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Fourier transform infrared analysis of hydroxyl content of hydrothermally processed heteroepitaxial barium titanate films

Published online by Cambridge University Press:  01 December 2005

Sandeep K. Patil ,
Nipun Shah ,
Frank D. Blum  and
Mohamed N. Rahaman
Sandeep K. Patil
Affiliation:
Department of Materials Science and Engineering, University of Missouri-Rolla, Rolla, Missouri 65409
Nipun Shah
Affiliation:
Materials Research Center, University of Missouri-Rolla, Rolla, Missouri 65409
Frank D. Blum
Affiliation:
Materials Research Center and Department of Chemistry, University of Missouri-Rolla, Rolla, Missouri 65409
Mohamed N. Rahaman*
Affiliation:
Department of Materials Science and Engineering, University of Missouri-Rolla, Rolla, Missouri 65409
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

The concentration of hydroxyl (–OH) groups in epitaxial barium titanate (BaTiO3) films (thickness ∼ 200 nm), deposited on single-crystal strontium titanate (SrTiO3) at 150 °C by a hydrothermal technique, was investigated using x-ray photoelectron spectroscopy and Fourier transform infrared (FTIR) spectroscopy. After hydrothermal treatment, a broad FTIR resonance for the hydroxyl groups indicated a significant concentration of surface –OH groups in the films. The as-deposited films were subsequently treated hydrothermally with D2O, and the kinetics of the exchange reaction between –OH incorporated into the film and –OD from the D2O were studied using FTIR. For reactions carried out intermittently, the kinetics of the exchange reaction between –OH by –OD depended not only on the total reaction time, but also on the duration of each treatment. The broad FTIR hydroxyl resonance in the as-deposited hydrothermal film was significantly reduced only after heating for 1 h at 600–800 °C.

Keywords

FilmHydrothermalInfrared (IR) spectroscopy
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 12 , December 2005 , pp. 3312 - 3319
Copyright
Copyright © Materials Research Society 2005

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