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Platinum nanoparticle-functionalized tin dioxide nanowires via radiolysis and their sensing capability

Published online by Cambridge University Press:  24 May 2012

Sun-Woo Choi
Affiliation:
School of Materials Science and Engineering, Inha University, Incheon 402-751, Republic of Korea
Sang Sub Kim*
Affiliation:
School of Materials Science and Engineering, Inha University, Incheon 402-751, Republic of Korea
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Platinum (Pt) nanoparticles were synthesized on tin dioxide (SnO2) nanowires by applying γ-ray radiolysis. The growth behavior of Pt nanoparticles was systematically investigated as a function of precursor concentration, illumination intensity and exposure time of the γ-rays. We found that these processing parameters greatly influenced the growth behavior of Pt nanoparticles in terms of size and formation density. Vapor-phase-grown SnO2 nanowires were uniformly covered with Pt nanoparticles by the radiolysis process. The Pt nanoparticle-functionalized SnO2 nanowires were tested as sensors for detecting reductive gases including carbon monoxide, toluene, and benzene. The results indicate that the γ-ray radiolysis is an efficient way of functionalizing the surface of oxide nanowires with catalytic Pt nanoparticles.

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Articles
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1.Kundu, S., Panigrahi, S., Praharaj, S., Basu, S., Ghosh, S.K., Pal, A., and Pal, T.: Anisotropic growth of gold clusters to gold nanocubes under UV irradiation. Nanotechnology 18, 075712 (2007).Google Scholar
2.Scaffardi, L.B., Pellegri, N., Sanceis, O., and Tocho, J.O.: Sizing gold nanoparticles by optical extinction spectroscopy. Nanotechnology 16, 158 (2005).CrossRefGoogle Scholar
3.Lung, J-K., Huang, J-C., Tien, D-C., Liao, C-Y., Tseng, K-H., Tsung, T-T., Kao, W-S., Tasi, T-H., Jwo, C-S., Lin, H-M., and Stobinski, L.: Preparation of gold nanoparticles by arc discharge in water. J. Alloys Compd. 434435, 655 (2007).Google Scholar
4.Henglein, A. and Meisel, D.: Radiolytic control of the size of colloidal gold nanoparticles. Langmuir 14, 7392 (1998).CrossRefGoogle Scholar
5.Mizukoshi, Y., Seino, S., Okitsu, K., Kinoshita, T., Otome, Y., Nakagawa, T., and Yamamoto, T.A.: Sonochemical preparation of composite nanoparticles of Au/γ-Fe2O3 and magnetic separation of glutathione. Ultrason. Sonochem. 12, 191 (2001).Google Scholar
6.Henglein, A.: Radiolytic preparation of ultrafine colloidal gold particles in aqueous solution: Optical spectrum, controlled growth, and some chemical reactions. Langmuir 15, 6738 (1999).Google Scholar
7.Henglein, A.: Reduction of Ag(CN)2 on silver and platinum colloidal nanoparticles. Langmuir 17, 2329 (2001).Google Scholar
8.Seino, S., Kusunose, T., and Sekino, T.: Synthesis of gold/magnetic iron oxide composite nanoparticles for biomedical applications with good dispersibility. J. Appl. Phys. 99, 08H101 (2006).CrossRefGoogle Scholar
9.Chwieroth, B., Patton, B.R., and Wang, Y.: Conduction and gas-surface reaction modeling in metal oxide gas sensors. J. Electroceram. 6, 27 (2001).Google Scholar
10.Kim, S.S., Park, J.Y., Choi, S-W., Kim, H.S., Na, H.G., Yang, J.C., and Kim, H.W.: Significant enhancement of the sensing characteristics of In2O3 nanowires by functionalization with Pt nanoparticles. Nanotechnology 21, 415502 (2010).Google Scholar
11.Yamazoe, N.: Toward innovations of gas sensor technology. Sens. Actuators B 108, 2 (2005).CrossRefGoogle Scholar
12.Neri, G., Bonavita, A., Micali, G., Rizzo, G., Pinna, N., and Niederberger, M.: In2O3 and Pt-In2O3 nanopowders for low temperature oxygen sensors. Sens. Actuators B 127, 455 (2007).Google Scholar
13.Choi, J-K., Hwang, I-S., Kim, S-J., Park, J-S., Park, S-S., Jeong, U., Kang, Y.C., and Lee, J-H.: Design of selective gas sensors using electrospun Pd-doped SnO2 hollow nanofibers. Sens. Actuators, B 150, 191 (2010).CrossRefGoogle Scholar
14.Gamez, A., Richard, D., Gallezot, P., Gloguen, F., Faure, R., and Durand, R.: Oxygen reduction on well-defined platinum nanoparticles inside recast ionomer. Electrochim. Acta 41, 307 (1996).CrossRefGoogle Scholar
15.Antoine, O., Bultel, Y., and Durand, R.: Oxygen reduction reaction kinetics and mechanism on platinum nanoparticles inside nafion. J. Electroanal. Chem. 499, 85 (2001).Google Scholar
16.Hrapovic, S., Liu, Y.L., Male, K.B., and Luong, J.H.T.: Electrochemical biosensing platforms using platinum nanoparticles and carbon nanotubes. Anal. Chem. 76, 1083 (2004).CrossRefGoogle ScholarPubMed
17.Ikariyama, Y., Yamaguchi, S., Yukiashi, T., and Ushioda, H.: One-step fabrication of microbiosensor prepared by the codeposition of enzyme and platinum particles. Anal. Lett. 20, 1791 (1987).Google Scholar
18.Zhou, W., Xu, L., Wu, M., Xu, L., and Wang, E.: Determination of hydrazines by capillary zone electrophoresis with amperometric detection at a platinum particles-modified carbon fibre microelectrode. Anal. Chim. Acta 299, 189 (1994).Google Scholar
19.Attand, G.S., Barlett, P.N., Coleman, N.R.B., Elliot, J.M., Owen, J.R., and Wang, J.H.: Mesoporous platinum films from lyotropic liquid crystalline phases. Science 278, 838 (1997).Google Scholar
20.Birkin, P.R., Elliot, J.M., and Watson, Y.E.: Electrochemical reduction of oxygen on mesoporous platinum microelectrodes. Chem. Commun. 17, 1693 (2000).Google Scholar
21.Yogi, C., Kojima, K., Takai, T., and Wada, N.: Photocatalytic degradation of methylene blue by Au-deposited TiO2 film under UV irradiation. J. Mater. Sci. 44, 821 (2009).CrossRefGoogle Scholar
22.Choi, S-W., Jung, S-H., and Kim, S.S.: Functionalization of selectively grown networked SnO2 nanowires with Pd nanodots by γ-ray radiolysis. Nanotechnology 22, 225501 (2011).Google Scholar
23.Park, J.Y., Choi, S-W., and Kim, S.S.: Junction-tuned SnO2 nanowires and their sensing properties. J. Phys. Chem. C 115, 12774 (2011).Google Scholar
24.Ershov, G. and Henglein, A.: Optical spectrum and some chemical properties of colloidal thallium in aqueous solution. J. Phys. Chem. 97, 3434 (1993).Google Scholar
25.Belloni, J.: Nucleation, growth and properties of nanoclusters studied by radiation chemistry application to catalysis. Catal. Today 113, 141 (2010).Google Scholar
26.Hornebecq, V., Antonietti, M., Cardinal, T., and Treguer-Delapierre, M.: Stable silver nanoparticles immobilized in mesoporous silica. Chem. Mater. 15, 1993 (2003).Google Scholar
27.Mayer, A. and Antonietti, M.: Investigation of polymer-protected noble metal nanoparticles by transmission electron microscopy: Control of particles morphology and shape. Colloid Polym. Sci. 276, 769 (1998).Google Scholar
28.Klug, H.P. and Alexander, L.E.: X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd ed. (Wiley, New York, 1974).Google Scholar
29.Franke, M.E., Koplin, T.J., and Simon, U.: Metal and metal oxide nanoparticles in chemiresistors: Dose the nanoscale matter? Small 2, 36 (2006).CrossRefGoogle Scholar
30.Kolmakov, A., Klenov, D.O., Lilach, Y., Stemmer, S., and Moskovits, M.: Enhanced gas sensing by individual SnO2 nanowires and nanobelts functionalized with Pd catalyst particles. Nano Lett. 5, 667 (2005).Google Scholar