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The new mineral zolotarevite, Na5Zr[Si6O15(ОН)3]⋅2–3H2O, the first highly hydrated lovozerite-group member from the Lovozero alkaline massif, Kola Peninsula, Russia

Published online by Cambridge University Press:  07 March 2022

Julia A. Mikhailova Open the ORCID record for Julia A. Mikhailova [Opens in a new window] ,
Ekaterina A. Selivanova Open the ORCID record for Ekaterina A. Selivanova [Opens in a new window] ,
Sergey V. Krivovichev Open the ORCID record for Sergey V. Krivovichev [Opens in a new window] ,
Yakov A. Pakhomovsky ,
Nikita V. Chukanov  and
Victor N. Yakovenchuk
Julia A. Mikhailova*
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia
Ekaterina A. Selivanova
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia
Sergey V. Krivovichev
Affiliation:
Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia St. Petersburg State University, Department of Crystallography, 7/9 Universitetskaya Naberezhnaya, St. Petersburg 199034, Russia
Yakov A. Pakhomovsky
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia
Nikita V. Chukanov
Affiliation:
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432 Russia Faculty of Geology, Moscow State University, Vorobievy Gory, Moscow, 119991 Russia
Victor N. Yakovenchuk
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street, Apatity 184209, Murmansk Region, Russia
*
*Author for correspondence: Julia A. Mikhailova, Email: [email protected]
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Abstract

Zolotarevite (IMA2020-076), ideally Na5Zr[Si6O15(ОН)3]⋅2–3H2O, is а new mineral of the lovozerite group. The mineral was found in a leucocratic nepheline syenite from Kedykverpakhk Mt., Lovozero alkaline massif, Kola Peninsula, Russia. It occurs as anhedral grains up to 1 mm across and is associated with microcline–perthite, nepheline, sodalite, aegirine, lamprophyllite, lueshite, umbozerite, lomonosovite, nastrophite, a mineral of the kazakovite–tisinalite series, sphalerite and löllingite. Zolotarevite is cherry red, with a vitreous lustre and white streak. The mineral is brittle, with a Mohs hardness of 5. Cleavage was not observed; the fracture is uneven. The measured density is 2.75(5) g⋅cm–3, the density calculated using the empirical formula and single-crystal unit-cell parameters is 2.85 g⋅cm–3. Zolotarevite is anomalously biaxial (–), α = 1.580(2), β = 1.600(2) and γ = 1.602(2) (for λ = 589 nm); 2Vmeas < 10°. Chemical data (electron microprobe, wt.%) are: Na2O 20.41, СаО 0.42, MnO 3.49, Fе2O3 0.55, SiO2 52.46, ТiO2 1.34, ZrO2 11.33, H2O (calculated from the structural formula) 10.20, total 100.20. The empirical formula based оn 6 Si atoms per formula unit is Na4.53Zr0.63Mn0.34Ti0.11Ca0.05Fe3+0.05Si6O14.43(ОН)3.56(H2О)2.11. Zolotarevite is trigonal, space group R${\bar 3}$m, with a = 10.294(6) Å, c = 13.115(8) Å, V = 1203.7(16) Å3 and Z = 3. The crystal structure was solved from single-crystal data and refined to R1 = 0.049. The strongest lines of the powder X-ray diffraction pattern [d in Å (I) (hkl)] are: 7.37 (69) (101); 5.26 (56) (012); 3.686 (64) (202); 3.330 (79) (113); 3.265 (99) (211), 2.640 (100) (024) and 2.576 (60) (220). Zolotarevite is unique in that it is a highly hydrated lovozerite-group mineral with the B site occupied by variable amounts of H2O.

Keywords

lovozerite groupcyclosilicatenew mineralcrystal structurezolotarevitefoyaiteLovozero alkaline massifKola Peninsula
Type
Article
Information
Mineralogical Magazine , Volume 86 , Issue 2 , April 2022 , pp. 263 - 271
Copyright
Copyright © The Author(s), 2022. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Ian T. Graham

References

Barrer, R.M. (1982) Hydrothermal Chemistry of Zeolites. Academic Press, London, 360 pp.Google Scholar
Belov, N.V. (1976) Essays on Structural Mineralogy. Nedra Publishing, Moscow, 344 pp. [in Russian].Google Scholar
Bruker (2014) APEX2, SAINT, XPREP, SADABS, XCIF, and SHELXTL. Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
Bussen, I.V. and Sakharov, A.S. (1972) Petrology of the Lovozero Alkaline Massif. Nedra, Leningrad, 296 pp. [in Russian].Google Scholar
Chernitsova, N.M., Pudovkina, Z.V., Voronkov, A.A., Kapustin, Yu.L. and Pyatenko, Yu.A. (1975) On the new crystallochemical lovozerite family. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 104, 18–27 [in Russian].Google Scholar
Chukanov, N.V. (2014) Infrared Spectra of Mineral Species: Extended Library. Springer-Verlag GmbH, Dordrecht–Heidelberg–New York–London, 2014. 1716 pp.10.1007/978-94-007-7128-4CrossRefGoogle Scholar
Chukanov, N.V. and Chervonnyi, A.D. (2016) Infrared Spectroscopy of Minerals and Related Compounds. Springer, Cham–Heidelberg–Dordrecht–New York–London, 1109 pp.10.1007/978-3-319-25349-7CrossRefGoogle Scholar
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K. and Puschmann, H. (2009) OLEX2: a complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42, 339–341.10.1107/S0021889808042726CrossRefGoogle Scholar
Fischer, R.X. and Tillmanns, E. (1987) Revised data for combeite, Na2Ca2Si3O9. Acta Crystallographica, C43, 1852–1854.Google Scholar
Gerasimovsky, V.I. (1939) Lovozerite a new mineral. Doklady Akademii Nauk SSSR, 25, 753–756 [in Russian].Google Scholar
Gerasimovsky, V.I., Volkov, V.P., Kogarko, L.N., Polyakov, A.I., Saprykina, T.V. and Balashov, Y.A. (1966) Geochemistry of the Lovozero Alkaline Massif. Nauka, Moscow, 396 pp. [in Russian].Google Scholar
Grey, I.E., Macrae, C.M., Mumme, W.G. and Pring, A. (2010) Townendite, Na8ZrSi6O18, a new uranium-bearing lovozerite group mineral from the Ilimaussaq alkaline complex, Southern Greenland, American Mineralogist, 95, 646–650.CrossRefGoogle Scholar
Ilyukhin, V.V. and Belov, N.V. (1960) Crystal structure of lovozerite. Doklady Akademii Nauk SSSR, 131, 176–179 [in Russian].Google Scholar
Kaposta, E.C. (2005) Gas Phase Infrared Photodissociation Spectroscopy of Mass Selected Cluster Ions: Strong Hydrogen Bonds and Vanadium Oxides. Thesis, Free University of Berlin, Berlin, 174 pp.Google Scholar
Kapustin, Yu.L., Bykova, A.V. and Pudovkina, Z.V. (1973) On the mineralogy of the lovozerite group. Izvestiya AN SSSR, Seriya Geologicheskaya, 8, 106–112 [in Russian].Google Scholar
Kapustin, Yu.L., Pudovkina, Z.V. and Bykova, A.V. (1974a) Zirsinalite – a new mineral. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 103, 551–558 [in Russian].Google Scholar
Kapustin, Yu.L., Pudovkina, Z.V., Bykova, A.V. and Lyubomilova, G.V. (1974b) Koashvite – a new mineral. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 103, 559–566 [in Russian].Google Scholar
Kapustin, Yu.L., Pudovkina, Z.V. and Bykova, A.V. (1980) Tisinalite, Na3H3(Mn,Ca,Fe)TiSi6(O,OH)18⋅2H2O – a new mineral. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 109, 223–229 [in Russian].Google Scholar
Khomyakov, A.P. (1977) New in the mineralogy of the lovozerite group. Doklady Akademii Nauk SSSR, 237, 199–202 [in Russian].Google Scholar
Khomyakov, A.P. (1995) Mineralogy of Hyperagpaitic Alkaline Rocks. Clarendon Press, Oxford, UK, 223 pp.Google Scholar
Khomyakov, A.P., Semenov, E.I., Es'kova, E.M. and Voronkov, A.A. (1974) Kazakovite – a new mineral of the lovozerite group. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 103, 342–345 [in Russian].Google Scholar
Khomyakov, A.P., Kaptsov, V.V., Shchepochkina, N.I., Rudnitskaya, E.S. and Krutetskaya, L.M. (1978) Phenomenon of ultra-quick hydrolysis of hyperalkaline titano- and zirconosilicates. Experimental testing. Doklady Akademii Nauk SSSR, 243 1028–1031 [in Russian].Google Scholar
Kogarko, L.N. (1977) Problems of the Genesis of the Agpaitic Magmas. Nauka, Moscow, 296 pp. [in Russian]Google Scholar
Kramm, U. and Kogarko, L.N. (1994) Nd and Sr isotope signatures of the Khibina and Lovozero agpaitic centres, Kola Alkaline province, Russia. Lithos, 32, 225–242.10.1016/0024-4937(94)90041-8CrossRefGoogle Scholar
Krivovichev, S.V. (2015) Local approach and the theory of lovozerite structures. Proceedings of the Steklov Institute of Mathematics, 288, 105–116.CrossRefGoogle Scholar
Kulig, W. and Agmon, N. (2014) Both Zundel and Eigen isomers contribute to the IR spectrum of the gas-phase H9O4+ cluster. Journal of Physical Chemistry, B118, 278–286.10.1021/jp410446dCrossRefGoogle Scholar
Malinovsky, Yu.A., Burzlaff, H. and Rothammel, W. (1993) Structures of the lovozerite type – a quantitative investigation. Acta Crystallographica, B49, 158–164.CrossRefGoogle Scholar
Mikhailova, J.A., Ivanyuk, G.Yu., Kalashnikov, A.O., Pakhomovsky, Y.A., Bazai, A.V. and Yakovenchuk, V.N. (2019) Petrogenesis of the Eudialyte Complex of the Lovozero Alkaline Massif (Kola Peninsula, Russia). Minerals, 9, 581.10.3390/min9100581CrossRefGoogle Scholar
Mikhailova, J.A., Selivanova, E.A., Krivovichev, S.V., Pakhomovsky, Y.A. and Chukanov, N.V. (2021) Zolotarevite, IMA 2020-076. CNMNC Newsletter 59. Mineralogical Magazine, 85, 278–281.Google Scholar
Park, M., Shin, I., Singh, N.J. and Kim, K.S. (2007) Eigen and Zundel forms of small protonated water clusters: structures and infrared spectra. Journal of Physical Chemistry, A111, 10692–10702.10.1021/jp073912xCrossRefGoogle Scholar
Pekov, I.V. (2005) Genetic Mineralogy and Crystal Chemistry of Rare Elements in High-Alkaline Postmagmatic Systems, D.Sc. thesis, Moscow State University, Moscow [in Russian].Google Scholar
Pekov, I.V., Ekimenkova, I.A., Chukanov, N.V., Zadov, A.E., Yamnova, N.A. and Egorov-Tismenko, Yu.K. (2000) Litvinskite, Na2(□,Na,Mn)Zr[Si6O12(OH,O)6] – a new mineral of the lovozerite group. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 129, 45–53 [in Russian].Google Scholar
Pekov, I.V., Chukanov, N.V., Yamnova, N.A., Egorov-Tismenko, Yu.K., Zadov, A.E. (2003) Kapustinite, Na5.5Mn0.25ZrSi6O16(OH)2, a new mineral from Lovozero massif (Kola Peninsula) and new data on the genetic crystal chemistry of the lovozerite group. Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 132, 1–14 [in Russian].Google Scholar
Pekov, I.V., Krivovichev, S.V., Zolotarev, A.A., Yakovenchuk, V.N., Armbruster, T. and Pakhomovsky, Y.A. (2009) Crystal chemistry and nomenclature of the lovozerite group. European Journal of Mineralogy, 21, 1061–1071.CrossRefGoogle Scholar
Semenov, E.I. (1972) Mineralogy of the Lovozero Alkaline Massif. Nauka Publishing, Moscow, 308 pp. [in Russian].Google Scholar
Sheldrick, G.M. (2007) SADABS. University of Gottingen, Gottingen, Germany.Google Scholar
Sheldrick, G.M. (2015) Crystal structure refinement with SHELXL. Acta Crystallographica, C71, 3–8.Google Scholar
Shevchenko, V.Ya., Krivovichev, S.V. and Mackay, A.L. (2010) Cellular automata and local order in the structural chemistry of the lovozerite group minerals. Glass Physics and Chemistry, 36, 1–9.CrossRefGoogle Scholar
Sitarza, M., Handke, M., Mozgawa, W., Galuskin, E. and Galuskina, I. (2000) The non-ring cations influence on silicooxygen ring vibrations. Journal of Molecular Structure, 555, 357–362.CrossRefGoogle Scholar
Tamazyan, R.A., Malinovskii, Yu.A. (1990) Crystal chemistry of silicates of the lovozerite family. Kristallografiya, 35, 398–405 [in Russian].Google Scholar
Warr, L.N. (2021) IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85, 291–320.10.1180/mgm.2021.43CrossRefGoogle Scholar
Wilkins, R.W., Mateen, A. and West, G.W. (1974) The spectroscopic study of oxonium ions in minerals. American Mineralogist, 59, 811–819.Google Scholar
Yamnova, N.A., Egorov-Tismenko, Yu.K., Pekov, I.V. and Ekimenkova, I.A. (2001) Crystal structure of litvinskite: A new natural representative of the lovozerite group. Crystallography Reports, 46, 190–193.10.1134/1.1358391CrossRefGoogle Scholar
Yukhnevich, G.V. (1973) Infrared Spectroscopy of Water. Nauka, Moscow, 208 pp. [in Russian].Google Scholar
Zolotarev, A.A., Krivovichev, S.V., Yakovenchuk, V.N., Armbruster, T. and Pakhomovsky, Y.A. (2008) Trigonal members of the lovozerite group: a re-investigation. Pp. 79–86 in: Minerals as Advanced Materials I. Springer, Berlin, Heidelberg.CrossRefGoogle Scholar
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