Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-24T06:50:07.190Z Has data issue: false hasContentIssue false
  • English
  • Français

Inorganic coordination polymer quantum sheets@graphene oxide composite photocatalysts: Performance and mechanism

Published online by Cambridge University Press:  15 July 2019

Shixiong Li Open the ORCID record for Shixiong Li [Opens in a new window] ,
Qiaoling Mo ,
Xiaoxia Lai ,
Yufeng Chen ,
Chuansong Lin ,
Yan Lu  and
Beiling Liao
Shixiong Li*
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Qiaoling Mo
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Xiaoxia Lai
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Yufeng Chen
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Chuansong Lin*
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Yan Lu
Affiliation:
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou 543002, China
Beiling Liao*
Affiliation:
School of Chemistry and Biological Engineering, Hechi University, Hechi 546300, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
Get access

Abstract

Heterogeneous photocatalytic oxidation technology is currently a technology with the potential to solve environmental pollution and energy shortages. The key to this technology is to find and design efficient photocatalysts. Here, a series of inorganic coordination polymer quantum sheets (ICPQS)@graphene oxide (GO) composite photocatalysts are synthesized by adding GO to the synthesis process of ICPQS: {[CuII(H2O)4][CuI4(CN)6]}n. These composite photocatalysts were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, cyclic voltammetry, scanning electron microscopy, transmission electron microscopy, Zeta potential, and N2 adsorption/desorption isotherms. The photocatalytic degradation of methylene blue showed that the activity of ICPQS@GO composite photocatalysts is better than that of ICPQS. Among ICPQS@GO composite photocatalysts, the 10.6% ICPQS@GO composite photocatalyst has the best activity, which can reach 3.3 mg/(L min) at pH 3. This method of loading low–specific surface area photocatalysts onto GO to improve photocatalytic performance indicates the direction for the synthesis of highly efficient photocatalysts.

Keywords

graphene oxidecompositephotocatalystsquantum sheets
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 18 , 30 September 2019 , pp. 3220 - 3230
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Colmenares, J.C. and Luque, R.: Heterogeneous photocatalytic nanomaterials: Prospects and challenges in selective transformations of biomass-derived compounds. Chem. Soc. Rev. 43, 765 (2014).CrossRefGoogle ScholarPubMed
Yin, X.J. and Zhu, L.G.: High-efficiency photocatalytic performance and mechanism of silver-based metal–organic framework. J. Mater. Res. 34, 991 (2019).CrossRefGoogle Scholar
Li, S., Wei, C., Hu, Y., Wu, H., and Li, F.: In situ synthesis and photocatalytic mechanism of a cyano bridged Cu(I) polymer. Inorg. Chem. Front. 5, 1282 (2018).CrossRefGoogle Scholar
Pasti, L., Sarti, E., Martucci, A., Marchetti, N., Stevanin, C., and Molinari, A.: An advanced oxidation process by photoexcited heterogeneous sodium decatungstate for the degradation of drugs present in aqueous environment. Appl. Catal., B 239, 345 (2018).CrossRefGoogle Scholar
Mena, E., Rey, A., and Beltrán, F.J.: TiO2 photocatalytic oxidation of a mixture of emerging contaminants: A kinetic study independent of radiation absorption based on the direct-indirect model. Chem. Eng. J. 339, 369 (2018).CrossRefGoogle Scholar
Saavedra, J., Pursell, C.J., and Chandler, B.D.: CO oxidation kinetics over Au/TiO2 and Au/Al2O3 catalysts: Evidence for a common water-assisted mechanism. J. Am. Chem. Soc. 140, 3712 (2018).CrossRefGoogle ScholarPubMed
Schlexer, P., Widmann, D., Behm, R.J., and Pacchioni, G.: CO oxidation on a Au/TiO2 nanoparticle catalyst via the Au-assisted Mars–van Krevelen mechanism. ACS Catal. 8, 6513 (2018).CrossRefGoogle Scholar
Nguyen, C.C., Nguyen, D.T., and Do, T.O.: A novel route to synthesize C/Pt/TiO2 phase tunable anatase–Rutile TiO2 for efficient sunlight-driven photocatalytic applications. Appl. Catal., B 226, 46 (2018).CrossRefGoogle Scholar
Chiarello, G.L., Ferri, D., and Selli, E.: In situ attenuated total reflection infrared spectroscopy study of the photocatalytic steam reforming of methanol on Pt/TiO2. Appl. Surf. Sci. 450, 146 (2018).CrossRefGoogle Scholar
Camacho, S.Y.T., Rey, A., Hernández-Alonso, M.D., Llorca, J., Medina, F., and Contreras, S.: Pd/TiO2–WO3 photocatalysts for hydrogen generation from water-methanol mixtures. Appl. Surf. Sci. 455, 570–580 (2018).CrossRefGoogle Scholar
Shen, R., Xie, J., Ding, Y., Liu, S.Y., Adamski, A., Chen, X., and Li, X.: Carbon nanotube-supported Cu3P as high-efficiency and low-cost cocatalysts for exceptional semiconductor-free photocatalytic H2 evolution. ACS Sustainable Chem. Eng. 7, 3243 (2019).CrossRefGoogle Scholar
Spanopoulos, I., Tsangarakis, C., Klontzas, E., Tylianakis, E., Froudakis, G., Adil, K., and Trikalitis, P.N.: Reticular synthesis of HKUST-like tbo-MOFs with enhanced CH4 storage. J. Am. Chem. Soc. 138, 1568 (2016).CrossRefGoogle ScholarPubMed
Yang, X. and Xu, Q.: Bimetallic metal–organic frameworks for gas storage and separation. Cryst. Growth Des. 17, 1450 (2017).CrossRefGoogle Scholar
Hasan, Z. and Jhung, S.H.: Removal of hazardous organics from water using metal–organic frameworks (MOFs): Plausible mechanisms for selective adsorptions. J. Hazard. Mater. 283, 329 (2015).CrossRefGoogle ScholarPubMed
Liao, P.Q., Huang, N.Y., Zhang, W.X., Zhang, J.P., and Chen, X.M.: Controlling guest conformation for efficient purification of butadiene. Science 356, 1193 (2017).CrossRefGoogle ScholarPubMed
Lin, R.B., Xiang, S., Xing, H., Zhou, W., and Chen, B.: Exploration of porous metal–organic frameworks for gas separation and purification. Coord. Chem. Rev. 378, 87 (2019).CrossRefGoogle Scholar
Lu, Y. and Yan, B.: A ratiometric fluorescent pH sensor based on nanoscale metal–organic frameworks (MOFs) modified by europium(III) complexes. Chem. Commun. 50, 13323 (2014).CrossRefGoogle ScholarPubMed
Shustova, N.B., McCarthy, B.D., and Dinca, M.: Turn-on fluorescence in tetraphenylethylene-based metal–organic frameworks: An alternative to aggregation-induced emission. J. Am. Chem. Soc. 133, 20126 (2011).CrossRefGoogle ScholarPubMed
Li, S.X., Liao, B.L., Liao, P., and Jiang, Y.M.: Syntheses, structures, fluorescence and anticancer activity of Co(II) and Ag(I) complexes with 4-(3H)-Quinazolinone. Chinese J. Inorg. Chem. 31, 291 (2015).Google Scholar
Liao, B.L., Li, S.X., and Yin, Y.J.: One trinuclear copper(II) polymer based on pyridine-2,4,6-tricarboxylic acid: Synthesis, structure, and magnetic analysis. Russ. J. Coord. Chem. 44, 39 (2018).CrossRefGoogle Scholar
Liao, B.L., Yang, G.G., Li, S.X., Jiang, Y.M., and Yin, Y.J.: Syntheses, structures and magnetic analysis of Co(II) coordination polymer based on N-(pyridine-3-sulfonyl amino)-acetate. Chinese J. Inorg. Chem. 33, 1843 (2017).Google Scholar
Yin, Y.J., Liao, B.L., Wu, H.M., Pang, Y.L., and Li, S.X.: Syntheses, structures and magnetic analysis of Co(II), Ni(II) coordination polymers based on pyridine-2,4,6-tricarboxylic acid. Chinese J. Inorg. Chem. 33, 1043 (2017).Google Scholar
Jia, J.J., Li, S.X., and Jiang, Y.M.: Synthesis, crystal structure, and magnetic analysis of Ni(II) polymer based on N-[(3-pyridine)-sulfonyl] aspartate. Inorg. Nano-Met. Chem. 47, 1318 (2017).CrossRefGoogle Scholar
Hod, I., Sampson, M.D., Deria, P., Kubiak, C.P., Farha, O.K., and Hupp, J.T.: Fe-porphyrin-based metal–organic framework films as high-surface concentration, heterogeneous catalysts for electrochemical reduction of CO2. ACS Catal. 5, 6302 (2015).CrossRefGoogle Scholar
Chen, W., Han, B., Tian, C., Liu, X., Liang, S., Deng, H., and Lin, Z.: MOFs-derived ultrathin holey Co3O4 nanosheets for enhanced visible light CO2 reduction. Appl. Catal., B 244, 996 (2019).CrossRefGoogle Scholar
Li, X., Yu, J., Jaroniec, M., and Chen, X.: Cocatalysts for selective photoreduction of CO2 into solar fuels. Chem. Rev. 119, 3962 (2019).CrossRefGoogle ScholarPubMed
Pi, Y., Li, X., Xia, Q., Wu, J., Li, Y., Xiao, J., and Li, Z.: Adsorptive and photocatalytic removal of persistent organic pollutants (POPs) in water by metal–organic frameworks (MOFs). Chem. Eng. J. 337, 351 (2018).CrossRefGoogle Scholar
Huang, J., Zhang, X., Song, H., Chen, C., Han, F., and Wen, C.: Protonated graphitic carbon nitride coated metal–organic frameworks with enhanced visible-light photocatalytic activity for contaminants degradation. Appl. Surf. Sci. 441, 85 (2018).CrossRefGoogle Scholar
Azhar, M.R., Vijay, P., Tadé, M.O., Sun, H., and Wang, S.: Submicron sized water-stable metal organic framework (bio-MOF-11) for catalytic degradation of pharmaceuticals and personal care products. Chemosphere 196, 105 (2018).CrossRefGoogle ScholarPubMed
Li, X., Xie, J., Jiang, C., Yu, J., and Zhang, P.: Review on design and evaluation of environmental photocatalysts. Front. Environ. Sci. Eng. 12, 14 (2018).CrossRefGoogle Scholar
Li, X., Shen, R., Ma, S., Chen, X., and Xie, J.: Graphene-based heterojunction photocatalysts. Appl. Surf. Sci. 430, 53 (2018).CrossRefGoogle Scholar
Zhang, R., Wan, W., Li, D., Dong, F., and Zhou, Y.: Three-dimensional MoS2/reduced graphene oxide aerogel as a macroscopic visible-light photocatalyst. Chin. J. Catal. 38, 313 (2017).CrossRefGoogle Scholar
Thirugnanam, N., Song, H., and Wu, Y.: Photocatalytic degradation of Brilliant Green dye using CdSe quantum dots hybridized with graphene oxide under sunlight irradiation. Chin. J. Catal. 38, 2150 (2017).CrossRefGoogle Scholar
Yan, J., Xu, M., Chai, B., Wang, H., Wang, C., and Ren, Z.: In situ construction of BiOBr/Ag3PO4 composites with enhanced visible light photocatalytic performances. J. Mater. Res. 32, 1603 (2017).CrossRefGoogle Scholar
Challagulla, S. and Roy, S.: The role of fuel to oxidizer ratio in solution combustion synthesis of TiO2 and its influence on photocatalysis. J. Mater. Res. 32, 2764 (2017).CrossRefGoogle Scholar
Feng, Z., Zeng, L., Chen, Y., Ma, Y., Zhao, C., Jin, R., Lu, Y., Wu, Y., and He, Y.: In situ preparation of Z-scheme MoO3/gC3N4 composite with high performance in photocatalytic CO2 reduction and RhB degradation. J. Mater. Res. 32, 3660 (2017).CrossRefGoogle Scholar
Li, S., Sun, S., Wu, H., Wei, C., and Hu, Y.: Effects of electron-donating groups on the photocatalytic reaction of MOFs. Catal. Sci. Technol. 8, 1696 (2018).CrossRefGoogle Scholar
Li, S., Feng, Z., Hu, Y., Wei, C., Wu, H., and Huang, J.: In situ synthesis and high-efficiency photocatalytic performance of Cu(I)/Cu(II) inorganic coordination polymer quantum sheets. Inorg. Chem. 57, 13289 (2018).CrossRefGoogle ScholarPubMed
Yin, H. and Tang, Z.: Ultrathin two-dimensional layered metal hydroxides: An emerging platform for advanced catalysis, energy conversion and storage. Chem. Soc. Rev. 45, 4873 (2016).CrossRefGoogle ScholarPubMed
Dou, L., Wong, A.B., Yu, Y., Lai, M., Kornienko, N., Eaton, S.W., Fu, A., Bischak, C.G., Ma, J., Ding, T., Ginsberg, N.S., Wang, L.W., Alivisatos, A.P., and Yang, P.: Atomically thin two-dimensional organic–inorganic hybrid perovskites. Science 349, 1518 (2015).CrossRefGoogle ScholarPubMed
Huang, J., Li, Y., Huang, R.K., He, C.T., Gong, L., Hu, Q., Wang, L.S., Xu, Y.T., Tian, X.Y., Liu, S.Y., Ye, Z.M., Wang, F.X., Zhou, D.D., Zhang, W.X., and Zhang, J.P.: Electrochemical exfoliation of pillared-layer metal–organic framework to boost the oxygen evolution reaction. Angew. Chem., Int. Ed. 57, 4632 (2018).CrossRefGoogle ScholarPubMed
Han, C., Zhang, Y., Gao, P., Chen, S., Liu, X., Mi, Y., and Chang, J.: High-yield production of MoS2 and WS2 quantum sheets from their bulk materials. Nano Lett. 17, 7767 (2017).CrossRefGoogle ScholarPubMed
Xu, M., Yuan, S., Chen, X.Y., Chang, Y.J., Day, G., Gu, Z.Y., and Zhou, H.C.: Two-dimensional metal–organic framework nanosheets as an enzyme inhibitor: Modulation of the α-chymotrypsin activity. J. Am. Chem. Soc. 139, 8312 (2017).CrossRefGoogle ScholarPubMed
Sim, U., Moon, J., An, J., Kang, J.H., Jerng, S.E., Moon, J., and Nam, K.T.: N-doped graphene quantum sheets on silicon nanowire photocathodes for hydrogen production. Energy Environ. Sci. 8, 1329 (2015).CrossRefGoogle Scholar
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D.C.B., Fujita, T., Chen, M., Asefa, T., Shenoy, V.B., Eda, G., and Chhowalla, M.: Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution. Nat. Mater. 12, 850 (2013).CrossRefGoogle Scholar
Supplementary material: File

Li et al. supplementary material

Figures S1-S6 and Table SI

Download Li et al. supplementary material(File)
File 5.3 MB