogical and chemi¬cal evidence. Geological Society of America Bulletin, 87, 725–737.2.0.CO;2>CrossRefGoogle Scholar
Kautz, C.Q. and Ryan, P.C. (2003) The 10 angstrom to 7 angstrom halloysite transition in a tropical soil sequence, Costa Rica. Clays and Clay Minerals, 51, 252–263.CrossRefGoogle Scholar
Kirkman, J.H. (1977) Possible structure of halloysite disks and cylinders observed in some New Zealand rhyolitic tephras. Clay Minerals, 12, 199–216.CrossRefGoogle Scholar
Kirkman, J.H. (1981) Morphology and structure of halloysite in New Zealand tephras. Clays and Clay Minerals, 29, 1–9.CrossRefGoogle Scholar
Papoulis, D., Tsolis-Katagas, P. and Katagas, C. (2004) Progressive stages in the formation of kaolin minerals of different morphologies in the weathering of plagioclase. Clays and Clay Minerals, 52, 275–286.CrossRefGoogle Scholar
Saigusa, M., Shoji, S. and Kato, T. (1978) Origin and nature of halloysite in Andosols from Towada Tephra, Japan. Geoderma, 20, 115–129.CrossRefGoogle Scholar
Singh, B. and Gilkes, R.J. (1992) An electron optical investigation of the alteration of kaolinite to halloysite. Clays and Clay Minerals, 40, 212–229.CrossRefGoogle Scholar
Wang, P., Pan, Z.L. and Weng, L.B. (1984) Mineralogy. Geological Publishing House, Beijing, pp. 411–414 (in Chinese).Google Scholar
Zhang, R.Y., Wu, F.Q. and Zhang, D.H. (1987) Rectorite in Permian pelitic rocks at Zhongxiang, Hubei province. Acta Mineralogica Sinica, 7, 113–120. (in Chinese with English abstract).Google Scholar