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High-performance antistatic acrylic coating by incorporation with modified graphene

Published online by Cambridge University Press:  21 January 2019

Yanjun Zhao ,
Weiyu Yao ,
Yu Wang ,
Quan Wang ,
Feipeng Lou  and
Weihong Guo Open the ORCID record for Weihong Guo [Opens in a new window]
Yanjun Zhao
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Weiyu Yao
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Yu Wang
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Quan Wang
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Feipeng Lou
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
Weihong Guo*
Affiliation:
Polymer Processing Laboratory, Key Laboratory for Preparation and Application of Ultrafine Materials of Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Graphene (G) has attracted great interest because of its excellent chemical and electrical properties. However, the aggregation of graphene restricts its application. Herein, linoleic acid sodium salt (LASS), a low-cost and environmentally friendly material, was used to improve the dispersion of graphene through covalent interaction. Then, the mixture (G@LASS) was integrated with acrylic resin matrix via hydrogen bond between the carboxyl and ester groups. The excellent interfacial compatibility between G@LASS and acrylic matrix, as well as good dispersibility of G@LASS, was demonstrated by Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, Raman, and scanning electron microscopy tests. Compared with acrylic matrix, the surface hydrophobicity of G@LASS@Acrylic increased considerably because of its compact structure. G@LASS@Acrylic composites meet the requirement of antistatic materials when the content of G was only about 0.5 wt%. The results showed that conductive pathways were established successfully through this method.

Keywords

graphenelinoleic acid sodium saltwater-based coatingshydrogen bondantistatic properties
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 4 , 28 February 2019 , pp. 510 - 518
Copyright
Copyright © Materials Research Society 2019 

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