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Interactive formation of Cu-rich precipitate, reverted austenite, and alloyed carbide during partial austenite reversion treatment for high-strength low-alloy steel

Published online by Cambridge University Press:  02 May 2017

Qingdong Liu
Affiliation:
Institute of Materials Modification and Modelling, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China; and Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai Jiaotong University, Shanghai 200240, People’s Republic of China
Chuanwei Li
Affiliation:
Institute of Materials Modification and Modelling, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China
Jianfeng Gu*
Affiliation:
Institute of Materials Modification and Modelling, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China; and Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai Jiaotong University, Shanghai 200240, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

We address the competitive precipitation and coprecipitation of three types of secondary phases, i.e., Cu-rich precipitates (CRPs), reverted austenite (RA), and alloyed carbide, in a high-strength low-alloy steel with austenite reversion treatment at 675 °C by using electron back-scatter diffraction, transmission electron microscopy, and atom probe tomography. There is a strong competitive diffusion of Ni and Cu participating in austenite reversion and Cu precipitation with the fact that no CRPs are detected in and around the RA. Meanwhile, there is also a strong competitive diffusion of austenite stabilizing element Ni and carbide-forming elements Cr and Mo into the pre-existing C-rich zone, leading to the formation of nonequilibrium alloyed carbide deviating from the stoichiometric composition. On the other hand, the alloyed carbide and CRPs provide constituent elements for each other and make the coprecipitation thermodynamically favorable. The knowledge on the interactive formation of these three features provides versatile access to tailor the distributional morphology of CRPs, RA, and alloyed carbide via a multistage heat treatment and thus realize their beneficial effect on strength and toughness.

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Articles
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jürgen Eckert

References

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